IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v219y2023ip2s0960148123014106.html
   My bibliography  Save this article

A-site deficient La1-xCr0.95Ru0.05O3-δ perovskites for N-hexadecane steam reforming: Effect of steam activation and active oxygen

Author

Listed:
  • Guo, Qunwei
  • Geng, Jiaqi
  • Pan, Jiawen
  • Chi, Bo
  • Xiong, Chunyan
  • Pu, Jian

Abstract

Liquid fuels like diesel, biodiesel, and alcohols can be utilized for onboard hydrogen production in auxiliary power systems by steam reforming, in which hydrogen productivity and carbon deposition are key issues. A-site deficient La1-xCr0.95Ru0.05O3 catalysts are prepared using the Glycine-nitrate method and characterized by multiple techniques. The catalyst with 20 % A-site deficiency exhibits about 95 % fuel conversion and stable performance over a 100 h continuous test at 750 °C and a steam/carbon ratio of 3.0 using n-hexadecane. However, the catalyst with a 10 % deficiency shows fluctuating fuel conversion with higher ethylene and ethane contents. Catalyst performance is mainly determined by active oxygen. The activation of steam on oxygen vacancies and Cr ions with variable valences could produce surface-free oxygen and freely migrating lattice oxygen respectively, which can react with CHx intermediates to form CO and H2.

Suggested Citation

  • Guo, Qunwei & Geng, Jiaqi & Pan, Jiawen & Chi, Bo & Xiong, Chunyan & Pu, Jian, 2023. "A-site deficient La1-xCr0.95Ru0.05O3-δ perovskites for N-hexadecane steam reforming: Effect of steam activation and active oxygen," Renewable Energy, Elsevier, vol. 219(P2).
    • Handle: RePEc:eee:renene:v:219:y:2023:i:p2:s0960148123014106
    DOI: 10.1016/j.renene.2023.119495
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148123014106
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2023.119495?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Menezes, João Paulo da S.Q. & Duarte, Karine R. & Manfro, Robinson L. & Souza, Mariana M.V.M., 2020. "Effect of niobia addition on cobalt catalysts supported on alumina for glycerol steam reforming," Renewable Energy, Elsevier, vol. 148(C), pages 864-875.
    2. Dragos Neagu & Tae-Sik Oh & David N. Miller & Hervé Ménard & Syed M. Bukhari & Stephen R. Gamble & Raymond J. Gorte & John M. Vohs & John T.S. Irvine, 2015. "Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    3. Jalali, Ramin & Rezaei, Mehran & Nematollahi, Behzad & Baghalha, Morteza, 2020. "Preparation of Ni/MeAl2O4-MgAl2O4 (Me=Fe, Co, Ni, Cu, Zn, Mg) nanocatalysts for the syngas production via combined dry reforming and partial oxidation of methane," Renewable Energy, Elsevier, vol. 149(C), pages 1053-1067.
    4. Aramouni, Nicolas Abdel Karim & Touma, Jad G. & Tarboush, Belal Abu & Zeaiter, Joseph & Ahmad, Mohammad N., 2018. "Catalyst design for dry reforming of methane: Analysis review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2570-2585.
    5. Zhu, Zhu & Liao, Qi & Liang, Yongtu & Qiu, Rui & Zhang, ZeZhou & Zhang, Haoran, 2022. "The era of renewables: Infrastructure disposal strategies under market decline of oil products," Energy, Elsevier, vol. 249(C).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Abdulrasheed, Abdulrahman & Jalil, Aishah Abdul & Gambo, Yahya & Ibrahim, Maryam & Hambali, Hambali Umar & Shahul Hamid, Muhamed Yusuf, 2019. "A review on catalyst development for dry reforming of methane to syngas: Recent advances," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 175-193.
    2. Lu, J.F. & Dong, Y.X. & Wang, Y.R. & Wang, W.L. & Ding, J., 2022. "High efficient thermochemical energy storage of methane reforming with carbon dioxide in cavity reactor with novel catalyst bed under concentrated sun simulator," Renewable Energy, Elsevier, vol. 188(C), pages 361-371.
    3. Bo-Wen Zhang & Meng-Nan Zhu & Min-Rui Gao & Xiuan Xi & Nanqi Duan & Zhou Chen & Ren-Fei Feng & Hongbo Zeng & Jing-Li Luo, 2022. "Boosting the stability of perovskites with exsolved nanoparticles by B-site supplement mechanism," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    4. Al-Fatesh, Ahmed Sadeq & Hanan atia, & Ibrahim, Ahmed Aidid & Fakeeha, Anis Hamza & Singh, Sunit Kumar & Labhsetwar, Nitin K. & Shaikh, Hamid & Qasim, Shamsudeen O., 2019. "CO2 reforming of CH4: Effect of Gd as promoter for Ni supported over MCM-41 as catalyst," Renewable Energy, Elsevier, vol. 140(C), pages 658-667.
    5. Chengyang Zhang & Renkun Zhang & Hui Liu & Qinhong Wei & Dandan Gong & Liuye Mo & Hengcong Tao & Sha Cui & Luhui Wang, 2020. "One-Step Synthesis of Highly Dispersed and Stable Ni Nanoparticles Confined by CeO 2 on SiO 2 for Dry Reforming of Methane," Energies, MDPI, vol. 13(22), pages 1-12, November.
    6. Macedo, M. Salomé & Soria, M.A. & Madeira, Luis M., 2021. "Process intensification for hydrogen production through glycerol steam reforming," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
    7. Baena-Moreno, Francisco M. & Sebastia-Saez, Daniel & Pastor-Pérez, Laura & Reina, Tomas Ramirez, 2021. "Analysis of the potential for biogas upgrading to syngas via catalytic reforming in the United Kingdom," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    8. Wang, Junkai & Zhou, Jun & Yang, Jiaming & Zong, Zheng & Fu, Lei & Lian, Zhongjie & Zhang, Xinchang & Wang, Xuan & Chen, Chengxiang & Ma, Wanli & Wu, Kai, 2020. "Nanoscale architecture of (La0.6Sr1.4)0.95Mn0.9B0.1O4 (BCo, Ni, Cu) Ruddlesden–Popper oxides as efficient and durable catalysts for symmetrical solid oxide fuel cells," Renewable Energy, Elsevier, vol. 157(C), pages 840-850.
    9. Mattia Boscherini & Alba Storione & Matteo Minelli & Francesco Miccio & Ferruccio Doghieri, 2023. "New Perspectives on Catalytic Hydrogen Production by the Reforming, Partial Oxidation and Decomposition of Methane and Biogas," Energies, MDPI, vol. 16(17), pages 1-33, September.
    10. Toledo, Mario & Arriagada, Andrés & Ripoll, Nicolás & Salgansky, Eugene A. & Mujeebu, Muhammad Abdul, 2023. "Hydrogen and syngas production by hybrid filtration combustion: Progress and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 177(C).
    11. Georgiadis, Amvrosios G. & Tsiotsias, Anastasios I. & Siakavelas, George I. & Charisiou, Nikolaos D. & Ehrhardt, Benedikt & Wang, Wen & Sebastian, Victor & Hinder, Steven J. & Baker, Mark A. & Mascott, 2024. "An experimental and theoretical approach for the biogas dry reforming reaction using perovskite-derived La0.8X0.2NiO3-δ catalysts (X = Sm, Pr, Ce)," Renewable Energy, Elsevier, vol. 227(C).
    12. Bian, Zhoufeng & Deng, Shaobi & Sun, Zhenkun & Ge, Tianshu & Jiang, Bo & Zhong, Wenqi, 2022. "Multi-core@Shell catalyst derived from LDH@SiO2 for low- temperature dry reforming of methane," Renewable Energy, Elsevier, vol. 200(C), pages 1362-1370.
    13. Galina Xanthopoulou & Savvas Varitis & Manapkhan Zhumabek & Konstantinos Karanasios & George Vekinis & Svetlana A. Tungatarova & Tolkyn S. Baizhumanova, 2021. "Direct Reduction in Greenhouse Gases by Continuous Dry (CO 2 ) Reforming of Methane over Ni-Containing SHS Catalysts," Energies, MDPI, vol. 14(19), pages 1-13, September.
    14. Arslan Mazhar & Asif Hussain Khoja & Abul Kalam Azad & Faisal Mushtaq & Salman Raza Naqvi & Sehar Shakir & Muhammad Hassan & Rabia Liaquat & Mustafa Anwar, 2021. "Performance Analysis of TiO 2 -Modified Co/MgAl 2 O 4 Catalyst for Dry Reforming of Methane in a Fixed Bed Reactor for Syngas (H 2 , CO) Production," Energies, MDPI, vol. 14(11), pages 1-20, June.
    15. Wang, Junkai & Yang, Jiaming & Fu, Lei & Zong, Zheng & Zhou, Jun & Wu, Kai, 2022. "In-situ growth of Ru/RuO2 nanoparticles decorated (La0.6Sr1.4)0.95Mn0.9Ru0.1O4 as a potential electrode for symmetrical solid oxide fuel cells," Renewable Energy, Elsevier, vol. 189(C), pages 1419-1427.
    16. Sanaz Koohfar & Masoud Ghasemi & Tyler Hafen & Georgios Dimitrakopoulos & Dongha Kim & Jenna Pike & Singaravelu Elangovan & Enrique D. Gomez & Bilge Yildiz, 2023. "Improvement of oxygen reduction activity and stability on a perovskite oxide surface by electrochemical potential," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    17. Simon P. Philbin, 2020. "Critical Analysis and Evaluation of the Technology Pathways for Carbon Capture and Utilization," Clean Technol., MDPI, vol. 2(4), pages 1-21, December.
    18. Vecino-Mantilla, Sebastian & Zignani, Sabrina C. & Vannier, Rose-Noëlle & Aricò, Antonino S. & Lo Faro, Massimiliano, 2022. "Insights on a Ruddlesden-Popper phase as an active layer for a solid oxide fuel cell fed with dry biogas," Renewable Energy, Elsevier, vol. 192(C), pages 784-792.
    19. Li, Ziwei & Lin, Qian & Li, Min & Cao, Jianxin & Liu, Fei & Pan, Hongyan & Wang, Zhigang & Kawi, Sibudjing, 2020. "Recent advances in process and catalyst for CO2 reforming of methane," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    20. Zain, Munirah Md & Mohamed, Abdul Rahman, 2018. "An overview on conversion technologies to produce value added products from CH4 and CO2 as major biogas constituents," Renewable and Sustainable Energy Reviews, Elsevier, vol. 98(C), pages 56-63.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:219:y:2023:i:p2:s0960148123014106. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.