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One-Step Synthesis of Highly Dispersed and Stable Ni Nanoparticles Confined by CeO 2 on SiO 2 for Dry Reforming of Methane

Author

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  • Chengyang Zhang

    (Department of Chemical Engineering, School of Petrochemical Engineering & Environment, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, China
    School of Marine Engineering Equipments, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, China)

  • Renkun Zhang

    (Department of Chemical Engineering, School of Petrochemical Engineering & Environment, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, China)

  • Hui Liu

    (School of Food and Pharmaceutical, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, China)

  • Qinhong Wei

    (Department of Chemical Engineering, School of Petrochemical Engineering & Environment, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, China)

  • Dandan Gong

    (Department of Chemical Engineering, School of Petrochemical Engineering & Environment, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, China)

  • Liuye Mo

    (Institute of Innovation & Application, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, China)

  • Hengcong Tao

    (Department of Chemical Engineering, School of Petrochemical Engineering & Environment, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, China)

  • Sha Cui

    (Department of Chemical Engineering, School of Petrochemical Engineering & Environment, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, China)

  • Luhui Wang

    (Department of Chemical Engineering, School of Petrochemical Engineering & Environment, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, China)

Abstract

Sintering and carbon deposition are the two main ways to deactivate Ni-based catalysts during methane reforming. Herein, a stable Ni-CeO 2 /SiO 2 (CSC) catalyst was prepared by a one-step colloidal solution combustion method (CSC) and used for dry reforming of methane. In the catalyst, the small Ni particles were confined by CeO 2 particles and highly dispersed on the surface of SiO 2 , forming a spatial confinement structure with a rich Ni-CeO 2 interface in the catalyst. The Ni-CeO 2 /SiO 2 (CSC) catalyst prepared by the one-step CSC method exhibited superior activity at 700 °C during dry reforming of methane, and the performance of the catalyst was stable after 20 h of reaction with only a small amount of carbon deposition present (1.8%). Due to the spatial confinement effect, Ni was stable and less than 5 nm during reaction. The small Ni particle size and rich Ni-CeO 2 interface reduced the rate of carbon deposition. This colloidal combustion method could be applied to prepare stable metal-based catalysts with rich metal–oxide interfaces for high-temperature reactions.

Suggested Citation

  • Chengyang Zhang & Renkun Zhang & Hui Liu & Qinhong Wei & Dandan Gong & Liuye Mo & Hengcong Tao & Sha Cui & Luhui Wang, 2020. "One-Step Synthesis of Highly Dispersed and Stable Ni Nanoparticles Confined by CeO 2 on SiO 2 for Dry Reforming of Methane," Energies, MDPI, vol. 13(22), pages 1-12, November.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:22:p:5956-:d:445261
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    References listed on IDEAS

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    1. Aramouni, Nicolas Abdel Karim & Touma, Jad G. & Tarboush, Belal Abu & Zeaiter, Joseph & Ahmad, Mohammad N., 2018. "Catalyst design for dry reforming of methane: Analysis review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2570-2585.
    2. Abdulrasheed, Abdulrahman & Jalil, Aishah Abdul & Gambo, Yahya & Ibrahim, Maryam & Hambali, Hambali Umar & Shahul Hamid, Muhamed Yusuf, 2019. "A review on catalyst development for dry reforming of methane to syngas: Recent advances," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 175-193.
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