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Multi-core@Shell catalyst derived from LDH@SiO2 for low- temperature dry reforming of methane

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  • Bian, Zhoufeng
  • Deng, Shaobi
  • Sun, Zhenkun
  • Ge, Tianshu
  • Jiang, Bo
  • Zhong, Wenqi

Abstract

In this paper, a multi-core@shell catalyst LDH@SiO2 was fabricated by coating a silica layer over hexagonal Ni–Mg–Al LDH nanoplates. After calcination and H2-reduction, Ni nanoparticles were well dispersed on the support, as well as encapsulated within the mesoporous silica shell. The multi-core@shell catalyst was then tested in low temperature dry reforming of methane (DRM) at 600 °C and showed a stable CH4 conversion of 27% for 16 h time on stream. Characterizations of the spent catalyst indicated that there was almost no carbon formation and the multi-core@shell structure was well preserved. While the pristine layered double hydroxide (LDH) catalyst exhibited a severe carbon formation as 68%. The confinement effect conveyed by the unique multi-core@shell structure effectively suppressed metal sintering and carbon deposition. Besides, the thickness of the silica shell was tuned and it made a great difference to the catalytic activity due to the diffusion resistance.

Suggested Citation

  • Bian, Zhoufeng & Deng, Shaobi & Sun, Zhenkun & Ge, Tianshu & Jiang, Bo & Zhong, Wenqi, 2022. "Multi-core@Shell catalyst derived from LDH@SiO2 for low- temperature dry reforming of methane," Renewable Energy, Elsevier, vol. 200(C), pages 1362-1370.
    • Handle: RePEc:eee:renene:v:200:y:2022:i:c:p:1362-1370
    DOI: 10.1016/j.renene.2022.10.046
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    1. Jalali, Ramin & Rezaei, Mehran & Nematollahi, Behzad & Baghalha, Morteza, 2020. "Preparation of Ni/MeAl2O4-MgAl2O4 (Me=Fe, Co, Ni, Cu, Zn, Mg) nanocatalysts for the syngas production via combined dry reforming and partial oxidation of methane," Renewable Energy, Elsevier, vol. 149(C), pages 1053-1067.
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    More about this item

    Keywords

    Low temperature DRM; H2 production; Multi-core@shell; Carbon resistance; Confinement effect;
    All these keywords.

    JEL classification:

    • H2 - Public Economics - - Taxation, Subsidies, and Revenue

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