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Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution

Author

Listed:
  • Dragos Neagu

    (School of Chemistry, University of St Andrews)

  • Tae-Sik Oh

    (University of Pennsylvania)

  • David N. Miller

    (School of Chemistry, University of St Andrews)

  • Hervé Ménard

    (Sasol Technology (UK) Ltd.)

  • Syed M. Bukhari

    (School of Chemistry, University of St Andrews)

  • Stephen R. Gamble

    (School of Chemistry, University of St Andrews)

  • Raymond J. Gorte

    (University of Pennsylvania)

  • John M. Vohs

    (University of Pennsylvania)

  • John T.S. Irvine

    (School of Chemistry, University of St Andrews)

Abstract

Metal particles supported on oxide surfaces are used as catalysts for a wide variety of processes in the chemical and energy conversion industries. For catalytic applications, metal particles are generally formed on an oxide support by physical or chemical deposition, or less commonly by exsolution from it. Although fundamentally different, both methods might be assumed to produce morphologically and functionally similar particles. Here we show that unlike nickel particles deposited on perovskite oxides, exsolved analogues are socketed into the parent perovskite, leading to enhanced stability and a significant decrease in the propensity for hydrocarbon coking, indicative of a stronger metal–oxide interface. In addition, we reveal key surface effects and defect interactions critical for future design of exsolution-based perovskite materials for catalytic and other functionalities. This study provides a new dimension for tailoring particle–substrate interactions in the context of increasing interest for emergent interfacial phenomena.

Suggested Citation

  • Dragos Neagu & Tae-Sik Oh & David N. Miller & Hervé Ménard & Syed M. Bukhari & Stephen R. Gamble & Raymond J. Gorte & John M. Vohs & John T.S. Irvine, 2015. "Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    • Handle: RePEc:nat:natcom:v:6:y:2015:i:1:d:10.1038_ncomms9120
    DOI: 10.1038/ncomms9120
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    1. Hyunmin Kim & Chaesung Lim & Ohhun Kwon & Jinkyung Oh & Matthew T. Curnan & Hu Young Jeong & Sihyuk Choi & Jeong Woo Han & Guntae Kim, 2021. "Unveiling the key factor for the phase reconstruction and exsolved metallic particle distribution in perovskites," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    2. Wang, Junkai & Yang, Jiaming & Fu, Lei & Zong, Zheng & Zhou, Jun & Wu, Kai, 2022. "In-situ growth of Ru/RuO2 nanoparticles decorated (La0.6Sr1.4)0.95Mn0.9Ru0.1O4 as a potential electrode for symmetrical solid oxide fuel cells," Renewable Energy, Elsevier, vol. 189(C), pages 1419-1427.
    3. Kwon, Byeong Wan & Oh, Joo Hyeng & Kim, Ghun Sik & Yoon, Sung Pil & Han, Jonghee & Nam, Suk Woo & Ham, Hyung Chul, 2018. "The novel perovskite-type Ni-doped Sr0.92Y0.08TiO3 as a reforming biogas (CH4+CO2) for H2 production," Applied Energy, Elsevier, vol. 227(C), pages 213-219.
    4. Vecino-Mantilla, Sebastian & Zignani, Sabrina C. & Vannier, Rose-Noëlle & Aricò, Antonino S. & Lo Faro, Massimiliano, 2022. "Insights on a Ruddlesden-Popper phase as an active layer for a solid oxide fuel cell fed with dry biogas," Renewable Energy, Elsevier, vol. 192(C), pages 784-792.
    5. Shuo Liu & Chaochao Dun & Qike Jiang & Zhengxi Xuan & Feipeng Yang & Jinghua Guo & Jeffrey J. Urban & Mark T. Swihart, 2024. "Challenging thermodynamics: combining immiscible elements in a single-phase nano-ceramic," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    6. Georgiadis, Amvrosios G. & Tsiotsias, Anastasios I. & Siakavelas, George I. & Charisiou, Nikolaos D. & Ehrhardt, Benedikt & Wang, Wen & Sebastian, Victor & Hinder, Steven J. & Baker, Mark A. & Mascott, 2024. "An experimental and theoretical approach for the biogas dry reforming reaction using perovskite-derived La0.8X0.2NiO3-δ catalysts (X = Sm, Pr, Ce)," Renewable Energy, Elsevier, vol. 227(C).
    7. Chan, Wei Ping & Veksha, Andrei & Lei, Junxi & Oh, Wen-Da & Dou, Xiaomin & Giannis, Apostolos & Lisak, Grzegorz & Lim, Teik-Thye, 2019. "A hot syngas purification system integrated with downdraft gasification of municipal solid waste," Applied Energy, Elsevier, vol. 237(C), pages 227-240.
    8. Sanaz Koohfar & Masoud Ghasemi & Tyler Hafen & Georgios Dimitrakopoulos & Dongha Kim & Jenna Pike & Singaravelu Elangovan & Enrique D. Gomez & Bilge Yildiz, 2023. "Improvement of oxygen reduction activity and stability on a perovskite oxide surface by electrochemical potential," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    9. Wang, Junkai & Zhou, Jun & Yang, Jiaming & Zong, Zheng & Fu, Lei & Lian, Zhongjie & Zhang, Xinchang & Wang, Xuan & Chen, Chengxiang & Ma, Wanli & Wu, Kai, 2020. "Nanoscale architecture of (La0.6Sr1.4)0.95Mn0.9B0.1O4 (BCo, Ni, Cu) Ruddlesden–Popper oxides as efficient and durable catalysts for symmetrical solid oxide fuel cells," Renewable Energy, Elsevier, vol. 157(C), pages 840-850.
    10. Hyeon Han & Yaolong Xing & Bumsu Park & Dmitry I. Bazhanov & Yeongrok Jin & John T. S. Irvine & Jaekwang Lee & Sang Ho Oh, 2022. "Anti-phase boundary accelerated exsolution of nanoparticles in non-stoichiometric perovskite thin films," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    11. Eleonora Calì & Melonie P. Thomas & Rama Vasudevan & Ji Wu & Oriol Gavalda-Diaz & Katharina Marquardt & Eduardo Saiz & Dragos Neagu & Raymond R. Unocic & Stephen C. Parker & Beth S. Guiton & David J. , 2023. "Real-time insight into the multistage mechanism of nanoparticle exsolution from a perovskite host surface," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    12. Nechache, Aziz & Hody, Stéphane, 2021. "Alternative and innovative solid oxide electrolysis cell materials: A short review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    13. Guo, Qunwei & Geng, Jiaqi & Pan, Jiawen & Chi, Bo & Xiong, Chunyan & Pu, Jian, 2023. "A-site deficient La1-xCr0.95Ru0.05O3-δ perovskites for N-hexadecane steam reforming: Effect of steam activation and active oxygen," Renewable Energy, Elsevier, vol. 219(P2).
    14. Min Xu & Yukwon Jeon & Aaron Naden & Heesu Kim & Gwilherm Kerherve & David J. Payne & Yong-gun Shul & John T. S. Irvine, 2024. "Synergistic growth of nickel and platinum nanoparticles via exsolution and surface reaction," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    15. Jo, Seungyeon & Han Kim, Yo & Jeong, Hyeongwon & Park, Chan-ho & Won, Bo-Ram & Jeon, Hyejin & Taek Lee, Kang & Myung, Jae-ha, 2022. "Exsolution of phase-separated nanoparticles via trigger effect toward reversible solid oxide cell," Applied Energy, Elsevier, vol. 323(C).
    16. Abdulrasheed, Abdulrahman & Jalil, Aishah Abdul & Gambo, Yahya & Ibrahim, Maryam & Hambali, Hambali Umar & Shahul Hamid, Muhamed Yusuf, 2019. "A review on catalyst development for dry reforming of methane to syngas: Recent advances," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 175-193.
    17. Bo-Wen Zhang & Meng-Nan Zhu & Min-Rui Gao & Xiuan Xi & Nanqi Duan & Zhou Chen & Ren-Fei Feng & Hongbo Zeng & Jing-Li Luo, 2022. "Boosting the stability of perovskites with exsolved nanoparticles by B-site supplement mechanism," Nature Communications, Nature, vol. 13(1), pages 1-12, December.

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