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Direct Reduction in Greenhouse Gases by Continuous Dry (CO 2 ) Reforming of Methane over Ni-Containing SHS Catalysts

Author

Listed:
  • Galina Xanthopoulou

    (Institute of Nanoscience and Nanotechnology, NCSR Demokritos, 15310 Athens, Greece)

  • Savvas Varitis

    (Institute of Nanoscience and Nanotechnology, NCSR Demokritos, 15310 Athens, Greece
    Department of Physics, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece)

  • Manapkhan Zhumabek

    (D.V. Sokolsky Institute of Fuel, Catalysis and Electrochemistry, 142, Kunaev Str., Almaty 050010, Kazakhstan
    Institute of Chemical and Biological Technologies, Satbayev University, 22a, Satpaev Str., Almaty 050013, Kazakhstan)

  • Konstantinos Karanasios

    (Institute of Nanoscience and Nanotechnology, NCSR Demokritos, 15310 Athens, Greece)

  • George Vekinis

    (Institute of Nanoscience and Nanotechnology, NCSR Demokritos, 15310 Athens, Greece)

  • Svetlana A. Tungatarova

    (D.V. Sokolsky Institute of Fuel, Catalysis and Electrochemistry, 142, Kunaev Str., Almaty 050010, Kazakhstan
    Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71, Al-Farabi Str., Almaty 050040, Kazakhstan)

  • Tolkyn S. Baizhumanova

    (D.V. Sokolsky Institute of Fuel, Catalysis and Electrochemistry, 142, Kunaev Str., Almaty 050010, Kazakhstan
    Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71, Al-Farabi Str., Almaty 050040, Kazakhstan)

Abstract

The world of energy is on the cusp of profound transformation. Hydrogen or hydrogen-containing fuel mixtures in the form of synthesis gas, as carriers of clean energy, will be in the short term among the most efficient solutions to pressing environmental problems, reducing the amount of greenhouse gases as well as pollution of cities and dependence on oil-based fuels. Carbon dioxide conversion of methane is the most promising method for the production of synthesis gas due to the simultaneous consumption of two greenhouse gases and, accordingly, a successful solution to environmental problems. Ni/Mn-based catalysts have been prepared by self-propagating high-temperature synthesis (SHS) for this process. The samples were characterized by X-ray diffraction, scanning electron microscopy, and nitrogen porosimetry. The effects of the catalysts’ composition on activity, selectivity, and product yield were investigated. The influence of the content of Ni, Mn on the behavior of catalysts has been established. Comparison of spinels with different component ratios showed that they have a defective structure. Non-stoichiometric spinels with highly defective catalyst structures were obtained due to very high heating and cooling rates during SHS. They work as active sites, which underlies the high activity of the catalysts.

Suggested Citation

  • Galina Xanthopoulou & Savvas Varitis & Manapkhan Zhumabek & Konstantinos Karanasios & George Vekinis & Svetlana A. Tungatarova & Tolkyn S. Baizhumanova, 2021. "Direct Reduction in Greenhouse Gases by Continuous Dry (CO 2 ) Reforming of Methane over Ni-Containing SHS Catalysts," Energies, MDPI, vol. 14(19), pages 1-13, September.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:19:p:6078-:d:641951
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    References listed on IDEAS

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    1. Jalali, Ramin & Rezaei, Mehran & Nematollahi, Behzad & Baghalha, Morteza, 2020. "Preparation of Ni/MeAl2O4-MgAl2O4 (Me=Fe, Co, Ni, Cu, Zn, Mg) nanocatalysts for the syngas production via combined dry reforming and partial oxidation of methane," Renewable Energy, Elsevier, vol. 149(C), pages 1053-1067.
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