IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i9p2412-d542080.html
   My bibliography  Save this article

Hydrogen Yield from CO 2 Reforming of Methane: Impact of La 2 O 3 Doping on Supported Ni Catalysts

Author

Listed:
  • Ahmed Abasaeed

    (Chemical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia)

  • Samsudeen Kasim

    (Chemical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia)

  • Wasim Khan

    (Chemical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia
    Department of Chemical and Process Engineering, University of Canterbury, 20 Kirkwood Avenue, Upper Riccarton, Christchurch 8041, New Zealand)

  • Mahmud Sofiu

    (Chemical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia)

  • Ahmed Ibrahim

    (Chemical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia)

  • Anis Fakeeha

    (Chemical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia
    King Abdullah City for Atomic & Renewable Energy, Energy Research & Innovation Center (ERIC) in Riyadh, Riyadh 11451, Saudi Arabia)

  • Ahmed Al-Fatesh

    (Chemical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia)

Abstract

Development of a transition metal based catalyst aiming at concomitant high activity and stability attributed to distinguished catalytic characteristics is considered as the bottleneck for dry reforming of methane (DRM). This work highlights the role of modifying zirconia (ZrO 2 ) and alumina (Al 2 O 3 ) supported nickel based catalysts using lanthanum oxide (La 2 O 3 ) varying from 0 to 20 wt% during dry reforming of methane. The mesoporous catalysts with improved BET surface areas, improved dispersion, relatively lower reduction temperatures and enhanced surface basicity are identified after La 2 O 3 doping. These factors have influenced the catalytic activity and higher hydrogen yields are found for La 2 O 3 modified catalysts as compared to base catalysts (5 wt% Ni-ZrO 2 and 5 wt% Ni-Al 2 O 3 ). Post-reaction characterizations such as TGA have showed less coke formation over La 2 O 3 modified samples. Raman spectra indicates decreased graphitization for La 2 O 3 catalysts. The 5Ni-10La 2 O 3 -ZrO 2 catalyst produced 80% hydrogen yields, 25% more than that of 5Ni-ZrO 2 . 5Ni-15La 2 O 3 -Al 2 O 3 gave 84% hydrogen yields, 8% higher than that of 5Ni-Al 2 O 3 . Higher CO 2 activity improved the surface carbon oxidation rate. From the study, the extent of La 2 O 3 loading is dependent on the type of oxide support.

Suggested Citation

  • Ahmed Abasaeed & Samsudeen Kasim & Wasim Khan & Mahmud Sofiu & Ahmed Ibrahim & Anis Fakeeha & Ahmed Al-Fatesh, 2021. "Hydrogen Yield from CO 2 Reforming of Methane: Impact of La 2 O 3 Doping on Supported Ni Catalysts," Energies, MDPI, vol. 14(9), pages 1-14, April.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:9:p:2412-:d:542080
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/9/2412/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/14/9/2412/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Jalali, Ramin & Rezaei, Mehran & Nematollahi, Behzad & Baghalha, Morteza, 2020. "Preparation of Ni/MeAl2O4-MgAl2O4 (Me=Fe, Co, Ni, Cu, Zn, Mg) nanocatalysts for the syngas production via combined dry reforming and partial oxidation of methane," Renewable Energy, Elsevier, vol. 149(C), pages 1053-1067.
    2. Boyano, A. & Blanco-Marigorta, A.M. & Morosuk, T. & Tsatsaronis, G., 2011. "Exergoenvironmental analysis of a steam methane reforming process for hydrogen production," Energy, Elsevier, vol. 36(4), pages 2202-2214.
    3. Themelis, Nickolas J. & Ulloa, Priscilla A., 2007. "Methane generation in landfills," Renewable Energy, Elsevier, vol. 32(7), pages 1243-1257.
    4. Wang, Qiang & Chen, Xi & Jha, Awadhesh N. & Rogers, Howard, 2014. "Natural gas from shale formation – The evolution, evidences and challenges of shale gas revolution in United States," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 1-28.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sharafian, Amir & Talebian, Hoda & Blomerus, Paul & Herrera, Omar & Mérida, Walter, 2017. "A review of liquefied natural gas refueling station designs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 503-513.
    2. Seck, Gondia Sokhna & Hache, Emmanuel & D'Herbemont, Vincent & Guyot, Mathis & Malbec, Louis-Marie, 2023. "Hydrogen development in Europe: Estimating material consumption in net zero emissions scenarios," International Economics, Elsevier, vol. 176(C).
    3. Lu, J.F. & Dong, Y.X. & Wang, Y.R. & Wang, W.L. & Ding, J., 2022. "High efficient thermochemical energy storage of methane reforming with carbon dioxide in cavity reactor with novel catalyst bed under concentrated sun simulator," Renewable Energy, Elsevier, vol. 188(C), pages 361-371.
    4. Xiaoyan Zou & Xianqing Li & Jizhen Zhang & Huantong Li & Man Guo & Pei Zhao, 2021. "Characteristics of Pore Structure and Gas Content of the Lower Paleozoic Shale from the Upper Yangtze Plate, South China," Energies, MDPI, vol. 14(22), pages 1-29, November.
    5. Sofia Dahlgren & Jonas Ammenberg, 2021. "Sustainability Assessment of Public Transport, Part II—Applying a Multi-Criteria Assessment Method to Compare Different Bus Technologies," Sustainability, MDPI, vol. 13(3), pages 1-30, January.
    6. Diyamandoglu, Vasil & Fortuna, Lorena M., 2015. "Deconstruction of wood-framed houses: Material recovery and environmental impact," Resources, Conservation & Recycling, Elsevier, vol. 100(C), pages 21-30.
    7. Reijnders, L., 2009. "Are forestation, bio-char and landfilled biomass adequate offsets for the climate effects of burning fossil fuels?," Energy Policy, Elsevier, vol. 37(8), pages 2839-2841, August.
    8. Gürbüz, Emine Yağız & Güler, Onur Vahip & Keçebaş, Ali, 2022. "Environmental impact assessment of a real geothermal driven power plant with two-stage ORC using enhanced exergo-environmental analysis," Renewable Energy, Elsevier, vol. 185(C), pages 1110-1123.
    9. Luis Sarmiento & Thorsten Burandt & Konstantin Löffler & Pao-Yu Oei, 2019. "Analyzing Scenarios for the Integration of Renewable Energy Sources in the Mexican Energy System—An Application of the Global Energy System Model (GENeSYS-MOD)," Energies, MDPI, vol. 12(17), pages 1-24, August.
    10. Balli, Ozgur & Kale, Utku & Rohács, Dániel & Hikmet Karakoc, T., 2022. "Environmental damage cost and exergoenvironmental evaluations of piston prop aviation engines for the landing and take-off flight phases," Energy, Elsevier, vol. 261(PB).
    11. Hao, Xiaoli & Yang, Hongxing & Zhang, Guoqiang, 2008. "Trigeneration: A new way for landfill gas utilization and its feasibility in Hong Kong," Energy Policy, Elsevier, vol. 36(10), pages 3662-3673, October.
    12. Ogunjuyigbe, A.S.O. & Ayodele, T.R. & Alao, M.A., 2017. "Electricity generation from municipal solid waste in some selected cities of Nigeria: An assessment of feasibility, potential and technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 149-162.
    13. Agostinho, Feni & Almeida, Cecília M.V.B. & Bonilla, Silvia H. & Sacomano, José B. & Giannetti, Biagio F., 2013. "Urban solid waste plant treatment in Brazil: Is there a net emergy yield on the recovered materials?," Resources, Conservation & Recycling, Elsevier, vol. 73(C), pages 143-155.
    14. Wang, Qiang & Li, Shuyu & Li, Rongrong & Ma, Minglu, 2018. "Forecasting U.S. shale gas monthly production using a hybrid ARIMA and metabolic nonlinear grey model," Energy, Elsevier, vol. 160(C), pages 378-387.
    15. Cuilin Li & Ya-Juan Du & Qiang Ji & Jiang-bo Geng, 2019. "Multiscale Market Integration and Nonlinear Granger Causality between Natural Gas Futures and Physical Markets," Sustainability, MDPI, vol. 11(19), pages 1-23, October.
    16. Nhuchhen, Daya R. & Sit, Song P. & Layzell, David B., 2022. "Towards net-zero emission cement and power production using Molten Carbonate Fuel Cells," Applied Energy, Elsevier, vol. 306(PB).
    17. Blanco-Marigorta, Ana M. & Masi, Marco & Manfrida, Giampaolo, 2014. "Exergo-environmental analysis of a reverse osmosis desalination plant in Gran Canaria," Energy, Elsevier, vol. 76(C), pages 223-232.
    18. Cai, Zhengyu & Maguire, Karen & Winters, John V., 2019. "Who benefits from local oil and gas employment? Labor market composition in the oil and gas industry in Texas and the rest of the United States," Energy Economics, Elsevier, vol. 84(C).
    19. Uddin, Md Mosleh & Simson, Amanda & Wright, Mark Mba, 2020. "Techno-economic and greenhouse gas emission analysis of dimethyl ether production via the bi-reforming pathway for transportation fuel," Energy, Elsevier, vol. 211(C).
    20. Xue-Ting Jiang & Rongrong Li, 2017. "Decoupling and Decomposition Analysis of Carbon Emissions from Electric Output in the United States," Sustainability, MDPI, vol. 9(6), pages 1-13, May.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:9:p:2412-:d:542080. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.