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Modern Trends in Design of Catalysts for Transformation of Biofuels into Syngas and Hydrogen: From Fundamental Bases to Performance in Real Feeds

Author

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  • Vladislav Sadykov

    (Department of Heterogeneous Catalysis, Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia)

  • Mikhail Simonov

    (Department of Heterogeneous Catalysis, Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia)

  • Nikita Eremeev

    (Department of Heterogeneous Catalysis, Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia)

  • Natalia Mezentseva

    (Department of Heterogeneous Catalysis, Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia)

Abstract

This review considers problems related to design of efficient structured catalysts for natural gas and biofuels transformation into syngas. Their active components are comprised of fluorite, perovskite and spinel oxides or their nanocomposites (both bulk and supported on high surface area Mg-doped alumina or MgAl 2 O 4 ) promoted by platinum group metals, nickel and their alloys. A complex of modern structural, spectroscopic and kinetic methods was applied to elucidate atomic-scale factors controlling their performance and stability to coking, such as dispersion of metals/alloys, strong metal-support interaction and oxygen mobility/reactivity as dependent upon their composition and synthesis procedures. Monolithic catalysts comprised of optimized active components loaded on structured substrates with a high thermal conductivity demonstrated high activity and stability to coking in processes of natural gas and biofuels reforming into syngas. A pilot-scale axial reactor equipped with the internal heat exchanger and such catalysts allowed to efficiently convert into syngas the mixture of natural gas, air and liquid biofuels in the autothermal reforming mode at low (~50–100 °C) inlet temperatures and GHSV up to 40,000 h −1 .

Suggested Citation

  • Vladislav Sadykov & Mikhail Simonov & Nikita Eremeev & Natalia Mezentseva, 2021. "Modern Trends in Design of Catalysts for Transformation of Biofuels into Syngas and Hydrogen: From Fundamental Bases to Performance in Real Feeds," Energies, MDPI, vol. 14(19), pages 1-25, October.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:19:p:6334-:d:649770
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    References listed on IDEAS

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    1. Dou, Binlin & Song, Yongchen & Wang, Chao & Chen, Haisheng & Xu, Yujie, 2014. "Hydrogen production from catalytic steam reforming of biodiesel byproduct glycerol: Issues and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 950-960.
    2. Valeria Fedorova & Mikhail Simonov & Konstantin Valeev & Yuliya Bespalko & Ekaterina Smal & Nikita Eremeev & Ekaterina Sadovskaya & Tamara Krieger & Arcady Ishchenko & Vladislav Sadykov, 2021. "Kinetic Regularities of Methane Dry Reforming Reaction on Nickel-Containing Modified Ceria–Zirconia," Energies, MDPI, vol. 14(10), pages 1-16, May.
    3. Bian, Zhoufeng & Wang, Zhigang & Jiang, Bo & Hongmanorom, Plaifa & Zhong, Wenqi & Kawi, Sibudjing, 2020. "A review on perovskite catalysts for reforming of methane to hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    4. Yuliya Bespalko & Ekaterina Smal & Mikhail Simonov & Konstantin Valeev & Valeria Fedorova & Tamara Krieger & Svetlana Cherepanova & Arcady Ishchenko & Vladimir Rogov & Vladislav Sadykov, 2020. "Novel Ni/Ce(Ti)ZrO 2 Catalysts for Methane Dry Reforming Prepared in Supercritical Alcohol Media," Energies, MDPI, vol. 13(13), pages 1-24, July.
    5. Svetlana Pavlova & Marina Smirnova & Aleksei Bobin & Svetlana Cherepanova & Vasily Kaichev & Arcady Ishchenko & Aleksandra Selivanova & Vladimir Rogov & Anne-Cécile Roger & Vladislav Sadykov, 2020. "Structural, Textural, and Catalytic Properties of Ni-Ce x Zr 1−x O 2 Catalysts for Methane Dry Reforming Prepared by Continuous Synthesis in Supercritical Isopropanol," Energies, MDPI, vol. 13(14), pages 1-20, July.
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    1. Vladislav Sadykov, 2023. "Advances in Hydrogen and Syngas Generation," Energies, MDPI, vol. 16(7), pages 1-4, March.

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