IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-36646-2.html
   My bibliography  Save this article

Synergistic promotions between CO2 capture and in-situ conversion on Ni-CaO composite catalyst

Author

Listed:
  • Bin Shao

    (East China University of Science and Technology)

  • Zhi-Qiang Wang

    (East China University of Science and Technology)

  • Xue-Qing Gong

    (East China University of Science and Technology)

  • Honglai Liu

    (East China University of Science and Technology
    East China University of Science and Technology)

  • Feng Qian

    (East China University of Science and Technology)

  • P. Hu

    (East China University of Science and Technology
    The Queen’s University of Belfast)

  • Jun Hu

    (East China University of Science and Technology)

Abstract

The integrated CO2 capture and conversion (iCCC) technology has been booming as a promising cost-effective approach for Carbon Neutrality. However, the lack of the long-sought molecular consensus about the synergistic effect between the adsorption and in-situ catalytic reaction hinders its development. Herein, we illustrate the synergistic promotions between CO2 capture and in-situ conversion through constructing the consecutive high-temperature Calcium-looping and dry reforming of methane processes. With systematic experimental measurements and density functional theory calculations, we reveal that the pathways of the reduction of carbonate and the dehydrogenation of CH4 can be interactively facilitated by the participation of the intermediates produced in each process on the supported Ni–CaO composite catalyst. Specifically, the adsorptive/catalytic interface, which is controlled by balancing the loading density and size of Ni nanoparticles on porous CaO, plays an essential role in the ultra-high CO2 and CH4 conversions of 96.5% and 96.0% at 650 °C, respectively.

Suggested Citation

  • Bin Shao & Zhi-Qiang Wang & Xue-Qing Gong & Honglai Liu & Feng Qian & P. Hu & Jun Hu, 2023. "Synergistic promotions between CO2 capture and in-situ conversion on Ni-CaO composite catalyst," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36646-2
    DOI: 10.1038/s41467-023-36646-2
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-36646-2
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-023-36646-2?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Mengran Li & Erdem Irtem & Hugo-Pieter Iglesias van Montfort & Maryam Abdinejad & Thomas Burdyny, 2022. "Energy comparison of sequential and integrated CO2 capture and electrochemical conversion," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Mutch, Greg A. & Anderson, James A. & Vega-Maza, David, 2017. "Surface and bulk carbonate formation in calcium oxide during CO2 capture," Applied Energy, Elsevier, vol. 202(C), pages 365-376.
    3. Alexey Kurlov & Evgeniya B. Deeva & Paula M. Abdala & Dmitry Lebedev & Athanasia Tsoukalou & Aleix Comas-Vives & Alexey Fedorov & Christoph R. Müller, 2020. "Exploiting two-dimensional morphology of molybdenum oxycarbide to enable efficient catalytic dry reforming of methane," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    4. Yan Tang & Chithra Asokan & Mingjie Xu & George W. Graham & Xiaoqing Pan & Phillip Christopher & Jun Li & Philippe Sautet, 2019. "Rh single atoms on TiO2 dynamically respond to reaction conditions by adapting their site," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wu, Xiaomei & Mao, Yuanhao & Fan, Huifeng & Sultan, Sayd & Yu, Yunsong & Zhang, Zaoxiao, 2023. "Investigation on the performance of EDA-based blended solvents for electrochemically mediated CO2 capture," Applied Energy, Elsevier, vol. 349(C).
    2. Xingyue Ma & Shuxuan Luo & Yunhui Hua & Seshadri Seetharaman & Xiaobo Zhu & Jingwei Hou & Lei Zhang & Wanlin Wang & Yongqi Sun, 2024. "An alumina phase induced composite transition shuttle to stabilize carbon capture cycles," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Lv, Zongze & Du, Hong & Xu, Shaojun & Deng, Tao & Ruan, Jiaqi & Qin, Changlei, 2024. "Techno-economic analysis on CO2 mitigation by integrated carbon capture and methanation," Applied Energy, Elsevier, vol. 355(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Cong-Xiao Wang & Hao-Xin Liu & Hao Gu & Jin-Ying Li & Xiao-Meng Lai & Xin-Pu Fu & Wei-Wei Wang & Qiang Fu & Feng Ryan Wang & Chao Ma & Chun-Jiang Jia, 2024. "Hydroxylated TiO2-induced high-density Ni clusters for breaking the activity-selectivity trade-off of CO2 hydrogenation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. D. F. Bruggeman & G. Rothenberg & A. C. Garcia, 2024. "Investigating proton shuttling and electrochemical mechanisms of amines in integrated CO2 capture and utilization," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Marti Checa & Addis S. Fuhr & Changhyo Sun & Rama Vasudevan & Maxim Ziatdinov & Ilia Ivanov & Seok Joon Yun & Kai Xiao & Alp Sehirlioglu & Yunseok Kim & Pankaj Sharma & Kyle P. Kelley & Neus Domingo &, 2023. "High-speed mapping of surface charge dynamics using sparse scanning Kelvin probe force microscopy," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Bian, Zhoufeng & Deng, Shaobi & Sun, Zhenkun & Ge, Tianshu & Jiang, Bo & Zhong, Wenqi, 2022. "Multi-core@Shell catalyst derived from LDH@SiO2 for low- temperature dry reforming of methane," Renewable Energy, Elsevier, vol. 200(C), pages 1362-1370.
    5. Zheng Chen & Zhangyun Liu & Xin Xu, 2023. "Dynamic evolution of the active center driven by hemilabile coordination in Cu/CeO2 single-atom catalyst," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    6. Lina Zhang & Shaolong Wan & Congcong Du & Qiang Wan & Hien Pham & Jiafei Zhao & Xingyu Ding & Diye Wei & Wei Zhao & Jiwei Li & Yanping Zheng & Hui Xie & Hua Zhang & Mingshu Chen & Kelvin H. L. Zhang &, 2024. "Generating active metal/oxide reverse interfaces through coordinated migration of single atoms," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    7. Yurou Celine Xiao & Siyu Sonia Sun & Yong Zhao & Rui Kai Miao & Mengyang Fan & Geonhui Lee & Yuanjun Chen & Christine M. Gabardo & Yan Yu & Chenyue Qiu & Zunmin Guo & Xinyue Wang & Panagiotis Papangel, 2024. "Reactive capture of CO2 via amino acid," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Xingyue Ma & Shuxuan Luo & Yunhui Hua & Seshadri Seetharaman & Xiaobo Zhu & Jingwei Hou & Lei Zhang & Wanlin Wang & Yongqi Sun, 2024. "An alumina phase induced composite transition shuttle to stabilize carbon capture cycles," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    9. Cornelius A. Obasanjo & Guorui Gao & Jackson Crane & Viktoria Golovanova & F. Pelayo García de Arquer & Cao-Thang Dinh, 2023. "High-rate and selective conversion of CO2 from aqueous solutions to hydrocarbons," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36646-2. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.