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Thermal influx induced biopolymeric transitions in paddy straw

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  • Durga, Mattaparthi Lakshmi
  • Gangil, Sandip
  • Bhargav, Vinod Kumar

Abstract

This is the first article highlighting the bio-polymeric transitions in individual intrinsic bio-constituents during pyrolytic thermal degradation of paddy straw through deconvolution of first order derivative of conversion profile. Non-isothermal slow pyrolysis of raw paddy straw was executed in a thermogravimetric analyzer at different heating rates (β = 10, 20 30 and 40 °C/min). Gaussian deconvolution technique was used to find individual signals related to each intrinsic biopolymers (hemicellulose, cellulose and lignin) in biomaterial. Different heating rates provided varied levels of heat influx to same biomaterial under same the environment which induced the different biopolymeric transitions in biomaterial. The multi-step mechanism was adopted to determine the kinetic triplets of paddy straw by using three different iso-conversional methods; OFW, KAS, and STM. The calculated activation energy from all three methods shows very negligible variations. From reaction mechanisms of three biopolymeric constituents, we established that thermal degradation of raw paddy straw underwent various complex reactions. This particular work found that all bioconsituents commonly followed the trends of diffusion model with no restriction of order of reaction.

Suggested Citation

  • Durga, Mattaparthi Lakshmi & Gangil, Sandip & Bhargav, Vinod Kumar, 2022. "Thermal influx induced biopolymeric transitions in paddy straw," Renewable Energy, Elsevier, vol. 199(C), pages 1024-1032.
    • Handle: RePEc:eee:renene:v:199:y:2022:i:c:p:1024-1032
    DOI: 10.1016/j.renene.2022.09.054
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    References listed on IDEAS

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    1. Gangil, Sandip, 2015. "Superiority of intrinsic biopolymeric constituents in briquettes of lignocellulosic crop residues over wood: A TG-diagnosis," Renewable Energy, Elsevier, vol. 76(C), pages 478-483.
    2. Tomasz Noszczyk & Arkadiusz Dyjakon & Jacek A. Koziel, 2021. "Kinetic Parameters of Nut Shells Pyrolysis," Energies, MDPI, vol. 14(3), pages 1-22, January.
    3. Gaurav Kumar Porichha & Yulin Hu & Kasanneni Tirumala Venkateswara Rao & Chunbao Charles Xu, 2021. "Crop Residue Management in India: Stubble Burning vs. Other Utilizations including Bioenergy," Energies, MDPI, vol. 14(14), pages 1-17, July.
    4. Gangil, Sandip, 2015. "Benefits of weakening in thermogravimetric signals of hemicellulose and lignin for producing briquettes from soybean crop residue," Energy, Elsevier, vol. 81(C), pages 729-737.
    5. Gangil, Sandip & Bhargav, Vinod Kumar, 2019. "Influences of binderless briquetting stresses on intrinsic bioconstituents of rice straw based solid biofuel," Renewable Energy, Elsevier, vol. 133(C), pages 462-469.
    6. Gangil, Sandip & Bhargav, Vinod Kumar, 2018. "Influence of torrefaction on intrinsic bioconstituents of cotton stalk: TG-insights," Energy, Elsevier, vol. 142(C), pages 1066-1073.
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    1. Sahu, Parmanand & Gangil, Sandip & Bhargav, Vinod Kumar, 2023. "Biopolymeric transitions under pyrolytic thermal degradation of Pigeon pea stalk," Renewable Energy, Elsevier, vol. 206(C), pages 157-167.
    2. Sahu, Parmanand & Gangil, Sandip, 2023. "Stepped pyrolysis: A novel approach for enhanced adsorbency and carbon in Pigeon pea stalk char," Renewable Energy, Elsevier, vol. 219(P2).

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