IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v142y2018icp1066-1073.html
   My bibliography  Save this article

Influence of torrefaction on intrinsic bioconstituents of cotton stalk: TG-insights

Author

Listed:
  • Gangil, Sandip
  • Bhargav, Vinod Kumar

Abstract

This is the first article presenting the detection of discrete and stratified nature of fringes in the lignin-related segment of the activation energy profile of a biomaterial. The torrefied biomaterial made from the cotton stalk was evaluated for intrinsic physico-chemical transformations in comparison with the raw cotton stalk. The intrinsic hemicellulose and cellulose components disappeared due to torrefaction process. Lignin was substantially noticed in torrefied biomaterial. Transitions of activation energy levels from raw to torrefied biomaterial were critically discussed and explained on the basis of Coats-Redfern kinetics. The patterned segregation of activation energy levels in the lignin degradation region, creating fringes like formations in activation energy profile, was noticed distinctly in the case of the torrefied biomaterial. These fringes were supposed to originate due to thermal stresses imposed on a biomaterial during the torrefaction process.

Suggested Citation

  • Gangil, Sandip & Bhargav, Vinod Kumar, 2018. "Influence of torrefaction on intrinsic bioconstituents of cotton stalk: TG-insights," Energy, Elsevier, vol. 142(C), pages 1066-1073.
    • Handle: RePEc:eee:energy:v:142:y:2018:i:c:p:1066-1073
    DOI: 10.1016/j.energy.2017.10.128
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217318339
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2017.10.128?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    2. Lu, Ke-Miao & Lee, Wen-Jhy & Chen, Wei-Hsin & Lin, Ta-Chang, 2013. "Thermogravimetric analysis and kinetics of co-pyrolysis of raw/torrefied wood and coal blends," Applied Energy, Elsevier, vol. 105(C), pages 57-65.
    3. Johansen, Joakim M. & Gadsbøll, Rasmus & Thomsen, Jesper & Jensen, Peter A. & Glarborg, Peter & Ek, Paul & De Martini, Nikolai & Mancini, Marco & Weber, Roman & Mitchell, Reginald E., 2016. "Devolatilization kinetics of woody biomass at short residence times and high heating rates and peak temperatures," Applied Energy, Elsevier, vol. 162(C), pages 245-256.
    4. Soponpongpipat, N. & Sae-Ueng, U., 2015. "The effect of biomass bulk arrangements on the decomposition pathways in the torrefaction process," Renewable Energy, Elsevier, vol. 81(C), pages 679-684.
    5. Bach, Quang-Vu & Skreiberg, Øyvind, 2016. "Upgrading biomass fuels via wet torrefaction: A review and comparison with dry torrefaction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 665-677.
    6. Gangil, Sandip, 2015. "Superiority of intrinsic biopolymeric constituents in briquettes of lignocellulosic crop residues over wood: A TG-diagnosis," Renewable Energy, Elsevier, vol. 76(C), pages 478-483.
    7. Kambo, Harpreet Singh & Dutta, Animesh, 2014. "Strength, storage, and combustion characteristics of densified lignocellulosic biomass produced via torrefaction and hydrothermal carbonization," Applied Energy, Elsevier, vol. 135(C), pages 182-191.
    8. Chai, Li & Saffron, Christopher M., 2016. "Comparing pelletization and torrefaction depots: Optimization of depot capacity and biomass moisture to determine the minimum production cost," Applied Energy, Elsevier, vol. 163(C), pages 387-395.
    9. Granados, D.A. & Velásquez, H.I. & Chejne, F., 2014. "Energetic and exergetic evaluation of residual biomass in a torrefaction process," Energy, Elsevier, vol. 74(C), pages 181-189.
    10. Gangil, Sandip, 2015. "Benefits of weakening in thermogravimetric signals of hemicellulose and lignin for producing briquettes from soybean crop residue," Energy, Elsevier, vol. 81(C), pages 729-737.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gangil, Sandip & Bhargav, Vinod Kumar, 2019. "Influences of binderless briquetting stresses on intrinsic bioconstituents of rice straw based solid biofuel," Renewable Energy, Elsevier, vol. 133(C), pages 462-469.
    2. Durga, Mattaparthi Lakshmi & Gangil, Sandip & Bhargav, Vinod Kumar, 2022. "Thermal influx induced biopolymeric transitions in paddy straw," Renewable Energy, Elsevier, vol. 199(C), pages 1024-1032.
    3. Jagadale, Manisha & Gangil, Sandip & Jadhav, Mahesh, 2023. "Enhancing fuel characteristics of jute sticks (Corchorus Sp.) using fixed bed torrefaction process," Renewable Energy, Elsevier, vol. 215(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Barskov, Stan & Zappi, Mark & Buchireddy, Prashanth & Dufreche, Stephen & Guillory, John & Gang, Daniel & Hernandez, Rafael & Bajpai, Rakesh & Baudier, Jeff & Cooper, Robbyn & Sharp, Richard, 2019. "Torrefaction of biomass: A review of production methods for biocoal from cultured and waste lignocellulosic feedstocks," Renewable Energy, Elsevier, vol. 142(C), pages 624-642.
    2. Wang, L. & Barta-Rajnai, E. & Skreiberg, Ø. & Khalil, R. & Czégény, Z. & Jakab, E. & Barta, Z. & Grønli, M., 2018. "Effect of torrefaction on physiochemical characteristics and grindability of stem wood, stump and bark," Applied Energy, Elsevier, vol. 227(C), pages 137-148.
    3. Gan, Yong Yang & Ong, Hwai Chyuan & Ling, Tau Chuan & Chen, Wei-Hsin & Chong, Cheng Tung, 2019. "Torrefaction of de-oiled Jatropha seed kernel biomass for solid fuel production," Energy, Elsevier, vol. 170(C), pages 367-374.
    4. Parkhurst, Kristen M. & Saffron, Christopher M. & Miller, Raymond O., 2016. "An energy analysis comparing biomass torrefaction in depots to wind with natural gas combustion for electricity generation," Applied Energy, Elsevier, vol. 179(C), pages 171-181.
    5. Jaime Martín-Pascual & Joaquín Jódar & Miguel L. Rodríguez & Montserrat Zamorano, 2020. "Determination of the Optimal Operative Conditions for the Torrefaction of Olive Waste Biomass," Sustainability, MDPI, vol. 12(16), pages 1-11, August.
    6. Leonel J. R. Nunes & Abel M. Rodrigues & João C. O. Matias & Ana I. Ferraz & Ana C. Rodrigues, 2021. "Production of Biochar from Vine Pruning: Waste Recovery in the Wine Industry," Agriculture, MDPI, vol. 11(6), pages 1-15, May.
    7. Akbari, Maryam & Oyedun, Adetoyese Olajire & Kumar, Amit, 2020. "Techno-economic assessment of wet and dry torrefaction of biomass feedstock," Energy, Elsevier, vol. 207(C).
    8. Gouws, S.M. & Carrier, M. & Bunt, J.R. & Neomagus, H.W.J.P., 2021. "Co-pyrolysis of coal and raw/torrefied biomass: A review on chemistry, kinetics and implementation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    9. Mostafa, Mohamed E. & Hu, Song & Wang, Yi & Su, Sheng & Hu, Xun & Elsayed, Saad A. & Xiang, Jun, 2019. "The significance of pelletization operating conditions: An analysis of physical and mechanical characteristics as well as energy consumption of biomass pellets," Renewable and Sustainable Energy Reviews, Elsevier, vol. 105(C), pages 332-348.
    10. Chen, Yun-Chun & Chen, Wei-Hsin & Lin, Bo-Jhih & Chang, Jo-Shu & Ong, Hwai Chyuan, 2016. "Impact of torrefaction on the composition, structure and reactivity of a microalga residue," Applied Energy, Elsevier, vol. 181(C), pages 110-119.
    11. Bach, Quang-Vu & Skreiberg, Øyvind & Lee, Chul-Jin, 2017. "Process modeling and optimization for torrefaction of forest residues," Energy, Elsevier, vol. 138(C), pages 348-354.
    12. Zhang, Congyu & Ho, Shih-Hsin & Chen, Wei-Hsin & Xie, Youping & Liu, Zhenquan & Chang, Jo-Shu, 2018. "Torrefaction performance and energy usage of biomass wastes and their correlations with torrefaction severity index," Applied Energy, Elsevier, vol. 220(C), pages 598-604.
    13. Granados, D.A. & Ruiz, R.A. & Vega, L.Y. & Chejne, F., 2017. "Study of reactivity reduction in sugarcane bagasse as consequence of a torrefaction process," Energy, Elsevier, vol. 139(C), pages 818-827.
    14. Adrian Knapczyk & Sławomir Francik & Marcin Jewiarz & Agnieszka Zawiślak & Renata Francik, 2020. "Thermal Treatment of Biomass: A Bibliometric Analysis—The Torrefaction Case," Energies, MDPI, vol. 14(1), pages 1-31, December.
    15. Ong, Hwai Chyuan & Yu, Kai Ling & Chen, Wei-Hsin & Pillejera, Ma Katreena & Bi, Xiaotao & Tran, Khanh-Quang & Pétrissans, Anelie & Pétrissans, Mathieu, 2021. "Variation of lignocellulosic biomass structure from torrefaction: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    16. Dimitrios K. Sidiras & Antonios G. Nazos & Georgios E. Giakoumakis & Dorothea V. Politi, 2020. "Simulating the Effect of Torrefaction on the Heating Value of Barley Straw," Energies, MDPI, vol. 13(3), pages 1-15, February.
    17. Zhang, Congyu & Chen, Wei-Hsin & Zhang, Ying & Ho, Shih-Hsin, 2023. "Influence of microorganisms on the variation of raw and oxidatively torrefied microalgal biomass properties," Energy, Elsevier, vol. 276(C).
    18. Chen, Wei-Hsin & Lin, Bo-Jhih & Colin, Baptiste & Chang, Jo-Shu & Pétrissans, Anélie & Bi, Xiaotao & Pétrissans, Mathieu, 2018. "Hygroscopic transformation of woody biomass torrefaction for carbon storage," Applied Energy, Elsevier, vol. 231(C), pages 768-776.
    19. Zhu, Youjian & Yang, Wei & Fan, Jiyuan & Kan, Tao & Zhang, Wennan & Liu, Heng & Cheng, Wei & Yang, Haiping & Wu, Xuehong & Chen, Hanping, 2018. "Effect of sodium carboxymethyl cellulose addition on particulate matter emissions during biomass pellet combustion," Applied Energy, Elsevier, vol. 230(C), pages 925-934.
    20. Reyes, Y.A. & Pérez, M. & Barrera, E.L. & Martínez, Y. & Cheng, K.K., 2022. "Thermochemical conversion processes of Dichrostachys cinerea as a biofuel: A review of the Cuban case," Renewable and Sustainable Energy Reviews, Elsevier, vol. 160(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:142:y:2018:i:c:p:1066-1073. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.