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Superiority of intrinsic biopolymeric constituents in briquettes of lignocellulosic crop residues over wood: A TG-diagnosis

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  • Gangil, Sandip

Abstract

The paper proves that briquettes of lignocellulosic crop residues have higher activation energy levels of intrinsic biopolymers as compared to these energy levels in wood, especially in context with the hemicellulosic and cellulosic segment. Binderless briquettes made of residues from pigeon pea and soybean crops were analyzed in comparison with wood. Thermal decompositions of these biofuels were experimented by thermogravimetry under pyrolysis environment and the transitions of the thermogravimetric signals were explained. Popular isoconversional kinetics method, namely integral Ozawa-Flynn-Wall was used to evaluate and compare the activation energies. Kinetics analyzed that wood was thermally weaker than the briquettes.

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  • Gangil, Sandip, 2015. "Superiority of intrinsic biopolymeric constituents in briquettes of lignocellulosic crop residues over wood: A TG-diagnosis," Renewable Energy, Elsevier, vol. 76(C), pages 478-483.
    • Handle: RePEc:eee:renene:v:76:y:2015:i:c:p:478-483
    DOI: 10.1016/j.renene.2014.11.071
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    References listed on IDEAS

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    1. Singh, R.N. & Vyas, D.K. & Srivastava, N.S.L. & Narra, Madhuri, 2008. "SPRERI experience on holistic approach to utilize all parts of Jatropha curcas fruit for energy," Renewable Energy, Elsevier, vol. 33(8), pages 1868-1873.
    2. Purohit, Pallav & Tripathi, Arun Kumar & Kandpal, Tara Chandra, 2006. "Energetics of coal substitution by briquettes of agricultural residues," Energy, Elsevier, vol. 31(8), pages 1321-1331.
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    1. Sahu, Parmanand & Gangil, Sandip & Bhargav, Vinod Kumar, 2023. "Biopolymeric transitions under pyrolytic thermal degradation of Pigeon pea stalk," Renewable Energy, Elsevier, vol. 206(C), pages 157-167.
    2. Sahu, Parmanand & Gangil, Sandip, 2023. "Stepped pyrolysis: A novel approach for enhanced adsorbency and carbon in Pigeon pea stalk char," Renewable Energy, Elsevier, vol. 219(P2).
    3. Gangil, Sandip & Bhargav, Vinod Kumar, 2019. "Influences of binderless briquetting stresses on intrinsic bioconstituents of rice straw based solid biofuel," Renewable Energy, Elsevier, vol. 133(C), pages 462-469.
    4. Gangil, Sandip & Bhargav, Vinod Kumar, 2018. "Influence of torrefaction on intrinsic bioconstituents of cotton stalk: TG-insights," Energy, Elsevier, vol. 142(C), pages 1066-1073.
    5. Durga, Mattaparthi Lakshmi & Gangil, Sandip & Bhargav, Vinod Kumar, 2022. "Thermal influx induced biopolymeric transitions in paddy straw," Renewable Energy, Elsevier, vol. 199(C), pages 1024-1032.
    6. Gangil, Sandip, 2015. "Benefits of weakening in thermogravimetric signals of hemicellulose and lignin for producing briquettes from soybean crop residue," Energy, Elsevier, vol. 81(C), pages 729-737.

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