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Simulation and economic evaluation of fuel additives production from glycerol

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  • Ribeiro, Mariana B.
  • Cavalcante, Raquel M.
  • Young, André F.

Abstract

Biodiesel production continuously increases. This also increases the production of glycerol, the main by-product of transesterification, whose surplus is not fully absorbed by the market. An interesting destination for glycerol is the production of additives for the biofuel itself, as a green and economical alternative to conventional additives. The objective of this work is to simulate the production processes of three oxygenated fuel additives from the glycerol that is generated in the biodiesel production process: solketal, glycerol tert-butyl ethers (GTBE) and glycerol ethyl ethers (GEE). The processes were simulated in Aspen HYSYS® v8.8 and the capital and production costs were estimated. Among the evaluated alternatives, solketal production showed to be the most promising, since it is simpler than those of the other products and it works with acetone, which is cheaper than tert-butanol - required for GTBE production - and is needed in lower flowrates than ethanol - required for GEE production.

Suggested Citation

  • Ribeiro, Mariana B. & Cavalcante, Raquel M. & Young, André F., 2022. "Simulation and economic evaluation of fuel additives production from glycerol," Renewable Energy, Elsevier, vol. 181(C), pages 1081-1099.
    • Handle: RePEc:eee:renene:v:181:y:2022:i:c:p:1081-1099
    DOI: 10.1016/j.renene.2021.09.123
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    References listed on IDEAS

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    1. Nanda, Malaya R. & Yuan, Zhongshun & Qin, Wensheng & Ghaziaskar, Hassan S. & Poirier, Marc-Andre & Xu, Chunbao (Charles), 2014. "A new continuous-flow process for catalytic conversion of glycerol to oxygenated fuel additive: Catalyst screening," Applied Energy, Elsevier, vol. 123(C), pages 75-81.
    2. Barreiros, Thaís & Young, André & Cavalcante, Raquel & Queiroz, Eduardo, 2020. "Impact of biodiesel production on a soybean biorefinery," Renewable Energy, Elsevier, vol. 159(C), pages 1066-1083.
    3. Cornejo, A. & Barrio, I. & Campoy, M. & Lázaro, J. & Navarrete, B., 2017. "Oxygenated fuel additives from glycerol valorization. Main production pathways and effects on fuel properties and engine performance: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1400-1413.
    4. Jiménez, Roberto X. & Young, André F. & Fernandes, Heloisa L.S., 2020. "Propylene glycol from glycerol: Process evaluation and break-even price determination," Renewable Energy, Elsevier, vol. 158(C), pages 181-191.
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    Cited by:

    1. Liu, Haiyang & Ma, Zhen & Liu, Xueli & Wu, Yuan & Zhang, Weihong & Zhao, Shiqiang & Chen, Wei & Chang, Chun, 2024. "Green synthesis of biobased glycerol levulinate ketal in a continuous flow reactor: Optimization, kinetics and simulation," Applied Energy, Elsevier, vol. 361(C).
    2. Vannucci, Julián A. & Gatti, Martín N. & Cardaci, Nicolas & Nichio, Nora N., 2022. "Economic feasibility of a solketal production process from glycerol at small industrial scale," Renewable Energy, Elsevier, vol. 190(C), pages 540-547.
    3. Yadav, Nidhi & Yadav, Gaurav & Ahmaruzzaman, Md., 2024. "Camellia sinensis leaf-assisted green synthesis of SO3H-functionalized ZnS/biochar nanocatalyst for highly selective solketal production and improved reusability in methylene blue dye adsorption," Renewable Energy, Elsevier, vol. 224(C).

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