IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v209y2023icp145-156.html
   My bibliography  Save this article

A new method for conversion of fructose and glucose to 5-hydroxymethylfurfural by magnetic mesoporous of SBA-16 was modified to sulfonic acid as Lewis's acid catalysts

Author

Listed:
  • Yang, Xiaoxun
  • Sadughi, Mohammad Mehdi
  • Bahadoran, Ashkan
  • Al-Haideri, Maysoon
  • Ghamari Kargar, Pouya
  • Noori, Aiyah S.
  • Sajjadinezhad, Seyed Mehrzad

Abstract

The sustainable process and direct synthesis of 5-hydroxymethylfurfural (5-HMF), a valuable renewable biofuel and biochemical, was systematically studied using inexpensive catalysts and recyclable magnetic nanocatalysts. Fe3O4@SBA-16-SO3H was obtained by the synthesis of SBA-16 and was modified by MPTES and H2O2. After that, Fe3O4 was synthesized via chemical precipitation and mixed with SBA-16-SO3H for easy separation and recovery (using five cycles of catalysts with excellent yield for the synthesis of 5-HMF) and a new magnetic heterogeneous catalyst for the synthesis of 5-HMF that was found to have 95% glucose and fructose conversion and 97% yield of 5-HMF, respectively. The prepared catalyst was characterized by FT-IR, EDAX, XRD, FE-SEM, TEM, VSM, BET, and TGA techniques. The experiments were carried out with good yields and implied that the catalytic method was effective, convenient, and promising for the synthesis of 5-HMF. The present study opens a new avenue for the renewable one-pot synthesis of 5-HMF, a precious product. The efficient conversion of biomass into value-added compounds under mild and safer conditions is a cornerstone of our current research efforts to meet the needs of the chemical industry with sustainable development.

Suggested Citation

  • Yang, Xiaoxun & Sadughi, Mohammad Mehdi & Bahadoran, Ashkan & Al-Haideri, Maysoon & Ghamari Kargar, Pouya & Noori, Aiyah S. & Sajjadinezhad, Seyed Mehrzad, 2023. "A new method for conversion of fructose and glucose to 5-hydroxymethylfurfural by magnetic mesoporous of SBA-16 was modified to sulfonic acid as Lewis's acid catalysts," Renewable Energy, Elsevier, vol. 209(C), pages 145-156.
    • Handle: RePEc:eee:renene:v:209:y:2023:i:c:p:145-156
    DOI: 10.1016/j.renene.2023.03.102
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148123004056
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2023.03.102?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Karimi, Sabah & Seidi, Farzad & Niakan, Mahsa & Shekaari, Hemayat & Masteri-Farahani, Majid, 2021. "Catalytic dehydration of fructose into 5-hydroxymethylfurfural by propyl sulfonic acid functionalized magnetic graphene oxide nanocomposite," Renewable Energy, Elsevier, vol. 180(C), pages 132-139.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Dowaki, Taishi & Guo, Haixin & Smith, Richard Lee, 2022. "Lignin-derived biochar solid acid catalyst for fructose conversion into 5-ethoxymethylfurfural," Renewable Energy, Elsevier, vol. 199(C), pages 1534-1542.
    2. Niakan, Mahsa & Masteri-Farahani, Majid & Seidi, Farzad, 2023. "Sulfonated ionic liquid immobilized SBA-16 as an active solid acid catalyst for the synthesis of biofuel precursor 5-hydroxymethylfurfural from fructose," Renewable Energy, Elsevier, vol. 212(C), pages 50-56.
    3. Wang, Shuai & Eberhardt, Thomas L. & Guo, Dayi & Feng, Junfeng & Pan, Hui, 2022. "Efficient conversion of glucose into 5-HMF catalyzed by lignin-derived mesoporous carbon solid acid in a biphasic system," Renewable Energy, Elsevier, vol. 190(C), pages 1-10.
    4. Shi, Xian & Xing, Xinyi & Liu, Wanni & Ruan, Mengya & Guan, Ying & Lyu, Gaojin & Gao, Hui & Xu, Siquan, 2024. "Cellulose conversion to 5-hydroxymethylfurfural via a simple and efficient phosphate-doped hafnium oxide catalyst," Renewable Energy, Elsevier, vol. 226(C).
    5. Cai, Bo & Kang, Rui & Guo, Dayi & Feng, Junfeng & Ma, Tianyi & Pan, Hui, 2022. "An eco-friendly acidic catalyst phosphorus-doped graphitic carbon nitride for efficient conversion of fructose to 5-Hydroxymethylfurfural," Renewable Energy, Elsevier, vol. 199(C), pages 1629-1638.
    6. Feng, Weiliang & Tie, Xinlong & Duan, Xiaoling & Yan, Su & Fang, Si & Sun, Peiyong & Gan, Lin & Wang, Tielin, 2023. "Covalent immobilization of phosphotungstic acid and amino acid on metal-organic frameworks with different structures: Acid-base bifunctional heterogeneous catalyst for the production of biodiesel from," Renewable Energy, Elsevier, vol. 210(C), pages 26-39.
    7. Niakan, Mahsa & Masteri-Farahani, Majid & Seidi, Farzad, 2022. "Efficient glucose-to-HMF conversion in deep eutectic solvents over sulfonated dendrimer modified activated carbon," Renewable Energy, Elsevier, vol. 200(C), pages 1134-1140.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:209:y:2023:i:c:p:145-156. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.