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A new method for conversion of fructose and glucose to 5-hydroxymethylfurfural by magnetic mesoporous of SBA-16 was modified to sulfonic acid as Lewis's acid catalysts

Author

Listed:
  • Yang, Xiaoxun
  • Sadughi, Mohammad Mehdi
  • Bahadoran, Ashkan
  • Al-Haideri, Maysoon
  • Ghamari Kargar, Pouya
  • Noori, Aiyah S.
  • Sajjadinezhad, Seyed Mehrzad

Abstract

The sustainable process and direct synthesis of 5-hydroxymethylfurfural (5-HMF), a valuable renewable biofuel and biochemical, was systematically studied using inexpensive catalysts and recyclable magnetic nanocatalysts. Fe3O4@SBA-16-SO3H was obtained by the synthesis of SBA-16 and was modified by MPTES and H2O2. After that, Fe3O4 was synthesized via chemical precipitation and mixed with SBA-16-SO3H for easy separation and recovery (using five cycles of catalysts with excellent yield for the synthesis of 5-HMF) and a new magnetic heterogeneous catalyst for the synthesis of 5-HMF that was found to have 95% glucose and fructose conversion and 97% yield of 5-HMF, respectively. The prepared catalyst was characterized by FT-IR, EDAX, XRD, FE-SEM, TEM, VSM, BET, and TGA techniques. The experiments were carried out with good yields and implied that the catalytic method was effective, convenient, and promising for the synthesis of 5-HMF. The present study opens a new avenue for the renewable one-pot synthesis of 5-HMF, a precious product. The efficient conversion of biomass into value-added compounds under mild and safer conditions is a cornerstone of our current research efforts to meet the needs of the chemical industry with sustainable development.

Suggested Citation

  • Yang, Xiaoxun & Sadughi, Mohammad Mehdi & Bahadoran, Ashkan & Al-Haideri, Maysoon & Ghamari Kargar, Pouya & Noori, Aiyah S. & Sajjadinezhad, Seyed Mehrzad, 2023. "A new method for conversion of fructose and glucose to 5-hydroxymethylfurfural by magnetic mesoporous of SBA-16 was modified to sulfonic acid as Lewis's acid catalysts," Renewable Energy, Elsevier, vol. 209(C), pages 145-156.
    • Handle: RePEc:eee:renene:v:209:y:2023:i:c:p:145-156
    DOI: 10.1016/j.renene.2023.03.102
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    References listed on IDEAS

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    1. Karimi, Sabah & Seidi, Farzad & Niakan, Mahsa & Shekaari, Hemayat & Masteri-Farahani, Majid, 2021. "Catalytic dehydration of fructose into 5-hydroxymethylfurfural by propyl sulfonic acid functionalized magnetic graphene oxide nanocomposite," Renewable Energy, Elsevier, vol. 180(C), pages 132-139.
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