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Cellulose conversion to 5-hydroxymethylfurfural via a simple and efficient phosphate-doped hafnium oxide catalyst

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  • Shi, Xian
  • Xing, Xinyi
  • Liu, Wanni
  • Ruan, Mengya
  • Guan, Ying
  • Lyu, Gaojin
  • Gao, Hui
  • Xu, Siquan

Abstract

The efficient catalytic conversion of cellulose to 5-hydroxymethylfurfural (HMF) can provide a valuable reference for the high-value utilization of biomass. In this work, a series of simple phosphate-doped hafnium oxide catalysts (x-P-HfO2) were prepared, and their physicochemical properties were analyzed by ICP-OES, XRD, XPS, FTIR, SEM-EDX, N2 adsorption-desorption isotherms, NH3-TPD and Py-FTIR characterizes. Detailed evaluation of the reaction conditions demonstrated the ideal catalytic performance of the x-P-HfO2 catalysts, and the HMF yield from cellulose reached a satisfactory 61% in the water(NaCl)/tetrahydrofuran biphasic reaction system. Based on the captured intermediates and detected by-products, possible catalytic pathways are summarized. Meanwhile, the hydrothermal stability of the catalyst was also investigated, and the reason for its performance degradation after five cycles was determined to be the loss of useful Brønsted active sites. In addition, the effects of the phosphating and sulfating modification approaches on the catalyst activity were also compared, verifying that the introduction of phosphate is more conducive to the catalyst expressing high activity for the formation of HMF from cellulose.

Suggested Citation

  • Shi, Xian & Xing, Xinyi & Liu, Wanni & Ruan, Mengya & Guan, Ying & Lyu, Gaojin & Gao, Hui & Xu, Siquan, 2024. "Cellulose conversion to 5-hydroxymethylfurfural via a simple and efficient phosphate-doped hafnium oxide catalyst," Renewable Energy, Elsevier, vol. 226(C).
  • Handle: RePEc:eee:renene:v:226:y:2024:i:c:s0960148124004907
    DOI: 10.1016/j.renene.2024.120425
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    References listed on IDEAS

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    1. Karimi, Sabah & Seidi, Farzad & Niakan, Mahsa & Shekaari, Hemayat & Masteri-Farahani, Majid, 2021. "Catalytic dehydration of fructose into 5-hydroxymethylfurfural by propyl sulfonic acid functionalized magnetic graphene oxide nanocomposite," Renewable Energy, Elsevier, vol. 180(C), pages 132-139.
    2. Cai, Bo & Kang, Rui & Guo, Dayi & Feng, Junfeng & Ma, Tianyi & Pan, Hui, 2022. "An eco-friendly acidic catalyst phosphorus-doped graphitic carbon nitride for efficient conversion of fructose to 5-Hydroxymethylfurfural," Renewable Energy, Elsevier, vol. 199(C), pages 1629-1638.
    3. Fang, Juan & Dong, Hao & Xu, Haimei, 2023. "The effect of Lewis acidity of tin loading siliceous MCM-41 on glucose conversion into 5-hydroxymethylfurfural," Renewable Energy, Elsevier, vol. 218(C).
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    Cited by:

    1. Du, Ya-Peng & Tian, Xin-Yu & Zheng, Xiao-Ping & Chai, Yu & Zhang, Yu-Cang & Zheng, Yan-Zhen, 2024. "Efficient preparation of 5-hydroxymethylfurfural from cellulose via one-step combination of mechanical and chemical pre-treatment," Renewable Energy, Elsevier, vol. 229(C).

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