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Transesterification of Litsea cubeba kernel oil to biodiesel over zinc supported on zirconia heterogeneous catalysts

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  • Li, Dongming
  • Feng, Wenping
  • Chen, Chao
  • Chen, Shangxing
  • Fan, Guorong
  • Liao, Shengliang
  • Wu, Guoqiang
  • Wang, Zongde

Abstract

An effective approach for synthesizing green and sustainable biodiesel fuel from low-value vegetable oils has been explored. Herein, a series of catalysts of zinc supported on zirconia (xZn/ZrO2) were successfully synthesized, characterized, and applied for the production of biodiesel from Litsea cubeba kernel oil (LCKO) through the transesterification process. The results showed that the monoclinic phase structure of the prepared catalysts transformed to the more stable tetragonal phase structure after supporting different Zn loadings (≥5%). Compared with the pure ZrO2, the highly dispersed Zn species on the surface of xZn/ZrO2 could be divided into Zn oxide and ZnOH+, which could promote the transesterification of LCKO. Thus, the 7%Zn/ZrO2 catalyst exhibited the best catalytic activity of the LCKO conversion 82.5%, which was attributed to the positive effects of both the ZrO2 support and Zn species. Furthermore, the various reaction parameters (such as reaction time, stirring rate, nCH3OH:nLCKO, catalyst amount, and reaction temperature) were investigated systematically and optimized carefully. And a possible mechanism of the transesterification process catalyzed by Zn/ZrO2 catalysts was also proposed. Finally, the physical properties of the as-synthesized biodiesel accorded with the current international biodiesel standards.

Suggested Citation

  • Li, Dongming & Feng, Wenping & Chen, Chao & Chen, Shangxing & Fan, Guorong & Liao, Shengliang & Wu, Guoqiang & Wang, Zongde, 2021. "Transesterification of Litsea cubeba kernel oil to biodiesel over zinc supported on zirconia heterogeneous catalysts," Renewable Energy, Elsevier, vol. 177(C), pages 13-22.
    • Handle: RePEc:eee:renene:v:177:y:2021:i:c:p:13-22
    DOI: 10.1016/j.renene.2021.05.129
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    2. Ebadinezhad, Behzad & Haghighi, Mohammad & Zeinalzadeh, Hossein, 2022. "Carbon-templated meso-design of nanostructured CeAPSO-34 for biodiesel production from free fatty acid and waste oil," Renewable Energy, Elsevier, vol. 195(C), pages 716-733.
    3. Wang, Quan & Wenlei Xie, & Guo, Lihong, 2022. "Molybdenum and zirconium oxides supported on KIT-6 silica: A recyclable composite catalyst for one–pot biodiesel production from simulated low-quality oils," Renewable Energy, Elsevier, vol. 187(C), pages 907-922.
    4. Ramoon Barros Lovate Temporim & Gianluca Cavalaglio & Alessandro Petrozzi & Valentina Coccia & Franco Cotana & Andrea Nicolini, 2022. "Life Cycle Assessment of Cynara cardunculus L. -Based Polygeneration and Biodiesel Chains," Sustainability, MDPI, vol. 14(21), pages 1-19, October.
    5. Wong, Wan-Ying & Lim, Steven & Pang, Yean-Ling & Shuit, Siew-Hoong & Lam, Man-Kee & Tan, Inn-Shi & Chen, Wei-Hsin, 2023. "A comprehensive review of the production methods and effect of parameters for glycerol-free biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    6. Tuti Suryati & Euis Julaeha & Kindi Farabi & Hanies Ambarsari & Ace Tatang Hidayat, 2023. "Lauric Acid from the Black Soldier Fly ( Hermetia illucens ) and Its Potential Applications," Sustainability, MDPI, vol. 15(13), pages 1-28, June.

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