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Rice bran oil based biodiesel production using calcium oxide catalyst derived from Chicoreus brunneus shell

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  • Mazaheri, Hoora
  • Ong, Hwai Chyuan
  • Masjuki, H.H.
  • Amini, Zeynab
  • Harrison, Mark D.
  • Wang, Chin-Tsan
  • Kusumo, Fitranto
  • Alwi, Azham

Abstract

Environmental pollution and the declining global supply of accessible fossil fuels are the key drivers of the search for alternative sources of energy. Biodiesel, a renewable liquid transport fuel, is commercially-produced using heterogeneous catalysts. Heterogeneous catalysts obtained from seashells appeared as promising alternatives thanks to their low preparation cost and increased efficiency in transesterification. In this study, shells from Chicoreus brunneus (known as Adusta murex) were calcined, hydrated, and dehydrated to produce CaO heterogeneous nanocatalyst for the transesterification of rice bran oil into biodiesel. Field emission scanning electron microscopy, Fourier transform infrared spectroscopy, transmission electron microscopy, surface area measurement (Brunauer-Emmett-Teller method), and X-ray diffraction were used to characterise the seashell-derived catalyst. The properties of the rice bran oil-derived biodiesel (acid value, calorific value, density, oxidation stability, and flash point) conformed to the American Society of Testing and Materials (ASTM) D6751 and European EN 14214 biodiesel standards, except for kinematic viscosity. Therefore, the impact of the parameters used for production of the CaO heterogeneous nanocatalyst (calcination temperature and time) and the transesterification reaction (catalyst loading and methanol to rice bran oil ratio) on the kinematic viscosity of RBO-derived biodiesel were determined. A model for the transesterification process was developed using a combination of artificial neural networking with ant colony optimisation. The model predicted that C. brunneus-derived CaO catalyst prepared at 1100 °C for 72 min could be used to produce biodiesel from rice bran oil with a minimum kinematic viscosity (4.42 mm2 s−1) confirming to both the ASTM D6751 and EN 14214 biodiesel standards in a transesterification reaction operating with a 35:1 methanol to rice bran oil molar ratio and 0.5 wt% catalyst mass.

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  • Mazaheri, Hoora & Ong, Hwai Chyuan & Masjuki, H.H. & Amini, Zeynab & Harrison, Mark D. & Wang, Chin-Tsan & Kusumo, Fitranto & Alwi, Azham, 2018. "Rice bran oil based biodiesel production using calcium oxide catalyst derived from Chicoreus brunneus shell," Energy, Elsevier, vol. 144(C), pages 10-19.
    • Handle: RePEc:eee:energy:v:144:y:2018:i:c:p:10-19
    DOI: 10.1016/j.energy.2017.11.073
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    12. Zik, N.A.F.A. & Sulaiman, S. & Jamal, P., 2020. "Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor," Renewable Energy, Elsevier, vol. 155(C), pages 267-277.
    13. Gülüm, Mert & Onay, Funda Kutlu & Bilgin, Atilla, 2018. "Comparison of viscosity prediction capabilities of regression models and artificial neural networks," Energy, Elsevier, vol. 161(C), pages 361-369.
    14. Hoora Mazaheri & Hwai Chyuan Ong & Zeynab Amini & Haji Hassan Masjuki & M. Mofijur & Chia Hung Su & Irfan Anjum Badruddin & T.M. Yunus Khan, 2021. "An Overview of Biodiesel Production via Calcium Oxide Based Catalysts: Current State and Perspective," Energies, MDPI, vol. 14(13), pages 1-23, July.
    15. Hoang, Anh Tuan & Tabatabaei, Meisam & Aghbashlo, Mortaza & Carlucci, Antonio Paolo & Ölçer, Aykut I. & Le, Anh Tuan & Ghassemi, Abbas, 2021. "Rice bran oil-based biodiesel as a promising renewable fuel alternative to petrodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
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    17. Li, Dongming & Feng, Wenping & Chen, Chao & Chen, Shangxing & Fan, Guorong & Liao, Shengliang & Wu, Guoqiang & Wang, Zongde, 2021. "Transesterification of Litsea cubeba kernel oil to biodiesel over zinc supported on zirconia heterogeneous catalysts," Renewable Energy, Elsevier, vol. 177(C), pages 13-22.
    18. Goh, Brandon Han Hoe & Ong, Hwai Chyuan & Cheah, Mei Yee & Chen, Wei-Hsin & Yu, Kai Ling & Mahlia, Teuku Meurah Indra, 2019. "Sustainability of direct biodiesel synthesis from microalgae biomass: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 59-74.
    19. Lourenço, Vitor Alves & Nadaleti, Willian Cézar & Vieira, Bruno Müller & Li, Hu, 2021. "Investigation of ethyl biodiesel via transesterification of rice bran oil: bioenergy from residual biomass in Pelotas, Rio Grande do Sul - Brazil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    20. Hwai Chyuan Ong & M. Mofijur & A.S. Silitonga & D. Gumilang & Fitranto Kusumo & T.M.I. Mahlia, 2020. "Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm Oils," Energies, MDPI, vol. 13(6), pages 1-14, March.
    21. Balajii, Muthusamy & Niju, Subramaniapillai, 2020. "Banana peduncle – A green and renewable heterogeneous base catalyst for biodiesel production from Ceiba pentandra oil," Renewable Energy, Elsevier, vol. 146(C), pages 2255-2269.
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