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Lipase-PDA-TiO2 NPs: An emphatic nano-biocatalyst for optimized biodiesel production from Jatropha curcas oil

Author

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  • Zulfiqar, Anam
  • Mumtaz, Muhammad Waseem
  • Mukhtar, Hamid
  • Najeeb, Jawayria
  • Irfan, Ahmad
  • Akram, Sadia
  • Touqeer, Tooba
  • Nabi, Ghulam

Abstract

Current study was designed for developing the novel nano-biocatalyst (Lipase-PDA-TiO2 NPs) for enzymatic transesterification of Jatropha curcas seed oil (JCSO). The TiO2 NPs were prepared by the hydrothermal method and were afterward modified by the polydopamine (PDA) polymer. The synthesized nanomaterial was characterized by SEM, FTIR, XRD and energy dispersive X-ray spectroscopy. Lipase activity assay was used to check the stability of immobilized enzyme under varying conditions of pH and temperature. Transesterification of JCSO using Lipase-PDA-TiO2 NPs catalyst was optimized by response surface methodology (RSM). Optimum biodiesel yield (92%) was achieved by carrying out the transesterification process for 30 h at 37 °C temperature with 10% nano-biocatalyst concentration, 6:1 methanol:oil ratio and 0.5% water content. On the basis of model significance, R2 value, lack of fit test and predicted vs. actual values, quadratic model was selected as the best fitted model. The FTIR technique was utilized to monitor the transesterification process. The comparison of the physiochemical characteristics of the synthesized biodiesel with the international standard for bio-fuel affirms that the transesterification of JCSO in the presence of the nano-biocatalyst provides an effective alternative for the production of biodiesel.

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  • Zulfiqar, Anam & Mumtaz, Muhammad Waseem & Mukhtar, Hamid & Najeeb, Jawayria & Irfan, Ahmad & Akram, Sadia & Touqeer, Tooba & Nabi, Ghulam, 2021. "Lipase-PDA-TiO2 NPs: An emphatic nano-biocatalyst for optimized biodiesel production from Jatropha curcas oil," Renewable Energy, Elsevier, vol. 169(C), pages 1026-1037.
    • Handle: RePEc:eee:renene:v:169:y:2021:i:c:p:1026-1037
    DOI: 10.1016/j.renene.2020.12.135
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    References listed on IDEAS

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    1. Migle Santaraite & Egle Sendzikiene & Violeta Makareviciene & Kiril Kazancev, 2020. "Biodiesel Production by Lipase-Catalyzed in Situ Transesterification of Rapeseed Oil Containing a High Free Fatty Acid Content with Ethanol in Diesel Fuel Media," Energies, MDPI, vol. 13(10), pages 1-12, May.
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    5. Balajii, Muthusamy & Niju, Subramaniapillai, 2020. "Banana peduncle – A green and renewable heterogeneous base catalyst for biodiesel production from Ceiba pentandra oil," Renewable Energy, Elsevier, vol. 146(C), pages 2255-2269.
    6. Zik, N.A.F.A. & Sulaiman, S. & Jamal, P., 2020. "Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor," Renewable Energy, Elsevier, vol. 155(C), pages 267-277.
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    3. Panchal, Balaji & Zhu, Zheng & Qin, Shenjun & Chang, Tao & Zhao, Qiaojing & Sun, Yuzhuang & Zhao, Cunliang & Wang, Jinxi & Bian, Kai & Rankhamb, Santosh, 2022. "The current state applications of ethyl carbonate with ionic liquid in sustainable biodiesel production: A review," Renewable Energy, Elsevier, vol. 181(C), pages 341-354.
    4. Wancura, João H.C. & Brondani, Michel & dos Santos, Maicon S.N. & Oro, Carolina E.D. & Wancura, Guilherme C. & Tres, Marcus V. & Oliveira, J. Vladimir, 2023. "Demystifying the enzymatic biodiesel: How lipases are contributing to its technological advances," Renewable Energy, Elsevier, vol. 216(C).

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