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Direct epitaxial synthesis of magnetic biomass derived acid/base bifunctional zirconium-based hybrid for catalytic transfer hydrogenation of ethyl levulinate into γ-valerolactone

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  • Wang, Yue
  • Liu, Huai
  • Zhang, Junhua
  • Cheng, Yuan
  • Lin, Wansi
  • Huang, Rulu
  • Peng, Lincai

Abstract

The development of efficient and reusable catalysts to improve the catalytic transfer hydrogenation (CTH) of biomass-derived platform molecules into high value-added chemicals is always desired. For this purpose, the magnetic Fe3O4@Zr-FDCA hybrid with Lewis acid and Lewis base sites was first designed by simple assembly of biomass derived 2,5-furandicarboxylic acid (FDCA) with zirconium and grown directly on the surface of carboxylated Fe3O4. The resulting Fe3O4@Zr-FDCA exhibited a unique core-shell structure with high specific surface area and proper acid/basic strength, it performed well in CTH reaction of diverse carbonyl compounds, especially for the conversion of ethyl levulinate to γ-valerolactone with the yield of 94.5% at 180 °C for 5 h. Furthermore, the good magnetic responsibility of Fe3O4@Zr-FDCA made it could be easily separated from the reaction mixture by an external magnet, and displayed a good reusability with no significant loss in the activity after reuse for five runs.

Suggested Citation

  • Wang, Yue & Liu, Huai & Zhang, Junhua & Cheng, Yuan & Lin, Wansi & Huang, Rulu & Peng, Lincai, 2022. "Direct epitaxial synthesis of magnetic biomass derived acid/base bifunctional zirconium-based hybrid for catalytic transfer hydrogenation of ethyl levulinate into γ-valerolactone," Renewable Energy, Elsevier, vol. 197(C), pages 911-921.
    • Handle: RePEc:eee:renene:v:197:y:2022:i:c:p:911-921
    DOI: 10.1016/j.renene.2022.07.158
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    References listed on IDEAS

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