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NiCo–N-doped carbon nanotubes based cathode catalyst for alkaline membrane fuel cell

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  • Hanif, Saadia
  • Iqbal, Naseem
  • Shi, Xuan
  • Noor, Tayyaba
  • Ali, Ghulam
  • Kannan, A.M.

Abstract

For alkaline fuel cell, development of highly efficient catalysts based on non-noble metal for oxygen reduction reaction is of high significance. In this work, synthesis of nitrogen doped carbon nanotubes (NCNTs) derived from Zeolitic Imidazolate Frameworks (ZIFs) and their performance for oxygen reduction reaction (ORR) in alkaline medium are studied. The NiCo/NCNTs (nitrogen doped carbon nanotubes) showing excellent ORR performance in KOH with current density of −5.6 mA cm−2 and onset potential of 0.98 V vs RHE. The improved electrochemical performance and stability is credited to the synergetic effect of the nitrogen doped carbon nanotubes (NCNTs) and the Ni/Co active sites. The alkaline fuel cell performance of NiCo/NCNTs as cathode catalyst was 65 mW cm−2, which is slightly higher than the commercial Pt/C as cathode (60 mW cm−2). These results indicate that NiCo/NCNTs are promising electrocatalysts for ORR in alkaline fuel cell.

Suggested Citation

  • Hanif, Saadia & Iqbal, Naseem & Shi, Xuan & Noor, Tayyaba & Ali, Ghulam & Kannan, A.M., 2020. "NiCo–N-doped carbon nanotubes based cathode catalyst for alkaline membrane fuel cell," Renewable Energy, Elsevier, vol. 154(C), pages 508-516.
    • Handle: RePEc:eee:renene:v:154:y:2020:i:c:p:508-516
    DOI: 10.1016/j.renene.2020.03.060
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    References listed on IDEAS

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    1. Mark K. Debe, 2012. "Electrocatalyst approaches and challenges for automotive fuel cells," Nature, Nature, vol. 486(7401), pages 43-51, June.
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    1. Han, Juan & Deng, Ximing & Chen, Keyu & Imhanria, Sarah & Sun, Yan & Wang, Wei, 2021. "Electrochemical conversion of CO2 into tunable syngas on a B, P, N tri-doped carbon," Renewable Energy, Elsevier, vol. 177(C), pages 636-642.
    2. Wenzhe Luo & Longsheng Cao & Ming Hou & Liang He & Yawen Zhou & Feng Xie & Zhigang Shao, 2022. "Nanofiber-Based Oxygen Reduction Electrocatalysts with Improved Mass Transfer Kinetics in a Meso-Porous Structure and Enhanced Reaction Kinetics by Confined Fe and Fe 3 C Particles for Anion-Exchange ," Energies, MDPI, vol. 15(11), pages 1-15, May.
    3. El-Nowihy, Ghada H. & El-Deab, Mohamed S., 2021. "Smart selection of fuel blends: Robust oxidation of formic acid in its blend with urea at NiOx/Pd nanoparticles-based binary anodes," Renewable Energy, Elsevier, vol. 167(C), pages 830-840.

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