IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v160y2020icp1168-1173.html
   My bibliography  Save this article

Construction of Ti3C2 supported hybrid Co3O4/NCNTs composite as an efficient oxygen reduction electrocatalyst

Author

Listed:
  • Liu, Jing
  • Mi, Liwei
  • Xing, Yanan
  • Wang, Tianfu
  • Wang, Fu

Abstract

Developing high performance non-Pt oxygen reduction reaction (ORR) electrocatalysts is vital for the practical applications of fuel cell but it still remains a grand challenge. Herein, an in-situ pyrolysis strategy was explored to prepare hybrid Co3O4/N-doped carbon nanotubes catalyst supported on the surface of Ti3C2 (Co3O4/NCNTs/Ti3C2). Owing to the synergistic effects of constituent components, as-prepared Co3O4/NCNTs/Ti3C2 exhibited superior ORR activity (diffusion limited current 5.41 mA cm−2 and half-wave potential 0.79 V) to the commercial Pt/C (diffusion limited current 5.14 mA cm−2 and half-wave potential 0.78 V). Meanwhile, the Co3O4/NCNTs/Ti3C2 catalyst demonstrated moderately good stability. Compared with the loss of current (∼54%) of commercial Pt/C, 48% current decrease was observed for Co3O4/NCNTs/Ti3C2 after the chronoamperometric measurement for 6 × 103 s. In view of the enhanced activity and stability, Co3O4/NCNTs/Ti3C2 holds high potential as a practical ORR electrocatalyst.

Suggested Citation

  • Liu, Jing & Mi, Liwei & Xing, Yanan & Wang, Tianfu & Wang, Fu, 2020. "Construction of Ti3C2 supported hybrid Co3O4/NCNTs composite as an efficient oxygen reduction electrocatalyst," Renewable Energy, Elsevier, vol. 160(C), pages 1168-1173.
    • Handle: RePEc:eee:renene:v:160:y:2020:i:c:p:1168-1173
    DOI: 10.1016/j.renene.2020.07.059
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120311356
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.07.059?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Mark K. Debe, 2012. "Electrocatalyst approaches and challenges for automotive fuel cells," Nature, Nature, vol. 486(7401), pages 43-51, June.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Qing & Han, Ning & Bokhari, Awais & Li, Xue & Cao, Yue & Asif, Saira & Shen, Zhengfeng & Si, Weimeng & Wang, Fagang & Klemeš, Jiří Jaromír & Zhao, Xiaolin, 2022. "Insights into MXenes-based electrocatalysts for oxygen reduction," Energy, Elsevier, vol. 255(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Lin, Rui & Zhong, Di & Lan, Shunbo & Guo, Rong & Ma, Yunyang & Cai, Xin, 2021. "Experimental validation for enhancement of PEMFC cold start performance: Based on the optimization of micro porous layer," Applied Energy, Elsevier, vol. 300(C).
    2. Chen, Dongfang & Pan, Lyuming & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries," Energy, Elsevier, vol. 224(C).
    3. Jung, Chi-Young & Yi, Jae-You & Yi, Sung-Chul, 2014. "On the role of the silica-containing catalyst layer for proton exchange membrane fuel cells," Energy, Elsevier, vol. 68(C), pages 794-800.
    4. Xia, Zhangxun & Sun, Ruili & Jing, Fenning & Wang, Suli & Sun, Hai & Sun, Gongquan, 2018. "Modeling and optimization of Scaffold-like macroporous electrodes for highly efficient direct methanol fuel cells," Applied Energy, Elsevier, vol. 221(C), pages 239-248.
    5. Li, Yanju & Li, Dongxu & Ma, Zheshu & Zheng, Meng & Lu, Zhanghao & Song, Hanlin & Guo, Xinjia & Shao, Wei, 2022. "Performance analysis and optimization of a novel vehicular power system based on HT-PEMFC integrated methanol steam reforming and ORC," Energy, Elsevier, vol. 257(C).
    6. Li, Yong & Song, Jian & Yang, Jie, 2015. "Graphene models and nano-scale characterization technologies for fuel cell vehicle electrodes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 66-77.
    7. Li, Xiang & Tang, Fumin & Wang, Qianqian & Li, Bing & Dai, Haifeng & Chang, Guofeng & Zhang, Cunman & Ming, Pingwen, 2023. "Effect of cathode catalyst layer on proton exchange membrane fuel cell performance: Considering the spatially variable distribution," Renewable Energy, Elsevier, vol. 212(C), pages 644-654.
    8. Zhang, Ruiyuan & Min, Ting & Chen, Li & Li, Hailong & Yan, Jinyue & Tao, Wen-Quan, 2022. "Pore-scale study of effects of relative humidity on reactive transport processes in catalyst layers in PEMFC," Applied Energy, Elsevier, vol. 323(C).
    9. Jiayue Zhang & Yikui Gao & Di Liu & Jing-Shan Zhao & Jie Wang, 2023. "Discharge domains regulation and dynamic processes of direct-current triboelectric nanogenerator," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    10. Sara Bakhtavar & Mehdi Mehrpooya & Mahboobeh Manoochehri & Mehrnoosh Karimkhani, 2022. "Proposal of a Facile Method to Fabricate a Multi-Dope Multiwall Carbon Nanotube as a Metal-Free Electrocatalyst for the Oxygen Reduction Reaction," Sustainability, MDPI, vol. 14(2), pages 1-17, January.
    11. Yuzhen Xia & Hangwei Lei & Xiaojun Wu & Guilin Hu & Hao Pan & Baizeng Fang, 2023. "Design of New Test System for Proton Exchange Membrane Fuel Cell," Energies, MDPI, vol. 16(2), pages 1-11, January.
    12. Xuan, Lingfeng & Wang, Yancheng & Lan, Jinwei & Tao, Kai & Zhou, Caiying & Mei, Deqing, 2023. "Development of cathode ordered membrane electrode assembly based on TiO2 nanowire array and ultrasonic spraying," Energy, Elsevier, vol. 264(C).
    13. Hanif, Saadia & Iqbal, Naseem & Shi, Xuan & Noor, Tayyaba & Ali, Ghulam & Kannan, A.M., 2020. "NiCo–N-doped carbon nanotubes based cathode catalyst for alkaline membrane fuel cell," Renewable Energy, Elsevier, vol. 154(C), pages 508-516.
    14. Noor H. Jawad & Ali Amer Yahya & Ali R. Al-Shathr & Hussein G. Salih & Khalid T. Rashid & Saad Al-Saadi & Adnan A. AbdulRazak & Issam K. Salih & Adel Zrelli & Qusay F. Alsalhy, 2022. "Fuel Cell Types, Properties of Membrane, and Operating Conditions: A Review," Sustainability, MDPI, vol. 14(21), pages 1-48, November.
    15. Lei Huang & Min Wei & Ruijuan Qi & Chung-Li Dong & Dai Dang & Cheng-Chieh Yang & Chenfeng Xia & Chao Chen & Shahid Zaman & Fu-Min Li & Bo You & Bao Yu Xia, 2022. "An integrated platinum-nanocarbon electrocatalyst for efficient oxygen reduction," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    16. Seok Hee Lee & Sung Pil Woo & Nitul Kakati & Dong-Joo Kim & Young Soo Yoon, 2018. "A Comprehensive Review of Nanomaterials Developed Using Electrophoresis Process for High-Efficiency Energy Conversion and Storage Systems," Energies, MDPI, vol. 11(11), pages 1-81, November.
    17. Chou, Chang-Chen & Liu, Cheng-Hong & Chen, Bing-Hung, 2014. "Effects of reduction temperature and pH value of polyol process on reduced graphene oxide supported Pt electrocatalysts for oxygen reduction reaction," Energy, Elsevier, vol. 70(C), pages 231-238.
    18. Mohideen, Mohamedazeem M. & Liu, Yong & Ramakrishna, Seeram, 2020. "Recent progress of carbon dots and carbon nanotubes applied in oxygen reduction reaction of fuel cell for transportation," Applied Energy, Elsevier, vol. 257(C).
    19. Jiajun Zhao & Cehuang Fu & Ke Ye & Zheng Liang & Fangling Jiang & Shuiyun Shen & Xiaoran Zhao & Lu Ma & Zulipiya Shadike & Xiaoming Wang & Junliang Zhang & Kun Jiang, 2022. "Manipulating the oxygen reduction reaction pathway on Pt-coordinated motifs," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    20. Wang, Likun & Bliznakov, Stoyan & Isseroff, Rebecca & Zhou, Yuchen & Zuo, Xianghao & Raut, Aniket & Wang, Wanhua & Cuiffo, Michael & Kim, Taejin & Rafailovich, Miriam H., 2020. "Enhancing proton exchange membrane fuel cell performance via graphene oxide surface synergy," Applied Energy, Elsevier, vol. 261(C).

    More about this item

    Keywords

    Ti3C2; Co3O4; N-doped carbon nanotubes; ORR;
    All these keywords.

    JEL classification:

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:160:y:2020:i:c:p:1168-1173. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.