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Experimental modeling and optimization of biodiesel production from waste cooking oil and ethanol using N,N′,N″-tris(3-dimethylaminopropyl)-guanidine as catalyst

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  • Racar, Marko
  • Faraguna, Fabio
  • Glasovac, Zoran
  • Jukić, Ante

Abstract

In this study biodiesel was produced from waste sunflower cooking oil and ethanol using N,N′,N″-tris(3-dimethylaminopropyl)-guanidine as new catalyst, which allows to avoid unwanted side-reaction of saponification. The influence of process variables on the conversion was investigated using experimental design and response surface methodology. Independent factors were varied in the following range: molar ratio of alcohol/oil from 3:1 to 15:1; catalyst concentration from 0.5 to 3 wt%; reaction temperature from 40 to 80 °C; and reaction time from 40 to 200 min. An empirical model of the process was developed. With this model and the goals of minimizing the independent factors in the tested range and maximizing the conversion, the optimization resulted in the following conditions: 1.13 wt% of catalyst, a molar ratio of 11.16:1, temperature of 67.96 °C, and a reaction time of 80 min. With those optimal conditions, the conversion predicted by the model was 94.6%.

Suggested Citation

  • Racar, Marko & Faraguna, Fabio & Glasovac, Zoran & Jukić, Ante, 2020. "Experimental modeling and optimization of biodiesel production from waste cooking oil and ethanol using N,N′,N″-tris(3-dimethylaminopropyl)-guanidine as catalyst," Renewable Energy, Elsevier, vol. 146(C), pages 2374-2379.
    • Handle: RePEc:eee:renene:v:146:y:2020:i:c:p:2374-2379
    DOI: 10.1016/j.renene.2019.08.028
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    1. Cardoso, Luana da Costa & Almeida, Fernanda Naiara Campos de & Souza, Gredson Keiff & Asanome, Isabela Yumi & Pereira, Nehemias Curvelo, 2019. "Synthesis and optimization of ethyl esters from fish oil waste for biodiesel production," Renewable Energy, Elsevier, vol. 133(C), pages 743-748.
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    4. Xie, Wenlei & Yang, Xinli & Fan, Mingliang, 2015. "Novel solid base catalyst for biodiesel production: Mesoporous SBA-15 silica immobilized with 1,3-dicyclohexyl-2-octylguanidine," Renewable Energy, Elsevier, vol. 80(C), pages 230-237.
    5. Zhang, Pingbo & Liu, Yanlei & Fan, Mingming & Jiang, Pingping, 2016. "Catalytic performance of a novel amphiphilic alkaline ionic liquid for biodiesel production: Influence of basicity and conductivity," Renewable Energy, Elsevier, vol. 86(C), pages 99-105.
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    1. Gotovuša, Mia & Medić, Mihovil & Faraguna, Fabio & Šibalić, Matea & Konjević, Lucija & Vuković, Jelena Parlov & Racar, Marko, 2022. "Fatty acids propyl esters: Synthesis optimization and application properties of their blends with diesel and 1-propanol," Renewable Energy, Elsevier, vol. 185(C), pages 655-664.
    2. Racar, Marko & Šoljić Jerbić, Ivana & Glasovac, Zoran & Jukić, Ante, 2023. "Guanidine catalysts for biodiesel production: Activity, process modelling and optimization," Renewable Energy, Elsevier, vol. 202(C), pages 1046-1053.
    3. Foteinis, Spyros & Chatzisymeon, Efthalia & Litinas, Alexandros & Tsoutsos, Theocharis, 2020. "Used-cooking-oil biodiesel: Life cycle assessment and comparison with first- and third-generation biofuel," Renewable Energy, Elsevier, vol. 153(C), pages 588-600.

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