IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v133y2019icp743-748.html
   My bibliography  Save this article

Synthesis and optimization of ethyl esters from fish oil waste for biodiesel production

Author

Listed:
  • Cardoso, Luana da Costa
  • Almeida, Fernanda Naiara Campos de
  • Souza, Gredson Keiff
  • Asanome, Isabela Yumi
  • Pereira, Nehemias Curvelo

Abstract

Fish oil is a sustainable, abundant, and low-cost raw material, as it is extracted from fish processing waste. This work suggests that fish oil is appropriate for biodiesel production and evaluates its potential through ethyl esters (EE). Initially, fish oil showed an acid value of 10.86 ± 0.05 mg KOH g−1. But after a neutralization reaction, the acid value was reduced to 0.68 ± 0.01 mg KOH g−1. Alkaline transesterification reactions were performed on a laboratory scale, using a central composite rotational design with three variables and a triplicate over the center point. We studied the appropriate concentrations of ethanol and catalysts, and the temperature that provide the best EE yield. The results showed the optimal condition is with 0.7% of a NaOH catalyst, a temperature of 54 °C, and an ethanol:oil molar ratio of 11.7:1. In such conditions, it was possible to acquire an EE yield of 96.4% with a low acid value of 0.32 ± 0.08 mg KOH g−1, which presented physicochemical properties consistent with the parameters by the Petroleum National Agency's (ANP). In the conditions studied, the results showed high levels of EE from the residual fish oil. This suggests that this raw material, rich in unsaturated fatty acid, can be beneficial for biodiesel.

Suggested Citation

  • Cardoso, Luana da Costa & Almeida, Fernanda Naiara Campos de & Souza, Gredson Keiff & Asanome, Isabela Yumi & Pereira, Nehemias Curvelo, 2019. "Synthesis and optimization of ethyl esters from fish oil waste for biodiesel production," Renewable Energy, Elsevier, vol. 133(C), pages 743-748.
    • Handle: RePEc:eee:renene:v:133:y:2019:i:c:p:743-748
    DOI: 10.1016/j.renene.2018.10.081
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148118312734
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2018.10.081?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Fadhil, Abdelrahman B. & Ali, Latif H., 2013. "Alkaline-catalyzed transesterification of Silurus triostegus Heckel fish oil: Optimization of transesterification parameters," Renewable Energy, Elsevier, vol. 60(C), pages 481-488.
    2. Kudre, Tanaji G. & Bhaskar, N. & Sakhare, Patiram Z., 2017. "Optimization and characterization of biodiesel production from rohu (Labeo rohita) processing waste," Renewable Energy, Elsevier, vol. 113(C), pages 1408-1418.
    3. Giakoumis, Evangelos G., 2013. "A statistical investigation of biodiesel physical and chemical properties, and their correlation with the degree of unsaturation," Renewable Energy, Elsevier, vol. 50(C), pages 858-878.
    4. Meher, L.C. & Vidya Sagar, D. & Naik, S.N., 2006. "Technical aspects of biodiesel production by transesterification--a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 10(3), pages 248-268, June.
    5. García-Moreno, Pedro J. & Khanum, Mohriam & Guadix, Antonio & Guadix, Emilia M., 2014. "Optimization of biodiesel production from waste fish oil," Renewable Energy, Elsevier, vol. 68(C), pages 618-624.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ravanipour, Masoumeh & Hamidi, Ali & Mahvi, Amir Hossein, 2021. "Microalgae biodiesel: A systematic review in Iran," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    2. Pascoal, C.V.P. & Oliveira, A.L.L. & Figueiredo, D.D. & Assunção, J.C.C., 2020. "Optimization and kinetic study of ultrasonic-mediated in situ transesterification for biodiesel production from the almonds of Syagrus cearensis," Renewable Energy, Elsevier, vol. 147(P1), pages 1815-1824.
    3. Impha Yalagudige Dharmegowda & Lakshmidevamma Madarakallu Muniyappa & Parameshwara Siddalingaiah & Ajith Bintravalli Suresh & Manjunath Patel Gowdru Chandrashekarappa & Chander Prakash, 2022. "MgO Nano-Catalyzed Biodiesel Production from Waste Coconut Oil and Fish Oil Using Response Surface Methodology and Grasshopper Optimization," Sustainability, MDPI, vol. 14(18), pages 1-23, September.
    4. Racar, Marko & Faraguna, Fabio & Glasovac, Zoran & Jukić, Ante, 2020. "Experimental modeling and optimization of biodiesel production from waste cooking oil and ethanol using N,N′,N″-tris(3-dimethylaminopropyl)-guanidine as catalyst," Renewable Energy, Elsevier, vol. 146(C), pages 2374-2379.
    5. Hammad Ahmad Jan & Igor Šurina & Ahmed S. Al-Fatesh & Abdulaziz M. Almutlaq & Sher Wali & Anton Lisý, 2022. "Biodiesel Synthesis from Milk Thistle ( Silybum marianum (L.) Gaertn.) Seed Oil using ZnO Nanoparticles as a Catalyst," Energies, MDPI, vol. 15(20), pages 1-18, October.
    6. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    7. Fernandes, David M. & Squissato, André L. & Lima, Alexandre F. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2019. "Corrosive character of Moringa oleifera Lam biodiesel exposed to carbon steel under simulated storage conditions," Renewable Energy, Elsevier, vol. 139(C), pages 1263-1271.
    8. Shalfoh, Ehsan & Ahmad, Mardiana Idayu & Binhweel, Fozy & Shaah, Marwan Abdulhakim & Senusi, Wardah & Hossain, Md Sohrab & Alsaadi, Sami, 2024. "Fish waste oil extraction using supercritical CO2 extraction for biodiesel production: Mathematical, and kinetic modeling," Renewable Energy, Elsevier, vol. 220(C).
    9. Lourenço, Vitor Alves & Nadaleti, Willian Cézar & Vieira, Bruno Müller & Li, Hu, 2021. "Investigation of ethyl biodiesel via transesterification of rice bran oil: bioenergy from residual biomass in Pelotas, Rio Grande do Sul - Brazil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    10. Elkelawy, Medhat & Etaiw, Safaa El-din H. & Alm-Eldin Bastawissi, Hagar & Ayad, Mohamed I. & Radwan, Ahmed Mohamed & Dawood, Mohamed M., 2021. "Diesel/ biodiesel /silver thiocyanate nanoparticles/hydrogen peroxide blends as new fuel for enhancement of performance, combustion, and Emission characteristics of a diesel engine," Energy, Elsevier, vol. 216(C).
    11. Sáez-Bastante, J. & Carmona-Cabello, M. & Pinzi, S. & Dorado, M.P., 2020. "Recycling of kebab restoration grease for bioenergy production through acoustic cavitation," Renewable Energy, Elsevier, vol. 155(C), pages 1147-1155.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    2. Kudre, Tanaji G. & Bhaskar, N. & Sakhare, Patiram Z., 2017. "Optimization and characterization of biodiesel production from rohu (Labeo rohita) processing waste," Renewable Energy, Elsevier, vol. 113(C), pages 1408-1418.
    3. de Medeiros, Eliane Freitas & Vieira, Bruno Muller & de Pereira, Cláudio Martin Pereira & Nadaleti, Willian Cézar & Quadro, Maurízio Silveira & Andreazza, Robson, 2019. "Production of biodiesel using oil obtained from fish processing residue by conventional methods assisted by ultrasonic waves: Heating and stirring," Renewable Energy, Elsevier, vol. 143(C), pages 1357-1365.
    4. García-Moreno, Pedro J. & Khanum, Mohriam & Guadix, Antonio & Guadix, Emilia M., 2014. "Optimization of biodiesel production from waste fish oil," Renewable Energy, Elsevier, vol. 68(C), pages 618-624.
    5. Takase, Mohammed & Zhao, Ting & Zhang, Min & Chen, Yao & Liu, Hongyang & Yang, Liuqing & Wu, Xiangyang, 2015. "An expatiate review of neem, jatropha, rubber and karanja as multipurpose non-edible biodiesel resources and comparison of their fuel, engine and emission properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 495-520.
    6. Jaiswal, Krishna Kumar & Dutta, Swapnamoy & Banerjee, Ishita & Jaiswal, Km Smriti & Renuka, Nirmal & Ratha, Sachitra Kumar & Jaiswal, Amit K., 2024. "Valorization of fish processing industry waste for biodiesel production: Opportunities, challenges, and technological perspectives," Renewable Energy, Elsevier, vol. 220(C).
    7. Moraes, Paola S. & Igansi, Andrei V. & Cadaval, Tito R.S. & Pinto, Luiz A.A., 2020. "Biodiesel produced from crude, degummed, neutralized and bleached oils of Nile tilapia waste: Production efficiency, physical-chemical quality and economic viability," Renewable Energy, Elsevier, vol. 161(C), pages 110-119.
    8. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    9. Siwina, Siraprapha & Leesing, Ratanaporn, 2021. "Bioconversion of durian (Durio zibethinus Murr.) peel hydrolysate into biodiesel by newly isolated oleaginous yeast Rhodotorula mucilaginosa KKUSY14," Renewable Energy, Elsevier, vol. 163(C), pages 237-245.
    10. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    11. Malhotra, Rashi & Ali, Amjad, 2019. "5-Na/ZnO doped mesoporous silica as reusable solid catalyst for biodiesel production via transesterification of virgin cottonseed oil," Renewable Energy, Elsevier, vol. 133(C), pages 606-619.
    12. Marco Castellini & Stefano Ubertini & Diego Barletta & Ilaria Baffo & Pietro Buzzini & Marco Barbanera, 2021. "Techno-Economic Analysis of Biodiesel Production from Microbial Oil Using Cardoon Stalks as Carbon Source," Energies, MDPI, vol. 14(5), pages 1-21, March.
    13. Thamsiriroj, Thanasit & Murphy, Jerry D., 2011. "A critical review of the applicability of biodiesel and grass biomethane as biofuels to satisfy both biofuel targets and sustainability criteria," Applied Energy, Elsevier, vol. 88(4), pages 1008-1019, April.
    14. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
    15. Lau, Pak-Chung & Kwong, Tsz-Lung & Yung, Ka-Fu, 2022. "Manganese glycerolate catalyzed simultaneous esterification and transesterification: The kinetic and mechanistic study, and application in biodiesel and bio-lubricants synthesis," Renewable Energy, Elsevier, vol. 189(C), pages 549-558.
    16. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part II," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1446-1466.
    17. Odoom-Wubah, Tareque & Rubio, Saúl & Tirado, José L. & Ortiz, Gregorio F. & Akoi, Bior James & Huang, Jiale & Li, Qingbiao, 2020. "Waste Pd/Fish-Collagen as anode for energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    18. Venu, Harish & Raju, V. Dhana & Subramani, Lingesan & Appavu, Prabhu, 2020. "Experimental assessment on the regulated and unregulated emissions of DI diesel engine fuelled with Chlorella emersonii methyl ester (CEME)," Renewable Energy, Elsevier, vol. 151(C), pages 88-102.
    19. Yano Surya Pradana & I Gusti B. N. Makertihartha & Antonius Indarto & Tirto Prakoso & Tatang Hernas Soerawidjaja, 2024. "A Review of Biodiesel Cold Flow Properties and Its Improvement Methods: Towards Sustainable Biodiesel Application," Energies, MDPI, vol. 17(18), pages 1-43, September.
    20. Lam, Man Kee & Tan, Kok Tat & Lee, Keat Teong & Mohamed, Abdul Rahman, 2009. "Malaysian palm oil: Surviving the food versus fuel dispute for a sustainable future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1456-1464, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:133:y:2019:i:c:p:743-748. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.