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Pyrolytic behavior and kinetic of wood sawdust at isothermal and non-isothermal conditions

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  • Zhang, Xin
  • Deng, Honghu
  • Hou, Xueyi
  • Qiu, Rongliang
  • Chen, Zhihua

Abstract

Pyrolytic behavior and kinetic of wood sawdust were studied at non-isothermal and isothermal conditions. The characteristic temperatures of ∼230 °C, ∼300 °C, ∼345 °C, ∼370 °C corresponded to degradation of pseudo hemicelluloses 1, hemicellulose 2, cellulose, lignin under non-isothermal condition, respectively. The release behaviors of gaseous products were closely related to the characteristic temperatures of weight loss. The tar generation could be characterized by CH3 group that was mainly dominated the by decompositions of hemicelluloses and cellulose. Under isothermal condition, the weight of derived biochar was described by a function of wchar = 775.5–2.9T + 0.0037T2-1.6 × 10−6T3. A novel nth-order discrete distributed activation energy model was developed to study the non-isothermal kinetic. The characteristic weight fractions of woody sawdust pyrolysis were found at conversions of 0.29, 0.30, 0.65, 0.84, 0.88 and 0.95. Parallel reaction model could explain the non-isothermal kinetic well with similar reaction orders to discrete distributed activation energy model. The isothermal kinetic of pyrolysis could be described by three or four components parallel reaction with nth-order Avrami-Erofeev model.

Suggested Citation

  • Zhang, Xin & Deng, Honghu & Hou, Xueyi & Qiu, Rongliang & Chen, Zhihua, 2019. "Pyrolytic behavior and kinetic of wood sawdust at isothermal and non-isothermal conditions," Renewable Energy, Elsevier, vol. 142(C), pages 284-294.
    • Handle: RePEc:eee:renene:v:142:y:2019:i:c:p:284-294
    DOI: 10.1016/j.renene.2019.04.115
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    1. Martín-Lara, M.A. & Blázquez, G. & Ronda, A. & Calero, M., 2016. "Kinetic study of the pyrolysis of pine cone shell through non-isothermal thermogravimetry: Effect of heavy metals incorporated by biosorption," Renewable Energy, Elsevier, vol. 96(PA), pages 613-624.
    2. Shadangi, Krushna Prasad & Mohanty, Kaustubha, 2014. "Kinetic study and thermal analysis of the pyrolysis of non-edible oilseed powders by thermogravimetric and differential scanning calorimetric analysis," Renewable Energy, Elsevier, vol. 63(C), pages 337-344.
    3. Wu, Chunfei & Budarin, Vitaliy L. & Wang, Meihong & Sharifi, Vida & Gronnow, Mark J. & Wu, Yajue & Swithenbank, Jim & Clark, James H. & Williams, Paul T., 2015. "CO2 gasification of bio-char derived from conventional and microwave pyrolysis," Applied Energy, Elsevier, vol. 157(C), pages 533-539.
    4. Jayaraman, Kandasamy & Kok, Mustafa Versan & Gokalp, Iskender, 2017. "Thermogravimetric and mass spectrometric (TG-MS) analysis and kinetics of coal-biomass blends," Renewable Energy, Elsevier, vol. 101(C), pages 293-300.
    5. Al Arni, Saleh, 2018. "Comparison of slow and fast pyrolysis for converting biomass into fuel," Renewable Energy, Elsevier, vol. 124(C), pages 197-201.
    6. Xie, Candie & Liu, Jingyong & Xie, Wuming & Kuo, Jiahong & Lu, Xingwen & Zhang, Xiaochun & He, Yao & Sun, Jian & Chang, Kenlin & Xie, Wenhao & Liu, Chao & Sun, Shuiyu & Buyukada, Musa & Evrendilek, Fa, 2018. "Quantifying thermal decomposition regimes of textile dyeing sludge, pomelo peel, and their blends," Renewable Energy, Elsevier, vol. 122(C), pages 55-64.
    7. Cai, Junmeng & Wu, Weixuan & Liu, Ronghou, 2014. "An overview of distributed activation energy model and its application in the pyrolysis of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 236-246.
    8. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    9. Wang, Bo & Xu, Fanfan & Zong, Peijie & Zhang, Jinhong & Tian, Yuanyu & Qiao, Yingyun, 2019. "Effects of heating rate on fast pyrolysis behavior and product distribution of Jerusalem artichoke stalk by using TG-FTIR and Py-GC/MS," Renewable Energy, Elsevier, vol. 132(C), pages 486-496.
    10. Yuan, Xinsong & He, Tao & Cao, Hongliang & Yuan, Qiaoxia, 2017. "Cattle manure pyrolysis process: Kinetic and thermodynamic analysis with isoconversional methods," Renewable Energy, Elsevier, vol. 107(C), pages 489-496.
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    6. Jia, Yongsheng & Wang, Yingjie & Zhang, Qi & Rong, Hongwei & Liu, Yuhuan & Xiao, Bo & Guo, Dabin & Laghari, Mahmood & Ruan, Roger, 2022. "Gas-carrying enhances the combustion temperature of the biomass particles," Energy, Elsevier, vol. 239(PA).
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    8. Hu, Mian & Zhang, Haiyang & Ye, Zhiheng & Ma, Jiajia & Chen, Zhihua & Wang, Junliang & Wang, Cheng & Pan, Zhiyan, 2022. "Thermogravimetric kinetics and pyrolytic tri-state products analysis towards insights into understanding the pyrolysis mechanism of Spirulina platensis with calcium oxide," Renewable Energy, Elsevier, vol. 184(C), pages 498-509.

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    Keywords

    Pyrolysis; Biomass; Kinetic; TG-FTIR;
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