IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v142y2019icp284-294.html
   My bibliography  Save this article

Pyrolytic behavior and kinetic of wood sawdust at isothermal and non-isothermal conditions

Author

Listed:
  • Zhang, Xin
  • Deng, Honghu
  • Hou, Xueyi
  • Qiu, Rongliang
  • Chen, Zhihua

Abstract

Pyrolytic behavior and kinetic of wood sawdust were studied at non-isothermal and isothermal conditions. The characteristic temperatures of ∼230 °C, ∼300 °C, ∼345 °C, ∼370 °C corresponded to degradation of pseudo hemicelluloses 1, hemicellulose 2, cellulose, lignin under non-isothermal condition, respectively. The release behaviors of gaseous products were closely related to the characteristic temperatures of weight loss. The tar generation could be characterized by CH3 group that was mainly dominated the by decompositions of hemicelluloses and cellulose. Under isothermal condition, the weight of derived biochar was described by a function of wchar = 775.5–2.9T + 0.0037T2-1.6 × 10−6T3. A novel nth-order discrete distributed activation energy model was developed to study the non-isothermal kinetic. The characteristic weight fractions of woody sawdust pyrolysis were found at conversions of 0.29, 0.30, 0.65, 0.84, 0.88 and 0.95. Parallel reaction model could explain the non-isothermal kinetic well with similar reaction orders to discrete distributed activation energy model. The isothermal kinetic of pyrolysis could be described by three or four components parallel reaction with nth-order Avrami-Erofeev model.

Suggested Citation

  • Zhang, Xin & Deng, Honghu & Hou, Xueyi & Qiu, Rongliang & Chen, Zhihua, 2019. "Pyrolytic behavior and kinetic of wood sawdust at isothermal and non-isothermal conditions," Renewable Energy, Elsevier, vol. 142(C), pages 284-294.
    • Handle: RePEc:eee:renene:v:142:y:2019:i:c:p:284-294
    DOI: 10.1016/j.renene.2019.04.115
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119305993
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2019.04.115?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Jayaraman, Kandasamy & Kok, Mustafa Versan & Gokalp, Iskender, 2017. "Thermogravimetric and mass spectrometric (TG-MS) analysis and kinetics of coal-biomass blends," Renewable Energy, Elsevier, vol. 101(C), pages 293-300.
    2. Martín-Lara, M.A. & Blázquez, G. & Ronda, A. & Calero, M., 2016. "Kinetic study of the pyrolysis of pine cone shell through non-isothermal thermogravimetry: Effect of heavy metals incorporated by biosorption," Renewable Energy, Elsevier, vol. 96(PA), pages 613-624.
    3. Shadangi, Krushna Prasad & Mohanty, Kaustubha, 2014. "Kinetic study and thermal analysis of the pyrolysis of non-edible oilseed powders by thermogravimetric and differential scanning calorimetric analysis," Renewable Energy, Elsevier, vol. 63(C), pages 337-344.
    4. Cai, Junmeng & Wu, Weixuan & Liu, Ronghou, 2014. "An overview of distributed activation energy model and its application in the pyrolysis of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 236-246.
    5. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    6. Wang, Bo & Xu, Fanfan & Zong, Peijie & Zhang, Jinhong & Tian, Yuanyu & Qiao, Yingyun, 2019. "Effects of heating rate on fast pyrolysis behavior and product distribution of Jerusalem artichoke stalk by using TG-FTIR and Py-GC/MS," Renewable Energy, Elsevier, vol. 132(C), pages 486-496.
    7. Yuan, Xinsong & He, Tao & Cao, Hongliang & Yuan, Qiaoxia, 2017. "Cattle manure pyrolysis process: Kinetic and thermodynamic analysis with isoconversional methods," Renewable Energy, Elsevier, vol. 107(C), pages 489-496.
    8. Al Arni, Saleh, 2018. "Comparison of slow and fast pyrolysis for converting biomass into fuel," Renewable Energy, Elsevier, vol. 124(C), pages 197-201.
    9. Wu, Chunfei & Budarin, Vitaliy L. & Wang, Meihong & Sharifi, Vida & Gronnow, Mark J. & Wu, Yajue & Swithenbank, Jim & Clark, James H. & Williams, Paul T., 2015. "CO2 gasification of bio-char derived from conventional and microwave pyrolysis," Applied Energy, Elsevier, vol. 157(C), pages 533-539.
    10. Xie, Candie & Liu, Jingyong & Xie, Wuming & Kuo, Jiahong & Lu, Xingwen & Zhang, Xiaochun & He, Yao & Sun, Jian & Chang, Kenlin & Xie, Wenhao & Liu, Chao & Sun, Shuiyu & Buyukada, Musa & Evrendilek, Fa, 2018. "Quantifying thermal decomposition regimes of textile dyeing sludge, pomelo peel, and their blends," Renewable Energy, Elsevier, vol. 122(C), pages 55-64.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Brillard, A. & Brilhac, J.F., 2020. "Improvements of global models for the determination of the kinetic parameters associated to the thermal degradation of lignocellulosic materials under low heating rates," Renewable Energy, Elsevier, vol. 146(C), pages 1498-1509.
    2. Jia, Yongsheng & Wang, Yingjie & Zhang, Qi & Rong, Hongwei & Liu, Yuhuan & Xiao, Bo & Guo, Dabin & Laghari, Mahmood & Ruan, Roger, 2022. "Gas-carrying enhances the combustion temperature of the biomass particles," Energy, Elsevier, vol. 239(PA).
    3. Vikraman, V. Karuppasamy & Boopathi, G. & Kumar, D. Praveen & Mythili, R. & Subramanian, P., 2021. "Non-isothermal pyrolytic kinetics of milk dust powder using thermogravimetric analysis," Renewable Energy, Elsevier, vol. 180(C), pages 838-849.
    4. Wądrzyk, Mariusz & Grzywacz, Przemysław & Janus, Rafał & Michalik, Marek, 2021. "A two-stage processing of cherry pomace via hydrothermal treatment followed by biochar gasification," Renewable Energy, Elsevier, vol. 179(C), pages 248-261.
    5. Radosław Slezak & Liliana Krzystek & Piotr Dziugan & Stanisław Ledakowicz, 2020. "Co-Pyrolysis of Beet Pulp and Defecation Lime in TG-MS System," Energies, MDPI, vol. 13(9), pages 1-13, May.
    6. Wądrzyk, Mariusz & Janus, Rafał & Lewandowski, Marek & Magdziarz, Aneta, 2021. "On mechanism of lignin decomposition – Investigation using microscale techniques: Py-GC-MS, Py-FT-IR and TGA," Renewable Energy, Elsevier, vol. 177(C), pages 942-952.
    7. Stančin, H. & Mikulčić, H. & Manić, N. & Stojiljiković, D. & Vujanović, M. & Wang, X. & Duić, N., 2021. "Thermogravimetric and kinetic analysis of biomass and polyurethane foam mixtures Co-Pyrolysis," Energy, Elsevier, vol. 237(C).
    8. Hu, Mian & Zhang, Haiyang & Ye, Zhiheng & Ma, Jiajia & Chen, Zhihua & Wang, Junliang & Wang, Cheng & Pan, Zhiyan, 2022. "Thermogravimetric kinetics and pyrolytic tri-state products analysis towards insights into understanding the pyrolysis mechanism of Spirulina platensis with calcium oxide," Renewable Energy, Elsevier, vol. 184(C), pages 498-509.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Zhikun & Zhu, Zongyuan & Shen, Boxiong & Liu, Lina, 2019. "Insights into biochar and hydrochar production and applications: A review," Energy, Elsevier, vol. 171(C), pages 581-598.
    2. Zhao, Ming & Memon, Muhammad Zaki & Ji, Guozhao & Yang, Xiaoxiao & Vuppaladadiyam, Arun K. & Song, Yinqiang & Raheem, Abdul & Li, Jinhui & Wang, Wei & Zhou, Hui, 2020. "Alkali metal bifunctional catalyst-sorbents enabled biomass pyrolysis for enhanced hydrogen production," Renewable Energy, Elsevier, vol. 148(C), pages 168-175.
    3. Sahoo, Abhisek & Kumar, Sachin & Mohanty, Kaustubha, 2021. "Kinetic and thermodynamic analysis of Putranjiva roxburghii (putranjiva) and Cassia fistula (amaltas) non-edible oilseeds using thermogravimetric analyzer," Renewable Energy, Elsevier, vol. 165(P1), pages 261-277.
    4. Gupta, Shubhi & Gupta, Goutam Kishore & Mondal, Monoj Kumar, 2019. "Slow pyrolysis of chemically treated walnut shell for valuable products: Effect of process parameters and in-depth product analysis," Energy, Elsevier, vol. 181(C), pages 665-676.
    5. Lech Nowicki & Dorota Siuta & Maciej Markowski, 2020. "Pyrolysis of Rapeseed Oil Press Cake and Steam Gasification of Solid Residues," Energies, MDPI, vol. 13(17), pages 1-12, August.
    6. Zhang, Lianjie & Tan, Yongdong & Cai, Dongqiang & Sun, Jifu & Zhang, Yue & Li, Longzhi & Zhang, Qiang & Zou, Guifu & Song, Zhanlong & Bai, Yonghui, 2022. "Enhanced pyrolysis of woody biomass under interaction of microwave and needle-shape metal and its production properties," Energy, Elsevier, vol. 249(C).
    7. Liu, Hui & Liu, Jingyong & Huang, Hongyi & Evrendilek, Fatih & Wen, Shaoting & Li, Weixin, 2021. "Optimizing bioenergy and by-product outputs from durian shell pyrolysis," Renewable Energy, Elsevier, vol. 164(C), pages 407-418.
    8. Liu, Jiazheng & Zhong, Fei & Niu, Wenjuan & Su, Jing & Gao, Ziqi & Zhang, Kai, 2019. "Effects of heating rate and gas atmosphere on the pyrolysis and combustion characteristics of different crop residues and the kinetics analysis," Energy, Elsevier, vol. 175(C), pages 320-332.
    9. Zhang, Zhiqing & Duan, Hanqi & Zhang, Youjun & Guo, Xiaojuan & Yu, Xi & Zhang, Xingguang & Rahman, Md. Maksudur & Cai, Junmeng, 2020. "Investigation of kinetic compensation effect in lignocellulosic biomass torrefaction: Kinetic and thermodynamic analyses," Energy, Elsevier, vol. 207(C).
    10. Chen, Zhiyun & Chen, Huashan & Wu, Xieyuan & Zhang, Junhui & Evrendilek, Deniz Eren & Liu, Jingyong & Liang, Guanjie & Li, Weixin, 2021. "Temperature- and heating rate-dependent pyrolysis mechanisms and emissions of Chinese medicine residues and numerical reconstruction and optimization of their non-linear dynamics," Renewable Energy, Elsevier, vol. 164(C), pages 1408-1423.
    11. Wen, Shaoting & Yan, Youping & Liu, Jingyong & Buyukada, Musa & Evrendilek, Fatih, 2019. "Pyrolysis performance, kinetic, thermodynamic, product and joint optimization analyses of incense sticks in N2 and CO2 atmospheres," Renewable Energy, Elsevier, vol. 141(C), pages 814-827.
    12. Tariq, Rumaisa & Mohd Zaifullizan, Yasmin & Salema, Arshad Adam & Abdulatif, Atiqah & Ken, Loke Shun, 2022. "Co-pyrolysis and co-combustion of orange peel and biomass blends: Kinetics, thermodynamic, and ANN application," Renewable Energy, Elsevier, vol. 198(C), pages 399-414.
    13. Naqvi, Salman Raza & Tariq, Rumaisa & Hameed, Zeeshan & Ali, Imtiaz & Naqvi, Muhammad & Chen, Wei-Hsin & Ceylan, Selim & Rashid, Harith & Ahmad, Junaid & Taqvi, Syed A. & Shahbaz, Muhammad, 2019. "Pyrolysis of high ash sewage sludge: Kinetics and thermodynamic analysis using Coats-Redfern method," Renewable Energy, Elsevier, vol. 131(C), pages 854-860.
    14. Qiu, Shuxing & Zhang, Shengfu & Zhou, Xiaohu & Zhang, Qingyun & Qiu, Guibao & Hu, Meilong & You, Zhixiong & Wen, Liangying & Bai, Chenguang, 2019. "Thermal behavior and organic functional structure of poplar-fat coal blends during co-pyrolysis," Renewable Energy, Elsevier, vol. 136(C), pages 308-316.
    15. Zhu, Haodong & Yi, Baojun & Hu, Hongyun & Fan, Qizhou & Wang, Hao & Yao, Hong, 2021. "The effects of char and potassium on the fast pyrolysis behaviors of biomass in an infrared-heating condition," Energy, Elsevier, vol. 214(C).
    16. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    17. Mika Pahnila & Aki Koskela & Petri Sulasalmi & Timo Fabritius, 2023. "A Review of Pyrolysis Technologies and the Effect of Process Parameters on Biocarbon Properties," Energies, MDPI, vol. 16(19), pages 1-27, October.
    18. Torres, Erick & Rodriguez-Ortiz, Leandro A. & Zalazar, Daniela & Echegaray, Marcelo & Rodriguez, Rosa & Zhang, Huili & Mazza, Germán, 2020. "4-E (environmental, economic, energetic and exergetic) analysis of slow pyrolysis of lignocellulosic waste," Renewable Energy, Elsevier, vol. 162(C), pages 296-307.
    19. Qi, Huini & Li, Fashe & Wang, Shuang & Sui, Meng & Lu, Fengju, 2024. "Pyrolysis and co-pyrolysis of cattle manure, rape straw, and their blend: Physicochemical characterization, kinetic triplets, reaction mechanism, and thermodynamic analysis," Energy, Elsevier, vol. 292(C).
    20. Siddiqi, Hammad & Bal, Manisha & Kumari, Usha & Meikap, B.C., 2020. "In-depth physiochemical characterization and detailed thermo-kinetic study of biomass wastes to analyze its energy potential," Renewable Energy, Elsevier, vol. 148(C), pages 756-771.

    More about this item

    Keywords

    Pyrolysis; Biomass; Kinetic; TG-FTIR;
    All these keywords.

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:142:y:2019:i:c:p:284-294. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.