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Kinetic study of the pyrolysis of pine cone shell through non-isothermal thermogravimetry: Effect of heavy metals incorporated by biosorption

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  • Martín-Lara, M.A.
  • Blázquez, G.
  • Ronda, A.
  • Calero, M.

Abstract

The study concerns the pyrolysis kinetics of exhausted pine cone shell after its use as biosorbent of copper and lead from aqueous solutions in a fixed bed column. First, breakthrough curves of biosorption process were obtained. Main dynamic biosorption parameters were determined and analyzed. Then, non-isothermal thermogravimetric experiments were carried out with raw and metal-loaded biomass in a thermobalance under nitrogen atmosphere at different heating rates. A comparative study was performed. The activation energy dependent on the conversion rate was estimated by Flynn–Wall–Ozawa (a free integral or iso-conventional method) and a mechanistic model (an integral or model-fitting method that considers three independent parallel reactions). The fluctuation of activation energy in Flynn-Wall Ozawa model can be considered the result of thermal degradation reactions of different pseudo-components of the lignocellulosic material (hemicellulose, cellulose and lignin). For raw pine cone shell and metal-loaded-pine cone shell, best fit parameters were determined according to a three independent parallel reactions scheme. The copper and lead present in metal-loaded samples did not modify values of determined parameters which describe the pyrolysis process. Finally, chemical analysis of the chars indicated that about 95% and 99% of copper and lead presented on original waste was recovered in generated chars.

Suggested Citation

  • Martín-Lara, M.A. & Blázquez, G. & Ronda, A. & Calero, M., 2016. "Kinetic study of the pyrolysis of pine cone shell through non-isothermal thermogravimetry: Effect of heavy metals incorporated by biosorption," Renewable Energy, Elsevier, vol. 96(PA), pages 613-624.
    • Handle: RePEc:eee:renene:v:96:y:2016:i:pa:p:613-624
    DOI: 10.1016/j.renene.2016.05.026
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    References listed on IDEAS

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    1. Ma, Zhongqing & Zhang, Yimeng & Zhang, Qisheng & Qu, Yongbiao & Zhou, Jianbin & Qin, Hengfei, 2012. "Design and experimental investigation of a 190 kWe biomass fixed bed gasification and polygeneration pilot plant using a double air stage downdraft approach," Energy, Elsevier, vol. 46(1), pages 140-147.
    2. Liang, Yue-gan & Cheng, Beijiu & Si, You-bin & Cao, De-ju & Jiang, Hai-yang & Han, Guo-min & Liu, Xiao-hong, 2014. "Thermal decomposition kinetics and characteristics of Spartina alterniflora via thermogravimetric analysis," Renewable Energy, Elsevier, vol. 68(C), pages 111-117.
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    1. Zhang, Xin & Deng, Honghu & Hou, Xueyi & Qiu, Rongliang & Chen, Zhihua, 2019. "Pyrolytic behavior and kinetic of wood sawdust at isothermal and non-isothermal conditions," Renewable Energy, Elsevier, vol. 142(C), pages 284-294.
    2. Singh, Rishikesh Kumar & Sarkar, Arnab & Chakraborty, Jyoti Prasad, 2020. "Effect of torrefaction on the physicochemical properties of eucalyptus derived biofuels: estimation of kinetic parameters and optimizing torrefaction using response surface methodology (RSM)," Energy, Elsevier, vol. 198(C).

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