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Pyrolysis and co-pyrolysis of cattle manure, rape straw, and their blend: Physicochemical characterization, kinetic triplets, reaction mechanism, and thermodynamic analysis

Author

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  • Qi, Huini
  • Li, Fashe
  • Wang, Shuang
  • Sui, Meng
  • Lu, Fengju

Abstract

Cattle manure (CM) and rape straw (RS) are typical agricultural wastes. In present study, pyrolysis and co-pyrolysis of CM, RS, and their blend (MM) were studied by thermogravimetric experiments at different heating rates (10, 20, and 30 °C/min). The kinetic analysis was carried out using three iso-conversional methods, Friedman (FR), Kissinger-Akahira-Sunose (KAS), and Flynn-Wall-Ozawa (FWO). The average apparent activation energies (Eα) values calculated by FR, KAS, and FWO methods were 181.82 kJ/mol, 176.09 kJ/mol, and 196.50 kJ/mol for CM, 221.55 kJ/mol, 204.91 kJ/mol, and 215.08 kJ/mol for RS, and 314.35 kJ/mol, 294.08 kJ/mol, and 304.33 kJ/mol for MM. The overall pyrolysis processes of CM, RS, and MM followed the diffusional and order of reaction models by the master-plots method. Thermodynamic parameters indicated the non-spontaneous and endothermic characteristics of the CM, RS, and MM pyrolysis. The kinetic and thermodynamic analysis will provide critical information for the safe and efficient design of pyrolysis reactors with CM, RS, and MM as feedstocks.

Suggested Citation

  • Qi, Huini & Li, Fashe & Wang, Shuang & Sui, Meng & Lu, Fengju, 2024. "Pyrolysis and co-pyrolysis of cattle manure, rape straw, and their blend: Physicochemical characterization, kinetic triplets, reaction mechanism, and thermodynamic analysis," Energy, Elsevier, vol. 292(C).
    • Handle: RePEc:eee:energy:v:292:y:2024:i:c:s0360544224002913
    DOI: 10.1016/j.energy.2024.130520
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    References listed on IDEAS

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    1. Liu, Chun-Min & Wu, Shu-Yii, 2016. "From biomass waste to biofuels and biomaterial building blocks," Renewable Energy, Elsevier, vol. 96(PB), pages 1056-1062.
    2. Masnadi, Mohammad S. & Grace, John R. & Bi, Xiaotao T. & Lim, C. Jim & Ellis, Naoko, 2015. "From fossil fuels towards renewables: Inhibitory and catalytic effects on carbon thermochemical conversion during co-gasification of biomass with fossil fuels," Applied Energy, Elsevier, vol. 140(C), pages 196-209.
    3. Shadangi, Krushna Prasad & Mohanty, Kaustubha, 2014. "Kinetic study and thermal analysis of the pyrolysis of non-edible oilseed powders by thermogravimetric and differential scanning calorimetric analysis," Renewable Energy, Elsevier, vol. 63(C), pages 337-344.
    4. Masnadi, Mohammad S. & Grace, John R. & Bi, Xiaotao T. & Lim, C. Jim & Ellis, Naoko & Li, Yong Hua & Watkinson, A. Paul, 2015. "From coal towards renewables: Catalytic/synergistic effects during steam co-gasification of switchgrass and coal in a pilot-scale bubbling fluidized bed," Renewable Energy, Elsevier, vol. 83(C), pages 918-930.
    5. Yuan, Xinsong & He, Tao & Cao, Hongliang & Yuan, Qiaoxia, 2017. "Cattle manure pyrolysis process: Kinetic and thermodynamic analysis with isoconversional methods," Renewable Energy, Elsevier, vol. 107(C), pages 489-496.
    6. Jiang, Chunlong & Zhou, Wenliang & Bi, Haobo & Ni, Zhanshi & Sun, Hao & Lin, Qizhao, 2022. "Co-pyrolysis of coal slime and cattle manure by TG–FTIR–MS and artificial neural network modeling: Pyrolysis behavior, kinetics, gas emission characteristics," Energy, Elsevier, vol. 247(C).
    7. Hou, Yanmei & Feng, Zixing & He, Yuyu & Gao, Qi & Ni, Liangmeng & Su, Mengfu & Ren, Hao & Liu, Zhijia & Hu, Wanhe, 2022. "Co-pyrolysis characteristics and synergistic interaction of bamboo residues and disposable face mask," Renewable Energy, Elsevier, vol. 194(C), pages 415-425.
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