IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v13y2020i9p2304-d354508.html
   My bibliography  Save this article

Co-Pyrolysis of Beet Pulp and Defecation Lime in TG-MS System

Author

Listed:
  • Radosław Slezak

    (Department of Bioprocess Engineering, Faculty of Process and Environmental Engineering, Lodz University of Technology, Wolczanska 213, 90-924 Lodz, Poland)

  • Liliana Krzystek

    (Department of Bioprocess Engineering, Faculty of Process and Environmental Engineering, Lodz University of Technology, Wolczanska 213, 90-924 Lodz, Poland)

  • Piotr Dziugan

    (Institute of Fermentation Technology and Microbiology, Faculty of Biotechnology and Food Sciences, Lodz University of Technology, Wolczanska 171-173, 90-924 Lodz, Poland)

  • Stanisław Ledakowicz

    (Department of Bioprocess Engineering, Faculty of Process and Environmental Engineering, Lodz University of Technology, Wolczanska 213, 90-924 Lodz, Poland)

Abstract

The process of pyrolysis of beet pulp, a by-product after the extraction of raw sugar from sugar beet, with the addition of defecation lime was studied in a thermobalance coupled with a mass spectrometer. The beet pulp pyrolysis process took place completely at 600 °C, and the resulting char, tar and gas were characterized by higher heating values of 23.9, 21.6 and 7.77 MJ/kg, respectively. The addition of the defecation lime to beet pulp caused both an increase in the char production yield and a decrease in the tar production yield. At the same time, the higher heating value of char and tar decreased along with the increase of defecation lime added to the sample. The deconvolution of derivative thermogravimetric (DTG) curves allowed us to identify the basic components of beet pulp, for which the activation energy by isoconversion method was calculated. The 20 wt.% addition of defecation lime caused an increase of the activation energy by about 18%. Further increase in the defecation lime content resulted in a reduction of activation energy. At the temperature above 600 °C, calcination of calcium carbonate contained in defecation lime occurred. The CO 2 produced during calcination process did not cause auto-gasification of char.

Suggested Citation

  • Radosław Slezak & Liliana Krzystek & Piotr Dziugan & Stanisław Ledakowicz, 2020. "Co-Pyrolysis of Beet Pulp and Defecation Lime in TG-MS System," Energies, MDPI, vol. 13(9), pages 1-13, May.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:9:p:2304-:d:354508
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/13/9/2304/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/13/9/2304/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Opatokun, Suraj Adebayo & Strezov, Vladimir & Kan, Tao, 2015. "Product based evaluation of pyrolysis of food waste and its digestate," Energy, Elsevier, vol. 92(P3), pages 349-354.
    2. Wang, Guangwei & Zhang, Jianliang & Shao, Jiugang & Liu, Zhengjian & Wang, Haiyang & Li, Xinyu & Zhang, Pengcheng & Geng, Weiwei & Zhang, Guohua, 2016. "Experimental and modeling studies on CO2 gasification of biomass chars," Energy, Elsevier, vol. 114(C), pages 143-154.
    3. Zhang, Xin & Deng, Honghu & Hou, Xueyi & Qiu, Rongliang & Chen, Zhihua, 2019. "Pyrolytic behavior and kinetic of wood sawdust at isothermal and non-isothermal conditions," Renewable Energy, Elsevier, vol. 142(C), pages 284-294.
    4. Zhong, Chongli & Wei, Xiaomin, 2004. "A comparative experimental study on the liquefaction of wood," Energy, Elsevier, vol. 29(11), pages 1731-1741.
    5. Nicodème, Thibault & Berchem, Thomas & Jacquet, Nicolas & Richel, Aurore, 2018. "Thermochemical conversion of sugar industry by-products to biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 151-159.
    6. Kwon, Eilhann E. & Lee, Taewoo & Ok, Yong Sik & Tsang, Daniel C.W. & Park, Chanhyuk & Lee, Jechan, 2018. "Effects of calcium carbonate on pyrolysis of sewage sludge," Energy, Elsevier, vol. 153(C), pages 726-731.
    7. Jun-Ho Jo & Seung-Soo Kim & Jae-Wook Shim & Ye-Eun Lee & Yeong-Seok Yoo, 2017. "Pyrolysis Characteristics and Kinetics of Food Wastes," Energies, MDPI, vol. 10(8), pages 1-13, August.
    8. Wilk, Małgorzata & Magdziarz, Aneta & Kalemba, Izabela & Gara, Paweł, 2016. "Carbonisation of wood residue into charcoal during low temperature process," Renewable Energy, Elsevier, vol. 85(C), pages 507-513.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Zhikun & Zhu, Zongyuan & Shen, Boxiong & Liu, Lina, 2019. "Insights into biochar and hydrochar production and applications: A review," Energy, Elsevier, vol. 171(C), pages 581-598.
    2. Brand, Steffen & Hardi, Flabianus & Kim, Jaehoon & Suh, Dong Jin, 2014. "Effect of heating rate on biomass liquefaction: Differences between subcritical water and supercritical ethanol," Energy, Elsevier, vol. 68(C), pages 420-427.
    3. Sun, Peiqin & Heng, Mingxing & Sun, Shaohui & Chen, Junwu, 2010. "Direct liquefaction of paulownia in hot compressed water: Influence of catalysts," Energy, Elsevier, vol. 35(12), pages 5421-5429.
    4. Hu, Qiang & Yang, Haiping & Wu, Zhiqiang & Lim, C. Jim & Bi, Xiaotao T. & Chen, Hanping, 2019. "Experimental and modeling study of potassium catalyzed gasification of woody char pellet with CO2," Energy, Elsevier, vol. 171(C), pages 678-688.
    5. Suraj Adebayo Opatokun & Ana Lopez-Sabiron & German Ferreira & Vladimir Strezov, 2017. "Life Cycle Analysis of Energy Production from Food Waste through Anaerobic Digestion, Pyrolysis and Integrated Energy System," Sustainability, MDPI, vol. 9(10), pages 1-15, October.
    6. Jung, Sungyup & Lee, Jechan & Moon, Deok Hyun & Kim, Ki-Hyun & Kwon, Eilhann E., 2021. "Upgrading biogas into syngas through dry reforming," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    7. Ye-Eun Lee & Jun-Ho Jo & I-Tae Kim & Yeong-Seok Yoo, 2018. "Value-Added Performance and Thermal Decomposition Characteristics of Dumped Food Waste Compost by Pyrolysis," Energies, MDPI, vol. 11(5), pages 1-14, April.
    8. Brillard, A. & Brilhac, J.F., 2020. "Improvements of global models for the determination of the kinetic parameters associated to the thermal degradation of lignocellulosic materials under low heating rates," Renewable Energy, Elsevier, vol. 146(C), pages 1498-1509.
    9. Liu, Xianjie & Feng, Qian & Peng, Zhigang & Zheng, Yong & Liu, Huan, 2020. "Preparation and evaluation of micro-encapsulated thermal control materials for oil well cement slurry," Energy, Elsevier, vol. 208(C).
    10. Wan Mahari, Wan Adibah & Chong, Cheng Tung & Cheng, Chin Kui & Lee, Chern Leing & Hendrata, Kristian & Yuh Yek, Peter Nai & Ma, Nyuk Ling & Lam, Su Shiung, 2018. "Production of value-added liquid fuel via microwave co-pyrolysis of used frying oil and plastic waste," Energy, Elsevier, vol. 162(C), pages 309-317.
    11. Hu, Sheng-Chun & Cheng, Jie & Wang, Wu-Ping & Zhu, Ya-Hong & Kang, Kang & Zhu, Ming-Qiang & Huang, Xiao-Hua, 2022. "Preparation and analysis of pyroligneous liquor, charcoal and gas from lacquer wood by carbonization method based on a biorefinery process," Energy, Elsevier, vol. 239(PA).
    12. Bonassa, Gabriela & Schneider, Lara Talita & Canever, Victor Bruno & Cremonez, Paulo André & Frigo, Elisandro Pires & Dieter, Jonathan & Teleken, Joel Gustavo, 2018. "Scenarios and prospects of solid biofuel use in Brazil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2365-2378.
    13. Du, Hong & Ma, Xiuyun & Jiang, Miao & Yan, Peifang & Zhang, Z.Conrad, 2021. "Autocatalytic co-upgrading of biochar and pyrolysis gas to syngas," Energy, Elsevier, vol. 221(C).
    14. Andrzej Biessikirski & Dominik Czerwonka & Jolanta Biegańska & Łukasz Kuterasiński & Magdalena Ziąbka & Michał Dworzak & Michał Twardosz, 2020. "Research on the Possible Application of Polyolefin Waste-Derived Pyrolysis Oils for ANFO Manufacturing," Energies, MDPI, vol. 14(1), pages 1-15, December.
    15. Magdalena Matusiak & Radosław Ślęzak & Stanisław Ledakowicz, 2020. "Thermogravimetric Kinetics of Selected Energy Crops Pyrolysis," Energies, MDPI, vol. 13(15), pages 1-15, August.
    16. Park, Chanyeong & Choi, Heeyoung & Andrew Lin, Kun-Yi & Kwon, Eilhann E. & Lee, Jechan, 2021. "COVID-19 mask waste to energy via thermochemical pathway: Effect of Co-Feeding food waste," Energy, Elsevier, vol. 230(C).
    17. Hasan, M.M. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Jahirul, M.I., 2021. "Energy recovery from municipal solid waste using pyrolysis technology: A review on current status and developments," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    18. Nobre, Catarina & Vilarinho, Cândida & Alves, Octávio & Mendes, Benilde & Gonçalves, Margarida, 2019. "Upgrading of refuse derived fuel through torrefaction and carbonization: Evaluation of RDF char fuel properties," Energy, Elsevier, vol. 181(C), pages 66-76.
    19. Singh, Saurabh & Morya, Raj & Jaiswal, Durgesh Kumar & Keerthana, S. & Kim, Sang-Hyoun & Manimekalai, R. & Prudêncio de Araujo Pereira, Arthur & Verma, Jay Prakash, 2024. "Innovations and advances in enzymatic deconstruction of biomass and their sustainability analysis: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).
    20. Brand, Steffen & Susanti, Ratna Frida & Kim, Seok Ki & Lee, Hong-shik & Kim, Jaehoon & Sang, Byung-In, 2013. "Supercritical ethanol as an enhanced medium for lignocellulosic biomass liquefaction: Influence of physical process parameters," Energy, Elsevier, vol. 59(C), pages 173-182.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:13:y:2020:i:9:p:2304-:d:354508. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.