IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v141y2019icp420-430.html
   My bibliography  Save this article

Catalytic upgrading of hydrothermal liquefaction biocrudes: Different challenges for different feedstocks

Author

Listed:
  • Castello, Daniele
  • Haider, Muhammad Salman
  • Rosendahl, Lasse Aistrup

Abstract

Hydrothermal liquefaction (HTL) followed by catalytic hydrotreating of the produced biocrude is increasingly gaining ground as an effective technology for the conversion of biomass into liquid biofuels. A strong advantage of HTL resides in its great flexibility towards the feedstock, since it is able to treat a large number of different organic substrates, ranging from dry to wet residual biomass. Nevertheless, the characteristics of biocrudes from different typologies of organic materials result in different challenges to be met during the hydrotreating step, leading to differences in heteroatoms removal and in the typology and composition of the targeted products. In this work, biocrudes were catalytically hydrotreated with a commercial NiMo/Al2O3 catalyst at different temperatures and pressures. Sewage sludge biocrude was found to be very promising for the production of straight-chain hydrocarbons in the diesel range, with considerable heteroatoms removal even at mild hydrotreating conditions. Similar results were shown by algal biocrude, although complete denitrogenation is challenging. Upgraded biocrudes from lignocellulosic feedstock (miscanthus) showed high yields in the gasoline range, with a remarkable content of aromatics. Operating at a higher H2 pressure was found to be crucial to prevent coking and decarboxylation reactions.

Suggested Citation

  • Castello, Daniele & Haider, Muhammad Salman & Rosendahl, Lasse Aistrup, 2019. "Catalytic upgrading of hydrothermal liquefaction biocrudes: Different challenges for different feedstocks," Renewable Energy, Elsevier, vol. 141(C), pages 420-430.
    • Handle: RePEc:eee:renene:v:141:y:2019:i:c:p:420-430
    DOI: 10.1016/j.renene.2019.04.003
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119304768
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2019.04.003?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Xu, Donghai & Lin, Guike & Guo, Shuwei & Wang, Shuzhong & Guo, Yang & Jing, Zefeng, 2018. "Catalytic hydrothermal liquefaction of algae and upgrading of biocrude: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 97(C), pages 103-118.
    2. Daniele Castello & Thomas Helmer Pedersen & Lasse Aistrup Rosendahl, 2018. "Continuous Hydrothermal Liquefaction of Biomass: A Critical Review," Energies, MDPI, vol. 11(11), pages 1-35, November.
    3. Patel, Bhavish & Arcelus-Arrillaga, Pedro & Izadpanah, Arash & Hellgardt, Klaus, 2017. "Catalytic Hydrotreatment of algal biocrude from fast Hydrothermal Liquefaction," Renewable Energy, Elsevier, vol. 101(C), pages 1094-1101.
    4. Konstantinos Anastasakis & Patrick Biller & René B. Madsen & Marianne Glasius & Ib Johannsen, 2018. "Continuous Hydrothermal Liquefaction of Biomass in a Novel Pilot Plant with Heat Recovery and Hydraulic Oscillation," Energies, MDPI, vol. 11(10), pages 1-23, October.
    5. Pedersen, T.H. & Jensen, C.U. & Sandström, L. & Rosendahl, L.A., 2017. "Full characterization of compounds obtained from fractional distillation and upgrading of a HTL biocrude," Applied Energy, Elsevier, vol. 202(C), pages 408-419.
    6. Muhammad Salman Haider & Daniele Castello & Karol Michal Michalski & Thomas Helmer Pedersen & Lasse Aistrup Rosendahl, 2018. "Catalytic Hydrotreatment of Microalgae Biocrude from Continuous Hydrothermal Liquefaction: Heteroatom Removal and Their Distribution in Distillation Cuts," Energies, MDPI, vol. 11(12), pages 1-14, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ekaterina Ovsyannikova & Andrea Kruse & Gero C. Becker, 2020. "Feedstock-Dependent Phosphate Recovery in a Pilot-Scale Hydrothermal Liquefaction Bio-Crude Production," Energies, MDPI, vol. 13(2), pages 1-21, January.
    2. Sharma, Nishesh & Jaiswal, Krishna Kumar & Kumar, Vinod & Vlaskin, Mikhail S. & Nanda, Manisha & Rautela, Indra & Tomar, Mahipal Singh & Ahmad, Waseem, 2021. "Effect of catalyst and temperature on the quality and productivity of HTL bio-oil from microalgae: A review," Renewable Energy, Elsevier, vol. 174(C), pages 810-822.
    3. Huang, Xinghua & Dong, Shengfei & Yang, Xiaoyi, 2022. "Refining lipid for aviation biofuel at the molecular level," Renewable Energy, Elsevier, vol. 201(P1), pages 148-159.
    4. Ahmad, Salman & Ouenniche, Jamal & Kolosz, Ben W. & Greening, Philip & Andresen, John M. & Maroto-Valer, M. Mercedes & Xu, Bing, 2021. "A stakeholders’ participatory approach to multi-criteria assessment of sustainable aviation fuels production pathways," International Journal of Production Economics, Elsevier, vol. 238(C).
    5. Kargbo, Hannah & Harris, Jonathan Stuart & Phan, Anh N., 2021. "“Drop-in” fuel production from biomass: Critical review on techno-economic feasibility and sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    6. Dylan J. Cronin & Senthil Subramaniam & Casper Brady & Alan Cooper & Zhibin Yang & Joshua Heyne & Corinne Drennan & Karthikeyan K. Ramasamy & Michael R. Thorson, 2022. "Sustainable Aviation Fuel from Hydrothermal Liquefaction of Wet Wastes," Energies, MDPI, vol. 15(4), pages 1-17, February.
    7. Hosseini, Mohammad & Hatefirad, Parvaneh & Salimi, Saeideh & Tavasoli, Ahmad, 2022. "Hydrothermal liquefaction of granular bacteria to high-quality bio-oil using Ni–Ce catalysts supported on functionalized activated carbon," Energy, Elsevier, vol. 241(C).
    8. Prestigiacomo, Claudia & Proietto, Federica & Laudicina, Vito Armando & Siragusa, Angelo & Scialdone, Onofrio & Galia, Alessandro, 2021. "Catalytic hydrothermal liquefaction of municipal sludge assisted by formic acid for the production of next-generation fuels," Energy, Elsevier, vol. 232(C).
    9. Aljabri, Hareb & Das, Probir & Khan, Shoyeb & AbdulQuadir, Mohammad & Thaher, Mahmoud & Hawari, Alaa H. & Al-Shamary, Noora Mahmoud, 2022. "A study to investigate the energy recovery potential from different macromolecules of a low-lipid marine Tetraselmis sp. biomass through HTL process," Renewable Energy, Elsevier, vol. 189(C), pages 78-89.
    10. Liu, Quan & Zhang, Guanyu & Liu, Mingyang & Kong, Ge & Xu, Ruolan & Han, Lujia & Zhang, Xuesong, 2022. "Fast hydrothermal liquefaction coupled with homogeneous catalysts to valorize livestock manure for enhanced biocrude oil and hydrochar production," Renewable Energy, Elsevier, vol. 198(C), pages 521-533.
    11. Li, Bingshuo & Liu, Yixuan & Yang, Tianhua & Feng, Bixuan & Kai, Xingping & Wang, Shurong & Li, Rundong, 2021. "Aqueous phase reforming of biocrude derived from lignocellulose hydrothermal liquefaction: Conditions optimization and mechanism study," Renewable Energy, Elsevier, vol. 175(C), pages 98-107.
    12. Do, Truong Xuan & Mujahid, Rana & Lim, Hyun Soo & Kim, Jae-Kon & Lim, Young-Il & Kim, Jaehoon, 2020. "Techno-economic analysis of bio heavy-oil production from sewage sludge using supercritical and subcritical water," Renewable Energy, Elsevier, vol. 151(C), pages 30-42.
    13. Robertson, Gilles & Adiningtyas, Kusuma Virginna & Ebrahim, Sayed Ahmed & Scoles, Ludmila & Baranova, Elena A. & Singh, Devinder, 2021. "Understanding the nature of bio-asphaltenes produced during hydrothermal liquefaction," Renewable Energy, Elsevier, vol. 173(C), pages 128-140.
    14. Xu, Donghua & Lin, Junhao & Ma, Rui & Fang, Lin & Sun, Shichang & Luo, Juan, 2022. "Microwave pyrolysis of biomass for low-oxygen bio-oil: Mechanisms of CO2-assisted in-situ deoxygenation," Renewable Energy, Elsevier, vol. 184(C), pages 124-133.
    15. Pelosin, Primavera & Longhin, Francesco & Hansen, Nikolaj Bisgaard & Lamagni, Paolo & Drazevic, Emil & Benito, Patricia & Anastasakis, Konstantinos & Catalano, Jacopo, 2024. "High-temperature high-pressure electrochemical hydrogenation of biocrude oil," Renewable Energy, Elsevier, vol. 222(C).
    16. Nikolaos Montesantos & Marco Maschietti, 2020. "Supercritical Carbon Dioxide Extraction of Lignocellulosic Bio-Oils: The Potential of Fuel Upgrading and Chemical Recovery," Energies, MDPI, vol. 13(7), pages 1-35, April.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shahbeik, Hossein & Kazemi Shariat Panahi, Hamed & Dehhaghi, Mona & Guillemin, Gilles J. & Fallahi, Alireza & Hosseinzadeh-Bandbafha, Homa & Amiri, Hamid & Rehan, Mohammad & Raikwar, Deepak & Latine, , 2024. "Biomass to biofuels using hydrothermal liquefaction: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    2. Ekaterina Ovsyannikova & Andrea Kruse & Gero C. Becker, 2020. "Feedstock-Dependent Phosphate Recovery in a Pilot-Scale Hydrothermal Liquefaction Bio-Crude Production," Energies, MDPI, vol. 13(2), pages 1-21, January.
    3. Ankit Mathanker & Snehlata Das & Deepak Pudasainee & Monir Khan & Amit Kumar & Rajender Gupta, 2021. "A Review of Hydrothermal Liquefaction of Biomass for Biofuels Production with a Special Focus on the Effect of Process Parameters, Co-Solvents, and Extraction Solvents," Energies, MDPI, vol. 14(16), pages 1-60, August.
    4. Nikolaos Montesantos & Marco Maschietti, 2020. "Supercritical Carbon Dioxide Extraction of Lignocellulosic Bio-Oils: The Potential of Fuel Upgrading and Chemical Recovery," Energies, MDPI, vol. 13(7), pages 1-35, April.
    5. Daniele Castello & Thomas Helmer Pedersen & Lasse Aistrup Rosendahl, 2018. "Continuous Hydrothermal Liquefaction of Biomass: A Critical Review," Energies, MDPI, vol. 11(11), pages 1-35, November.
    6. Taghipour, Alireza & Ramirez, Jerome A. & Brown, Richard J. & Rainey, Thomas J., 2019. "A review of fractional distillation to improve hydrothermal liquefaction biocrude characteristics; future outlook and prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    7. Lozano, E.M. & Pedersen, T.H. & Rosendahl, L.A., 2020. "Integration of hydrothermal liquefaction and carbon capture and storage for the production of advanced liquid biofuels with negative CO2 emissions," Applied Energy, Elsevier, vol. 279(C).
    8. Dylan J. Cronin & Senthil Subramaniam & Casper Brady & Alan Cooper & Zhibin Yang & Joshua Heyne & Corinne Drennan & Karthikeyan K. Ramasamy & Michael R. Thorson, 2022. "Sustainable Aviation Fuel from Hydrothermal Liquefaction of Wet Wastes," Energies, MDPI, vol. 15(4), pages 1-17, February.
    9. Perkins, Greg & Batalha, Nuno & Kumar, Adarsh & Bhaskar, Thallada & Konarova, Muxina, 2019. "Recent advances in liquefaction technologies for production of liquid hydrocarbon fuels from biomass and carbonaceous wastes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    10. Qian, Lili & Wang, Shuzhong & Savage, Phillip E., 2020. "Fast and isothermal hydrothermal liquefaction of sludge at different severities: Reaction products, pathways, and kinetics," Applied Energy, Elsevier, vol. 260(C).
    11. Wu, Yujian & Wang, Haoyu & Li, Haoyang & Han, Xue & Zhang, Mingyuan & Sun, Yan & Fan, Xudong & Tu, Ren & Zeng, Yimin & Xu, Chunbao Charles & Xu, Xiwei, 2022. "Applications of catalysts in thermochemical conversion of biomass (pyrolysis, hydrothermal liquefaction and gasification): A critical review," Renewable Energy, Elsevier, vol. 196(C), pages 462-481.
    12. SundarRajan, P. & Gopinath, K.P. & Arun, J. & GracePavithra, K. & Adithya Joseph, A. & Manasa, S., 2021. "Insights into valuing the aqueous phase derived from hydrothermal liquefaction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    13. Prestigiacomo, Claudia & Laudicina, Vito Armando & Siragusa, Angelo & Scialdone, Onofrio & Galia, Alessandro, 2020. "Hydrothermal liquefaction of waste biomass in stirred reactors: One step forward to the integral valorization of municipal sludge," Energy, Elsevier, vol. 201(C).
    14. Muhammad Salman Haider & Daniele Castello & Karol Michal Michalski & Thomas Helmer Pedersen & Lasse Aistrup Rosendahl, 2018. "Catalytic Hydrotreatment of Microalgae Biocrude from Continuous Hydrothermal Liquefaction: Heteroatom Removal and Their Distribution in Distillation Cuts," Energies, MDPI, vol. 11(12), pages 1-14, December.
    15. Al-Jabri, Hareb & Das, Probir & Khan, Shoyeb & AbdulQuadir, Mohammad & Thaher, Mehmoud Ibrahim & Hoekman, Kent & Hawari, Alaa H., 2022. "A comparison of bio-crude oil production from five marine microalgae – Using life cycle analysis," Energy, Elsevier, vol. 251(C).
    16. Sharma, Nishesh & Jaiswal, Krishna Kumar & Kumar, Vinod & Vlaskin, Mikhail S. & Nanda, Manisha & Rautela, Indra & Tomar, Mahipal Singh & Ahmad, Waseem, 2021. "Effect of catalyst and temperature on the quality and productivity of HTL bio-oil from microalgae: A review," Renewable Energy, Elsevier, vol. 174(C), pages 810-822.
    17. Tahir H. Seehar & Saqib S. Toor & Ayaz A. Shah & Thomas H. Pedersen & Lasse A. Rosendahl, 2020. "Biocrude Production from Wheat Straw at Sub and Supercritical Hydrothermal Liquefaction," Energies, MDPI, vol. 13(12), pages 1-18, June.
    18. Raquel de Souza Deuber & Jéssica Marcon Bressanin & Daniel Santos Fernandes & Henrique Real Guimarães & Mateus Ferreira Chagas & Antonio Bonomi & Leonardo Vasconcelos Fregolente & Marcos Djun Barbosa , 2023. "Production of Sustainable Aviation Fuels from Lignocellulosic Residues in Brazil through Hydrothermal Liquefaction: Techno-Economic and Environmental Assessments," Energies, MDPI, vol. 16(6), pages 1-21, March.
    19. Liu, Xiaoguang & Wang, Qian & Tang, Yuanzhi & Pavlostathis, Spyros G., 2021. "A comparative study on biogas production, energy balance, and nutrients conversion with inter-stage hydrothermal treatment of sewage sludge," Applied Energy, Elsevier, vol. 288(C).
    20. Savvas L. Douvartzides & Nikolaos D. Charisiou & Kyriakos N. Papageridis & Maria A. Goula, 2019. "Green Diesel: Biomass Feedstocks, Production Technologies, Catalytic Research, Fuel Properties and Performance in Compression Ignition Internal Combustion Engines," Energies, MDPI, vol. 12(5), pages 1-41, February.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:141:y:2019:i:c:p:420-430. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.