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Catalytic Hydrotreatment of algal biocrude from fast Hydrothermal Liquefaction

Author

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  • Patel, Bhavish
  • Arcelus-Arrillaga, Pedro
  • Izadpanah, Arash
  • Hellgardt, Klaus

Abstract

Hydrotreatment(HDT) of algal biocrude produced via a continuous flow reactor system at reaction condition of 380 °C and 0.5 min is conducted over a range of commercially available C and mesoporous gamma Al2O3 supported, 5 wt% loaded Pt, Pd, Ru and NiMo catalysts. Upgraded Biocrude(UBC) yield of over 60 wt% was achieved with the highest yield gained via NiMo/Al2O3 catalysed reaction. The change in elemental composition resulted in the UBC attaining deoxygenation levels similar to crude oil with oxygen level in the region of 6.07–1.60 wt%, and a maximum denitrogenation of 42.7%. The low O content of the UBC increased the Higher Heating Value(HHV) in the range of 38.36–45.40 MJ/kg from a value of 36.54 MJ/kg for the biocrude feedstock. Similarly, combined with the yield, an Energy Recovery (ER) figure in the range of 0.76 and 1.03 was calculated for the Ru/Al2O3 and control HDT reactions, respectively. Simulated Distillation(SIMDIST) of the UBC showed redistribution of gas oil fraction (271–343 °C) to lower and higher boiling point fractions, confirming both cracking and polymerisation reactions, also confirmed via Size Exclusion Chromatography(SEC). Additional analysis via ATR FT-IR showed formation of aromatics and GC-MS shed light on some of the molecular species present in the UBC.

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  • Patel, Bhavish & Arcelus-Arrillaga, Pedro & Izadpanah, Arash & Hellgardt, Klaus, 2017. "Catalytic Hydrotreatment of algal biocrude from fast Hydrothermal Liquefaction," Renewable Energy, Elsevier, vol. 101(C), pages 1094-1101.
    • Handle: RePEc:eee:renene:v:101:y:2017:i:c:p:1094-1101
    DOI: 10.1016/j.renene.2016.09.056
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    References listed on IDEAS

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    1. Tian, Chunyan & Li, Baoming & Liu, Zhidan & Zhang, Yuanhui & Lu, Haifeng, 2014. "Hydrothermal liquefaction for algal biorefinery: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 933-950.
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    5. Castello, Daniele & Haider, Muhammad Salman & Rosendahl, Lasse Aistrup, 2019. "Catalytic upgrading of hydrothermal liquefaction biocrudes: Different challenges for different feedstocks," Renewable Energy, Elsevier, vol. 141(C), pages 420-430.
    6. Shahbeik, Hossein & Kazemi Shariat Panahi, Hamed & Dehhaghi, Mona & Guillemin, Gilles J. & Fallahi, Alireza & Hosseinzadeh-Bandbafha, Homa & Amiri, Hamid & Rehan, Mohammad & Raikwar, Deepak & Latine, , 2024. "Biomass to biofuels using hydrothermal liquefaction: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    7. Das, Bikashbindu & Mohanty, Kaustubha, 2019. "A review on advances in sustainable energy production through various catalytic processes by using catalysts derived from waste red mud," Renewable Energy, Elsevier, vol. 143(C), pages 1791-1811.
    8. Xiao, Chao & Fu, Qian & Liao, Qiang & Huang, Yun & Xia, Ao & Chen, Hao & Zhu, Xun, 2020. "Life cycle and economic assessments of biogas production from microalgae biomass with hydrothermal pretreatment via anaerobic digestion," Renewable Energy, Elsevier, vol. 151(C), pages 70-78.

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