IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v175y2021icp98-107.html
   My bibliography  Save this article

Aqueous phase reforming of biocrude derived from lignocellulose hydrothermal liquefaction: Conditions optimization and mechanism study

Author

Listed:
  • Li, Bingshuo
  • Liu, Yixuan
  • Yang, Tianhua
  • Feng, Bixuan
  • Kai, Xingping
  • Wang, Shurong
  • Li, Rundong

Abstract

Hydrothermal liquefaction (HTL) of biomass into biocrude is attractive but the biocrude themselves are poor fuels, which need to be upgraded for further utilization. Compared with the traditional catalytic upgradation process, a non-catalytic method for biocrude upgrading in the aqueous waste (HTL-AW) derived from HTL of cornstalk was proposed. Optimal reaction conditions of upgradation process were obtained at 356 °C (temperature), 37 min (reaction time) and 19 mL/g (HTL-AW/biocrude) based on the response surface methodology. The biocrude was effectively upgraded in the HTL-AW and a high hydrogen to carbon effective (H/Ceff) ratio of 1.07 with a higher heating value of 36.94 MJ/kg was observed. The energy recovery of ∼80% from biocrude to upgraded biocrude was feasible. GC–MS analysis showed that the contents of phenols and ketones were decreased from 65.61% to 48.38% and 22.39%–16.78%, respectively, while the contents of nitrogen-containing compounds n-hexadecanoic acid were increased from 2.25% to 10.15% and 9.56%–22.23%, respectively. The high H/Ceff was attributed to the promoted deoxygenation by alkali and alkaline earth metals as well as H+ enriched in the HTL-AW. This study demonstrates the feasibility of improving the H/Ceff of biocrude in the HTL-AW under a relatively mild reaction condition.

Suggested Citation

  • Li, Bingshuo & Liu, Yixuan & Yang, Tianhua & Feng, Bixuan & Kai, Xingping & Wang, Shurong & Li, Rundong, 2021. "Aqueous phase reforming of biocrude derived from lignocellulose hydrothermal liquefaction: Conditions optimization and mechanism study," Renewable Energy, Elsevier, vol. 175(C), pages 98-107.
  • Handle: RePEc:eee:renene:v:175:y:2021:i:c:p:98-107
    DOI: 10.1016/j.renene.2021.04.127
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121006479
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2021.04.127?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chen, Wan-Ting & Zhang, Yuanhui & Zhang, Jixiang & Schideman, Lance & Yu, Guo & Zhang, Peng & Minarick, Mitchell, 2014. "Co-liquefaction of swine manure and mixed-culture algal biomass from a wastewater treatment system to produce bio-crude oil," Applied Energy, Elsevier, vol. 128(C), pages 209-216.
    2. Pedersen, T.H. & Grigoras, I.F. & Hoffmann, J. & Toor, S.S. & Daraban, I.M. & Jensen, C.U. & Iversen, S.B. & Madsen, R.B. & Glasius, M. & Arturi, K.R. & Nielsen, R.P. & Søgaard, E.G. & Rosendahl, L.A., 2016. "Continuous hydrothermal co-liquefaction of aspen wood and glycerol with water phase recirculation," Applied Energy, Elsevier, vol. 162(C), pages 1034-1041.
    3. Ong, Hwai Chyuan & Chen, Wei-Hsin & Farooq, Abid & Gan, Yong Yang & Lee, Keat Teong & Ashokkumar, Veeramuthu, 2019. "Catalytic thermochemical conversion of biomass for biofuel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    4. Zhu, Zhe & Rosendahl, Lasse & Toor, Saqib Sohail & Yu, Donghong & Chen, Guanyi, 2015. "Hydrothermal liquefaction of barley straw to bio-crude oil: Effects of reaction temperature and aqueous phase recirculation," Applied Energy, Elsevier, vol. 137(C), pages 183-192.
    5. Gollakota, A.R.K. & Kishore, Nanda & Gu, Sai, 2018. "A review on hydrothermal liquefaction of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1378-1392.
    6. Chen, Haitao & He, Zhixia & Zhang, Bo & Feng, Huan & Kandasamy, Sabariswaran & Wang, Bin, 2019. "Effects of the aqueous phase recycling on bio-oil yield in hydrothermal liquefaction of Spirulina Platensis, α-cellulose, and lignin," Energy, Elsevier, vol. 179(C), pages 1103-1113.
    7. Qineng Xia & Zongjia Chen & Yi Shao & Xueqing Gong & Haifeng Wang & Xiaohui Liu & Stewart F. Parker & Xue Han & Sihai Yang & Yanqin Wang, 2016. "Direct hydrodeoxygenation of raw woody biomass into liquid alkanes," Nature Communications, Nature, vol. 7(1), pages 1-10, September.
    8. Castello, Daniele & Haider, Muhammad Salman & Rosendahl, Lasse Aistrup, 2019. "Catalytic upgrading of hydrothermal liquefaction biocrudes: Different challenges for different feedstocks," Renewable Energy, Elsevier, vol. 141(C), pages 420-430.
    9. Zhang, Linghong & Champagne, Pascale & (Charles) Xu, Chunbao, 2011. "Bio-crude production from secondary pulp/paper-mill sludge and waste newspaper via co-liquefaction in hot-compressed water," Energy, Elsevier, vol. 36(4), pages 2142-2150.
    10. Oh, Shinyoung & Kim, Ung-Jin & Choi, In-Gyu & Choi, Joon Weon, 2016. "Solvent effects on improvement of fuel properties during hydrodeoxygenation process of bio-oil in the presence of Pt/C," Energy, Elsevier, vol. 113(C), pages 116-123.
    11. Chen, Xinfei & Ma, Xiaoqian & Zeng, Xianghao & Zheng, Chupeng & Lu, Xiaoluan, 2020. "Ethanol addition during aqueous phase recirculation for further improving bio-oil yield and quality," Applied Energy, Elsevier, vol. 262(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Jian & Wang, Yincheng & Dong, Xiaoshan & Hu, Yongjie & Tao, Junyu & Kumar, Akash & Yan, Beibei & Chen, Yuxuan & Su, Hong & Chen, Guanyi, 2024. "Insights into behaviors of functional groups in biomass derived products during aqueous phase reforming over Ni/α-MoO3 catalysts," Renewable Energy, Elsevier, vol. 224(C).
    2. Du, Chongzhen & Yang, Tianhua & Li, Bingshuo & Cao, He & Liu, Zheng & Huang, Shengzhao, 2023. "Effect of alkali and alkaline earth metals on the liquefaction of lignocellulosic model compounds to prepare bio-oil in ethanol solvent," Energy, Elsevier, vol. 278(C).
    3. Yang, Tianhua & Du, Chongzhen & Li, Bingshuo & Liu, Zheng & Kai, Xingping, 2022. "Influence of alkali and alkaline earth metals on the hydrothermal liquefaction of lignocellulosic model compounds," Renewable Energy, Elsevier, vol. 188(C), pages 1038-1048.
    4. Guanyu Zhang & Kejie Wang & Quan Liu & Lujia Han & Xuesong Zhang, 2022. "A Comprehensive Hydrothermal Co-Liquefaction of Diverse Biowastes for Energy-Dense Biocrude Production: Synergistic and Antagonistic Effects," IJERPH, MDPI, vol. 19(17), pages 1-17, August.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. SundarRajan, P. & Gopinath, K.P. & Arun, J. & GracePavithra, K. & Adithya Joseph, A. & Manasa, S., 2021. "Insights into valuing the aqueous phase derived from hydrothermal liquefaction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    2. Yang, Jie & (Sophia) He, Quan & Yang, Linxi, 2019. "A review on hydrothermal co-liquefaction of biomass," Applied Energy, Elsevier, vol. 250(C), pages 926-945.
    3. Prajitno, Hermawan & Park, Jongkeun & Ryu, Changkook & Park, Ho Young & Lim, Hyun Soo & Kim, Jaehoon, 2018. "Effects of solvent participation and controlled product separation on biomass liquefaction: A case study of sewage sludge," Applied Energy, Elsevier, vol. 218(C), pages 402-416.
    4. Kamaldeep Sharma & Ayaz A. Shah & Saqib S. Toor & Tahir H. Seehar & Thomas H. Pedersen & Lasse A. Rosendahl, 2021. "Co-Hydrothermal Liquefaction of Lignocellulosic Biomass in Supercritical Water," Energies, MDPI, vol. 14(6), pages 1-13, March.
    5. Siyuan Yin & Nianze Zhang & Chunyan Tian & Weiming Yi & Qiaoxia Yuan & Peng Fu & Yuchun Zhang & Zhiyu Li, 2021. "Effect of Accumulative Recycling of Aqueous Phase on the Properties of Hydrothermal Degradation of Dry Biomass and Bio-Crude Oil Formation," Energies, MDPI, vol. 14(2), pages 1-19, January.
    6. Nikolaos Montesantos & Marco Maschietti, 2020. "Supercritical Carbon Dioxide Extraction of Lignocellulosic Bio-Oils: The Potential of Fuel Upgrading and Chemical Recovery," Energies, MDPI, vol. 13(7), pages 1-35, April.
    7. Tahir H. Seehar & Saqib S. Toor & Ayaz A. Shah & Thomas H. Pedersen & Lasse A. Rosendahl, 2020. "Biocrude Production from Wheat Straw at Sub and Supercritical Hydrothermal Liquefaction," Energies, MDPI, vol. 13(12), pages 1-18, June.
    8. Liu, Quan & Zhang, Guanyu & Liu, Mingyang & Kong, Ge & Xu, Ruolan & Han, Lujia & Zhang, Xuesong, 2022. "Fast hydrothermal liquefaction coupled with homogeneous catalysts to valorize livestock manure for enhanced biocrude oil and hydrochar production," Renewable Energy, Elsevier, vol. 198(C), pages 521-533.
    9. Guanyu Zhang & Kejie Wang & Quan Liu & Lujia Han & Xuesong Zhang, 2022. "A Comprehensive Hydrothermal Co-Liquefaction of Diverse Biowastes for Energy-Dense Biocrude Production: Synergistic and Antagonistic Effects," IJERPH, MDPI, vol. 19(17), pages 1-17, August.
    10. Chen, Xinfei & Ma, Xiaoqian & Zeng, Xianghao & Zheng, Chupeng & Lu, Xiaoluan, 2020. "Ethanol addition during aqueous phase recirculation for further improving bio-oil yield and quality," Applied Energy, Elsevier, vol. 262(C).
    11. Chen, Wei-Hsin & Lin, Yu-Ying & Liu, Hsuan-Cheng & Baroutian, Saeid, 2020. "Optimization of food waste hydrothermal liquefaction by a two-step process in association with a double analysis," Energy, Elsevier, vol. 199(C).
    12. Komeil Kohansal & Kamaldeep Sharma & Saqib Sohail Toor & Eliana Lozano Sanchez & Joscha Zimmermann & Lasse Aistrup Rosendahl & Thomas Helmer Pedersen, 2021. "Bio-Crude Production Improvement during Hydrothermal Liquefaction of Biopulp by Simultaneous Application of Alkali Catalysts and Aqueous Phase Recirculation," Energies, MDPI, vol. 14(15), pages 1-21, July.
    13. Gollakota, A.R.K. & Kishore, Nanda & Gu, Sai, 2018. "A review on hydrothermal liquefaction of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1378-1392.
    14. Ankit Mathanker & Snehlata Das & Deepak Pudasainee & Monir Khan & Amit Kumar & Rajender Gupta, 2021. "A Review of Hydrothermal Liquefaction of Biomass for Biofuels Production with a Special Focus on the Effect of Process Parameters, Co-Solvents, and Extraction Solvents," Energies, MDPI, vol. 14(16), pages 1-60, August.
    15. Yuan, Chuan & Wang, Shuang & Cao, Bin & Hu, Yamin & Abomohra, Abd El-Fatah & Wang, Qian & Qian, Lili & Liu, Lu & Liu, Xinlin & He, Zhixia & Sun, Chaoqun & Feng, Yongqiang & Zhang, Bo, 2019. "Optimization of hydrothermal co-liquefaction of seaweeds with lignocellulosic biomass: Merging 2nd and 3rd generation feedstocks for enhanced bio-oil production," Energy, Elsevier, vol. 173(C), pages 413-422.
    16. Gundupalli, Marttin Paulraj & Bhattacharyya, Debraj, 2021. "Hydrothermal liquefaction of residues of Cocos nucifera (coir and pith) using subcritical water: Process optimization and product characterization," Energy, Elsevier, vol. 236(C).
    17. Li, Qingyin & Yuan, Xiangzhou & Hu, Xun & Meers, Erik & Ong, Hwai Chyuan & Chen, Wei-Hsin & Duan, Peigao & Zhang, Shicheng & Lee, Ki Bong & Ok, Yong Sik, 2022. "Co-liquefaction of mixed biomass feedstocks for bio-oil production: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    18. Shahbeik, Hossein & Kazemi Shariat Panahi, Hamed & Dehhaghi, Mona & Guillemin, Gilles J. & Fallahi, Alireza & Hosseinzadeh-Bandbafha, Homa & Amiri, Hamid & Rehan, Mohammad & Raikwar, Deepak & Latine, , 2024. "Biomass to biofuels using hydrothermal liquefaction: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    19. Daniele Castello & Thomas Helmer Pedersen & Lasse Aistrup Rosendahl, 2018. "Continuous Hydrothermal Liquefaction of Biomass: A Critical Review," Energies, MDPI, vol. 11(11), pages 1-35, November.
    20. Brigljević, Boris & Žuvela, Petar & Liu, J. Jay & Woo, Hee-Chul & Choi, Jae Hyung, 2018. "Development of an automated method for modelling of bio-crudes originating from biofuel production processes based on thermochemical conversion," Applied Energy, Elsevier, vol. 215(C), pages 670-678.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:175:y:2021:i:c:p:98-107. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.