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Design and simulation of an integrated process for biodiesel production from waste cooking oil using supercritical methanolysis

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  • Aboelazayem, Omar
  • Gadalla, Mamdouh
  • Saha, Basudeb

Abstract

Non-catalytic transesterification has been recognised as an effective technique for biodiesel production. It has many advantages over conventional catalytic transesterification, where it eliminates the difficulties of catalysts preparation and separation. It also produces high biodiesel yield in shorter reaction time. However, it requires harsh operating conditions at high reaction temperature and pressure, in addition to using large excess of methanol. In an attempt to mitigate these problems, a process design/integration for biodiesel production has been performed. The process has been subjected to both mass and energy integration to minimise fresh methanol requirements and to minimise heating and cooling energies, respectively. A new graphical Pinch Analysis method has been used to evaluate the energy performance of a literature design for the current process. It has been subsequently used to develop an optimum heat exchanger network (HEN) for the process by matching of process streams. Also, the design made by using an automated commercial simulation (Aspen Energy Analyzer) has been evaluated using the same graphical method. The produced HEN design from graphical method has achieved the optimum results with respect to energy targets.

Suggested Citation

  • Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2018. "Design and simulation of an integrated process for biodiesel production from waste cooking oil using supercritical methanolysis," Energy, Elsevier, vol. 161(C), pages 299-307.
    • Handle: RePEc:eee:energy:v:161:y:2018:i:c:p:299-307
    DOI: 10.1016/j.energy.2018.07.139
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    References listed on IDEAS

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    1. Đurišić-Mladenović, Nataša & Kiss, Ferenc & Škrbić, Biljana & Tomić, Milan & Mićić, Radoslav & Predojević, Zlatica, 2018. "Current state of the biodiesel production and the indigenous feedstock potential in Serbia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 280-291.
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    7. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2018. "Biodiesel production from waste cooking oil via supercritical methanol: Optimisation and reactor simulation," Renewable Energy, Elsevier, vol. 124(C), pages 144-154.
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    1. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2019. "Derivatisation-free characterisation and supercritical conversion of free fatty acids into biodiesel from high acid value waste cooking oil," Renewable Energy, Elsevier, vol. 143(C), pages 77-90.
    2. Aboelazayem, Omar & Gadalla, Mamdouh & Alhajri, Ibrahim & Saha, Basudeb, 2021. "Advanced process integration for supercritical production of biodiesel: Residual waste heat recovery via organic Rankine cycle (ORC)," Renewable Energy, Elsevier, vol. 164(C), pages 433-443.

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