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Catalytic pyrolysis of larch sawdust for phenol-rich bio-oil using different catalysts

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  • Wang, Wenliang
  • Li, Xinping
  • Ye, Dan
  • Cai, LiPing
  • Shi, Sheldon Q.

Abstract

Different kinds of catalysts have a great influence on the characteristics and products of the biomass catalytic pyrolysis. Catalysts of Cu/C, Pd/C, PdAg and H-Zeolites socony mobil #5 (HZSM-5) were selected and characterized by the X-ray diffraction (XRD) and field-emission scanning electron microscope (FE-SEM). Decomposition behaviors of the larch catalytic pyrolysis were studied by the thermogravimetric analyzer (TG). The total carboxylic acids (TCAs) and total phenolic compounds (TPCs) in bio-oil were determined using the non-aqueous potentiometric titration method. The chemical distribution of bio-oil was investigated by the gas chromatography/mass spectrometry (GC/MS). Results showed that the temperature of the maximum weight loss rate of larch was decreased by adding these four catalysts. The carbon residue rate was increased by using HZSM-5. The content of GC-detected phenols increased from 25.28% to 35.11% (area) by adding Pd/C. However, TCAs in bio-oil were decreased sharply with PdAg and Pd/C. HZSM-5 promoted the formation of phenols and enhanced TPCs in bio-oils (26.56 wt%), which increased by approximately 35% compared to that from the non-catalytic pyrolysis process. This phenol-rich bio-oil can be used to replace the traditional phenol for the manufacturing of high-value biomaterials.

Suggested Citation

  • Wang, Wenliang & Li, Xinping & Ye, Dan & Cai, LiPing & Shi, Sheldon Q., 2018. "Catalytic pyrolysis of larch sawdust for phenol-rich bio-oil using different catalysts," Renewable Energy, Elsevier, vol. 121(C), pages 146-152.
    • Handle: RePEc:eee:renene:v:121:y:2018:i:c:p:146-152
    DOI: 10.1016/j.renene.2018.01.018
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    References listed on IDEAS

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    1. Effendi, A. & Gerhauser, H. & Bridgwater, A.V., 2008. "Production of renewable phenolic resins by thermochemical conversion of biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(8), pages 2092-2116, October.
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