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Experimental investigation of steam reforming of methanol over La2CuO4/CuZnAl-oxides nanocatalysts

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  • Zhang, Yidian
  • Guo, Shaopeng
  • Tian, Zhenyu
  • Zhao, Yawen
  • Hao, Yong

Abstract

Nanocatalysts of compound metal oxides (La2CuO4)x(CNZ-1)1−x (x = 0.3, 0.5, 0.7) were prepared. Steam reforming of methanol (SRM) over these nanocatalysts was experimentally studied at a H2O/methanol molar ratio of 1.6. The results showed that the methanol solution catalyzed by all catalysts synthesized in this work could be completely converted into H2, CO2 and a small amount of CO below a reaction temperature of 270 °C with a liquid hourly space velocity (LHSV) of 1.2 ml/(g·h). The catalysts of La2CuO4 and CuO/ZnO/Al2O3 were tested under the same operating conditions. Compared with La2CuO4, LCOx-CNZ showed better performance with a higher methanol conversion rate and H2 yield. Conversely LCO5-CNZ had better CO and H2 selectivity compared with CuO/ZnO/Al2O3. LCO3-CNZ showed good competitiveness in all four above aspects when operated at 150–270 °C. It could be concluded that LCOx-CNZ with special structures provided a significant improvement in catalytic performance of SRM benefiting from the synergistic effect among La2CuO4 and CuZnAl oxides. Thermodynamics analysis and experiments using a hybrid power generation system were applied with the above catalysts. Under direct normal irradiation at 915 W/m2 and a reaction temperature of 230 °C, LCO3-CNZ showed 9.7% higher H2 yield and 3.9% higher net solar power generation efficiency than did Cu/Zn/Al oxides.

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  • Zhang, Yidian & Guo, Shaopeng & Tian, Zhenyu & Zhao, Yawen & Hao, Yong, 2019. "Experimental investigation of steam reforming of methanol over La2CuO4/CuZnAl-oxides nanocatalysts," Applied Energy, Elsevier, vol. 254(C).
    • Handle: RePEc:eee:appene:v:254:y:2019:i:c:s0306261919306439
    DOI: 10.1016/j.apenergy.2019.04.018
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    1. Zhang, Xiaowen & Liu, Helei & Liang, Zhiwu & Idem, Raphael & Tontiwachwuthikul, Paitoon & Jaber Al-Marri, Mohammed & Benamor, Abdelbaki, 2018. "Reducing energy consumption of CO2 desorption in CO2-loaded aqueous amine solution using Al2O3/HZSM-5 bifunctional catalysts," Applied Energy, Elsevier, vol. 229(C), pages 562-576.
    2. Saadabadi, S. Ali & Thallam Thattai, Aditya & Fan, Liyuan & Lindeboom, Ralph E.F. & Spanjers, Henri & Aravind, P.V., 2019. "Solid Oxide Fuel Cells fuelled with biogas: Potential and constraints," Renewable Energy, Elsevier, vol. 134(C), pages 194-214.
    3. Li, Wenjia & Hao, Yong, 2017. "Efficient solar power generation combining photovoltaics and mid-/low-temperature methanol thermochemistry," Applied Energy, Elsevier, vol. 202(C), pages 377-385.
    4. Wang, Hsueh-Sheng & Chang, Cheng-Ping & Huang, Yuh-Jeen & Su, Yu-Chuan & Tseng, Fan-Gang, 2017. "A high-yield and ultra-low-temperature methanol reformer integratable with phosphoric acid fuel cell (PAFC)," Energy, Elsevier, vol. 133(C), pages 1142-1152.
    5. Zhang, Yanwei & Xu, Chenyu & Chen, Jingche & Zhang, Xuhan & Wang, Zhihua & Zhou, Junhu & Cen, Kefa, 2015. "A novel photo-thermochemical cycle for the dissociation of CO2 using solar energy," Applied Energy, Elsevier, vol. 156(C), pages 223-229.
    6. Jiang, Qiongqiong & Zhang, Hao & Deng, Ya'nan & Kang, Qilan & Hong, Hui & Jin, Hongguang, 2018. "Properties and reactivity of LaCuxNi1−xO3 perovskites in chemical-looping combustion for mid-temperature solar-thermal energy storage," Applied Energy, Elsevier, vol. 228(C), pages 1506-1514.
    7. Zhao, Kun & Li, Luwei & Zheng, Anqing & Huang, Zhen & He, Fang & Shen, Yang & Wei, Guoqiang & Li, Haibin & Zhao, Zengli, 2017. "Synergistic improvements in stability and performance of the double perovskite-type oxides La2−xSrxFeCoO6 for chemical looping steam methane reforming," Applied Energy, Elsevier, vol. 197(C), pages 393-404.
    8. Choudhary, Vasant R. & Mondal, Kartick C., 2006. "CO2 reforming of methane combined with steam reforming or partial oxidation of methane to syngas over NdCoO3 perovskite-type mixed metal-oxide catalyst," Applied Energy, Elsevier, vol. 83(9), pages 1024-1032, September.
    9. Yapicioglu, Arda & Dincer, Ibrahim, 2019. "A review on clean ammonia as a potential fuel for power generators," Renewable and Sustainable Energy Reviews, Elsevier, vol. 103(C), pages 96-108.
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    Cited by:

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    2. Xiao Li & Lingzhi Yang & Yong Hao, 2023. "Absorption-Enhanced Methanol Steam Reforming for Low-Temperature Hydrogen Production with Carbon Capture," Energies, MDPI, vol. 16(20), pages 1-16, October.
    3. Fajín, José L.C. & Cordeiro, M. Natália D.S., 2021. "Light alcohols reforming towards renewable hydrogen production on multicomponent catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).

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