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g-C3N4 promoted DBD plasma assisted dry reforming of methane

Author

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  • Ray, Debjyoti
  • Nepak, Devadutta
  • Vinodkumar, T.
  • Subrahmanyam, Ch.

Abstract

The CO2 reforming of CH4 to synthesis gas is performed in a dielectric barrier discharge (DBD) plasma coupled with g-C3N4, g-C3N4/TiO2, g-C3N4/ZnO and g-C3N4/mixed oxide (2.5 wt% ZnO and 2.5 wt% TiO2) catalysts. For CH4 and CO2 gases, the highest conversion is obtained with 5 wt% TiO2 + g-C3N4 and 5 wt% ZnO + g-C3N4, respectively. The g-C3N4 and 5 wt% TiO2 + g-C3N4 catalysts shows poor selectivity towards H2 and CO formation. Whereas, 5 wt% ZnO + g-C3N4 exhibits the highest H2 and CO selectivity. However, with increasing SIE the CO selectivity decreases over 5 wt% ZnO + g-C3N4. The selectivity towards H2 and CO are found to be optimal over 5 wt% MO (1:1) + g-C3N4 and the combination of TiO2 + ZnO coupled with g-C3N4 significantly improves the carbon balance. This optimum performance by 5 wt% MO (1:1) + g-C3N4 in providing the best carbon balance is due to the combination of electronic and acid-base characteristics of the catalysts. The generation of various active species is evidenced by emission spectroscopic study.

Suggested Citation

  • Ray, Debjyoti & Nepak, Devadutta & Vinodkumar, T. & Subrahmanyam, Ch., 2019. "g-C3N4 promoted DBD plasma assisted dry reforming of methane," Energy, Elsevier, vol. 183(C), pages 630-638.
  • Handle: RePEc:eee:energy:v:183:y:2019:i:c:p:630-638
    DOI: 10.1016/j.energy.2019.06.147
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    1. Aleknaviciute, I. & Karayiannis, T.G. & Collins, M.W. & Xanthos, C., 2013. "Methane decomposition under a corona discharge to generate COx-free hydrogen," Energy, Elsevier, vol. 59(C), pages 432-439.
    2. Vita, A. & Italiano, C. & Previtali, D. & Fabiano, C. & Palella, A. & Freni, F. & Bozzano, G. & Pino, L. & Manenti, F., 2018. "Methanol synthesis from biogas: A thermodynamic analysis," Renewable Energy, Elsevier, vol. 118(C), pages 673-684.
    3. Chein, Rei-Yu & Wang, Chien-Yu & Yu, Ching-Tsung, 2017. "Parametric study on catalytic tri-reforming of methane for syngas production," Energy, Elsevier, vol. 118(C), pages 1-17.
    4. Guofeng, Xu & Xinwei, Ding, 2012. "Optimization geometries of a vortex gliding-arc reactor for partial oxidation of methane," Energy, Elsevier, vol. 47(1), pages 333-339.
    5. Chen, Wei-Hsin & Lin, Shih-Cheng, 2015. "Reaction phenomena of catalytic partial oxidation of methane under the impact of carbon dioxide addition and heat recirculation," Energy, Elsevier, vol. 82(C), pages 206-217.
    6. Yang, Yoon-Cheol & Lee, Bong-Ju & Chun, Young-Nam, 2009. "Characteristics of methane reforming using gliding arc reactor," Energy, Elsevier, vol. 34(2), pages 172-177.
    7. Chung, Wei-Chieh & Chang, Moo-Been, 2016. "Review of catalysis and plasma performance on dry reforming of CH4 and possible synergistic effects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 13-31.
    8. Zhang, Xiang & Kätelhön, Arne & Sorda, Giovanni & Helmin, Marta & Rose, Marcus & Bardow, André & Madlener, Reinhard & Palkovits, Regina & Mitsos, Alexander, 2018. "CO2 mitigation costs of catalytic methane decomposition," Energy, Elsevier, vol. 151(C), pages 826-838.
    9. Yang, Yu & Liu, Jing & Shen, Weifeng & Li, Jie & Chien, I-Lung, 2018. "High-efficiency utilization of CO2 in the methanol production by a novel parallel-series system combining steam and dry methane reforming," Energy, Elsevier, vol. 158(C), pages 820-829.
    10. Czylkowski, Dariusz & Hrycak, Bartosz & Jasiński, Mariusz & Dors, Mirosław & Mizeraczyk, Jerzy, 2016. "Microwave plasma-based method of hydrogen production via combined steam reforming of methane," Energy, Elsevier, vol. 113(C), pages 653-661.
    11. Anicic, B. & Trop, P. & Goricanec, D., 2014. "Comparison between two methods of methanol production from carbon dioxide," Energy, Elsevier, vol. 77(C), pages 279-289.
    Full references (including those not matched with items on IDEAS)

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    2. Li, Ziwei & Lin, Qian & Li, Min & Cao, Jianxin & Liu, Fei & Pan, Hongyan & Wang, Zhigang & Kawi, Sibudjing, 2020. "Recent advances in process and catalyst for CO2 reforming of methane," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    3. George, Adwek & Shen, Boxiong & Craven, Michael & Wang, Yaolin & Kang, Dongrui & Wu, Chunfei & Tu, Xin, 2021. "A Review of Non-Thermal Plasma Technology: A novel solution for CO2 conversion and utilization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).

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