IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v183y2019icp630-638.html
   My bibliography  Save this article

g-C3N4 promoted DBD plasma assisted dry reforming of methane

Author

Listed:
  • Ray, Debjyoti
  • Nepak, Devadutta
  • Vinodkumar, T.
  • Subrahmanyam, Ch.

Abstract

The CO2 reforming of CH4 to synthesis gas is performed in a dielectric barrier discharge (DBD) plasma coupled with g-C3N4, g-C3N4/TiO2, g-C3N4/ZnO and g-C3N4/mixed oxide (2.5 wt% ZnO and 2.5 wt% TiO2) catalysts. For CH4 and CO2 gases, the highest conversion is obtained with 5 wt% TiO2 + g-C3N4 and 5 wt% ZnO + g-C3N4, respectively. The g-C3N4 and 5 wt% TiO2 + g-C3N4 catalysts shows poor selectivity towards H2 and CO formation. Whereas, 5 wt% ZnO + g-C3N4 exhibits the highest H2 and CO selectivity. However, with increasing SIE the CO selectivity decreases over 5 wt% ZnO + g-C3N4. The selectivity towards H2 and CO are found to be optimal over 5 wt% MO (1:1) + g-C3N4 and the combination of TiO2 + ZnO coupled with g-C3N4 significantly improves the carbon balance. This optimum performance by 5 wt% MO (1:1) + g-C3N4 in providing the best carbon balance is due to the combination of electronic and acid-base characteristics of the catalysts. The generation of various active species is evidenced by emission spectroscopic study.

Suggested Citation

  • Ray, Debjyoti & Nepak, Devadutta & Vinodkumar, T. & Subrahmanyam, Ch., 2019. "g-C3N4 promoted DBD plasma assisted dry reforming of methane," Energy, Elsevier, vol. 183(C), pages 630-638.
    • Handle: RePEc:eee:energy:v:183:y:2019:i:c:p:630-638
    DOI: 10.1016/j.energy.2019.06.147
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219312794
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2019.06.147?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yang, Yu & Liu, Jing & Shen, Weifeng & Li, Jie & Chien, I-Lung, 2018. "High-efficiency utilization of CO2 in the methanol production by a novel parallel-series system combining steam and dry methane reforming," Energy, Elsevier, vol. 158(C), pages 820-829.
    2. Aleknaviciute, I. & Karayiannis, T.G. & Collins, M.W. & Xanthos, C., 2013. "Methane decomposition under a corona discharge to generate COx-free hydrogen," Energy, Elsevier, vol. 59(C), pages 432-439.
    3. Vita, A. & Italiano, C. & Previtali, D. & Fabiano, C. & Palella, A. & Freni, F. & Bozzano, G. & Pino, L. & Manenti, F., 2018. "Methanol synthesis from biogas: A thermodynamic analysis," Renewable Energy, Elsevier, vol. 118(C), pages 673-684.
    4. Chein, Rei-Yu & Wang, Chien-Yu & Yu, Ching-Tsung, 2017. "Parametric study on catalytic tri-reforming of methane for syngas production," Energy, Elsevier, vol. 118(C), pages 1-17.
    5. Guofeng, Xu & Xinwei, Ding, 2012. "Optimization geometries of a vortex gliding-arc reactor for partial oxidation of methane," Energy, Elsevier, vol. 47(1), pages 333-339.
    6. Chen, Wei-Hsin & Lin, Shih-Cheng, 2015. "Reaction phenomena of catalytic partial oxidation of methane under the impact of carbon dioxide addition and heat recirculation," Energy, Elsevier, vol. 82(C), pages 206-217.
    7. Czylkowski, Dariusz & Hrycak, Bartosz & Jasiński, Mariusz & Dors, Mirosław & Mizeraczyk, Jerzy, 2016. "Microwave plasma-based method of hydrogen production via combined steam reforming of methane," Energy, Elsevier, vol. 113(C), pages 653-661.
    8. Anicic, B. & Trop, P. & Goricanec, D., 2014. "Comparison between two methods of methanol production from carbon dioxide," Energy, Elsevier, vol. 77(C), pages 279-289.
    9. Yang, Yoon-Cheol & Lee, Bong-Ju & Chun, Young-Nam, 2009. "Characteristics of methane reforming using gliding arc reactor," Energy, Elsevier, vol. 34(2), pages 172-177.
    10. Chung, Wei-Chieh & Chang, Moo-Been, 2016. "Review of catalysis and plasma performance on dry reforming of CH4 and possible synergistic effects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 13-31.
    11. Zhang, Xiang & Kätelhön, Arne & Sorda, Giovanni & Helmin, Marta & Rose, Marcus & Bardow, André & Madlener, Reinhard & Palkovits, Regina & Mitsos, Alexander, 2018. "CO2 mitigation costs of catalytic methane decomposition," Energy, Elsevier, vol. 151(C), pages 826-838.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Feng, Rong & Zhu, Jiajian & Wang, Zhenguo & Sun, Mingbo & Wang, Hongbo & Cai, Zun & An, Bin & Li, Liang, 2021. "Ignition modes of a cavity-based scramjet combustor by a gliding arc plasma," Energy, Elsevier, vol. 214(C).
    2. Li, Ziwei & Lin, Qian & Li, Min & Cao, Jianxin & Liu, Fei & Pan, Hongyan & Wang, Zhigang & Kawi, Sibudjing, 2020. "Recent advances in process and catalyst for CO2 reforming of methane," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    3. George, Adwek & Shen, Boxiong & Craven, Michael & Wang, Yaolin & Kang, Dongrui & Wu, Chunfei & Tu, Xin, 2021. "A Review of Non-Thermal Plasma Technology: A novel solution for CO2 conversion and utilization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chein, Rei-Yu & Lu, Cheng-Yang & Chen, Wei-Hsin, 2022. "Syngas production via chemical looping reforming using methane-based feed and NiO/Al2O3 oxygen carrier," Energy, Elsevier, vol. 250(C).
    2. Kotowicz, Janusz & Węcel, Daniel & Brzęczek, Mateusz, 2021. "Analysis of the work of a “renewable” methanol production installation based ON H2 from electrolysis and CO2 from power plants," Energy, Elsevier, vol. 221(C).
    3. Alves, Luís & Pereira, Vítor & Lagarteira, Tiago & Mendes, Adélio, 2021. "Catalytic methane decomposition to boost the energy transition: Scientific and technological advancements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    4. Siang, T.J. & Jalil, A.A. & Abdulrasheed, A.A. & Hambali, H.U. & Nabgan, Walid, 2020. "Thermodynamic equilibrium study of altering methane partial oxidation for Fischer–Tropsch synfuel production," Energy, Elsevier, vol. 198(C).
    5. Czylkowski, Dariusz & Hrycak, Bartosz & Jasiński, Mariusz & Dors, Mirosław & Mizeraczyk, Jerzy, 2016. "Microwave plasma-based method of hydrogen production via combined steam reforming of methane," Energy, Elsevier, vol. 113(C), pages 653-661.
    6. Wachter, Philipp & Gaber, Christian & Demuth, Martin & Hochenauer, Christoph, 2020. "Experimental investigation of tri-reforming on a stationary, recuperative TCR-reformer applied to an oxy-fuel combustion of natural gas, using a Ni-catalyst," Energy, Elsevier, vol. 212(C).
    7. Majidi Bidgoli, Abbas & Ghorbanzadeh, Atamalek & Lotfalipour, Raheleh & Roustaei, Ehsan & Zakavi, Marjan, 2017. "Gliding spark plasma: Physical principles and performance in direct pyrolysis of methane," Energy, Elsevier, vol. 125(C), pages 705-715.
    8. Xin, Yanbin & Sun, Bing & Zhu, Xiaomei & Yan, Zhiyu & Sun, Xiaohang, 2021. "Hydrogen-rich syngas production by liquid phase pulsed electrodeless discharge," Energy, Elsevier, vol. 214(C).
    9. Rosha, Pali & Mohapatra, Saroj Kumar & Mahla, Sunil Kumar & Dhir, Amit, 2019. "Hydrogen enrichment of biogas via dry and autothermal-dry reforming with pure nickel (Ni) nanoparticle," Energy, Elsevier, vol. 172(C), pages 733-739.
    10. Kim, Dongin & Han, Jeehoon, 2020. "Comprehensive analysis of two catalytic processes to produce formic acid from carbon dioxide," Applied Energy, Elsevier, vol. 264(C).
    11. Elhambakhsh, Abbas & Van Duc Long, Nguyen & Lamichhane, Pradeep & Hessel, Volker, 2023. "Recent progress and future directions in plasma-assisted biomass conversion to hydrogen," Renewable Energy, Elsevier, vol. 218(C).
    12. Konrad, Kai A. & Lommerud, Kjell Erik, 2021. "Effective climate policy needs non-combustion uses for hydrocarbons," Energy Policy, Elsevier, vol. 157(C).
    13. Park, Min-Ju & Kim, Hak-Min & Gu, Yun-Jeong & Jeong, Dae-Woon, 2023. "Optimization of biogas-reforming conditions considering carbon formation, hydrogen production, and energy efficiencies," Energy, Elsevier, vol. 265(C).
    14. Kęstutis Venslauskas & Kęstutis Navickas & Marja Nappa & Petteri Kangas & Revilija Mozūraitytė & Rasa Šližytė & Vidmantas Župerka, 2021. "Energetic and Economic Evaluation of Zero-Waste Fish Co-Stream Processing," IJERPH, MDPI, vol. 18(5), pages 1-16, February.
    15. Peng, Qingguo & Yang, Wenming & E, Jiaqiang & Li, Shaobo & Li, Zhenwei & Xu, Hongpeng & Fu, Guang, 2021. "Effects of propane addition and burner scale on the combustion characteristics and working performance," Applied Energy, Elsevier, vol. 285(C).
    16. Wang, Guoqiang & Wang, Feng & Li, Longjian & Zhang, Guofu, 2013. "Experiment of catalyst activity distribution effect on methanol steam reforming performance in the packed bed plate-type reactor," Energy, Elsevier, vol. 51(C), pages 267-272.
    17. Wang, Qiuying & Zhu, Xiaomei & Sun, Bing & Li, Zhi & Liu, Jinglin, 2022. "Hydrogen production from methane via liquid phase microwave plasma: A deoxidation strategy," Applied Energy, Elsevier, vol. 328(C).
    18. Oner, Oytun & Khalilpour, Kaveh, 2022. "Evaluation of green hydrogen carriers: A multi-criteria decision analysis tool," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    19. Chen, Zong & Zhang, Rongjun & Xia, Guofu & Wu, Yu & Li, Hongwei & Sun, Zhao & Sun, Zhiqiang, 2021. "Vacuum promoted methane decomposition for hydrogen production with carbon separation: Parameter optimization and economic assessment," Energy, Elsevier, vol. 222(C).
    20. Wan, Jianlong & Fan, Aiwu & Yao, Hong & Liu, Wei, 2016. "Experimental investigation and numerical analysis on the blow-off limits of premixed CH4/air flames in a mesoscale bluff-body combustor," Energy, Elsevier, vol. 113(C), pages 193-203.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:183:y:2019:i:c:p:630-638. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.