IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v55y2013icp933-938.html
   My bibliography  Save this article

Synergistic hydrogen desorption of HCS MgH2 + LiAlH4 composite

Author

Listed:
  • Ding, Xiangqian
  • Zhu, Yunfeng
  • Wei, Lingjun
  • Li, Ying
  • Li, Liquan

Abstract

MgH2 was prepared by HCS (hydriding combustion synthesis) method, and the as-prepared product (HCS MgH2) was further combined with LiAlH4 by mechanical milling in order to form a new composite of HCS MgH2 + LiAlH4. Structural and hydrogen storage properties of the HCS MgH2 + LiAlH4 composite have been investigated systematically by XRD (X-ray diffraction), SEM (scanning electron microscope), DSC (differential scanning calorimetry) and hydrogenation/dehydrogenation measurements. A mutual destabilization effect has been observed between HCS MgH2 and LiAlH4 during hydrogen desorption. The dehydrogenation mechanism of the composite has been revealed. Compared with commercial MgH2 (Com MgH2) + LiAlH4 composite, the HCS MgH2 + LiAlH4 composite shows more pronounced synergistic hydrogen desorption with notably decreased dehydrogenation temperature owing to the unique microstructures of the HCS MgH2, which may provide favorable channels for diffusion of hydrogen atoms and promote synergistic hydrogen desorption of the composite. The dehydrogenation barrier of the HCS MgH2 + LiAlH4 composite is lower than that of the Com MgH2 + LiAlH4 composite. Moreover, the HCS MgH2 + LiAlH4 composite exhibits fast re-hydrogenation kinetics in the first two cycles.

Suggested Citation

  • Ding, Xiangqian & Zhu, Yunfeng & Wei, Lingjun & Li, Ying & Li, Liquan, 2013. "Synergistic hydrogen desorption of HCS MgH2 + LiAlH4 composite," Energy, Elsevier, vol. 55(C), pages 933-938.
    • Handle: RePEc:eee:energy:v:55:y:2013:i:c:p:933-938
    DOI: 10.1016/j.energy.2013.04.043
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S036054421300354X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2013.04.043?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Carton, J.G. & Olabi, A.G., 2010. "Design of experiment study of the parameters that affect performance of three flow plate configurations of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 35(7), pages 2796-2806.
    2. Fan, Mei-Qiang & Liu, Shu-sheng & Zhang, Yao & Zhang, Jian & Sun, Li-Xian & Xu, Fen, 2010. "Superior hydrogen storage properties of MgH2–10 wt.% TiC composite," Energy, Elsevier, vol. 35(8), pages 3417-3421.
    3. Pukazhselvan, D. & Hudson, M. Sterlin Leo & Sinha, A.S.K. & Srivastava, O.N., 2010. "Studies on metal oxide nanoparticles catalyzed sodium aluminum hydride," Energy, Elsevier, vol. 35(12), pages 5037-5042.
    4. Barbir, Frano, 2009. "Transition to renewable energy systems with hydrogen as an energy carrier," Energy, Elsevier, vol. 34(3), pages 308-312.
    5. Louis Schlapbach & Andreas Züttel, 2001. "Hydrogen-storage materials for mobile applications," Nature, Nature, vol. 414(6861), pages 353-358, November.
    6. Principi, G. & Agresti, F. & Maddalena, A. & Lo Russo, S., 2009. "The problem of solid state hydrogen storage," Energy, Elsevier, vol. 34(12), pages 2087-2091.
    7. Carton, J.G. & Lawlor, V. & Olabi, A.G. & Hochenauer, C. & Zauner, G., 2012. "Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels," Energy, Elsevier, vol. 39(1), pages 63-73.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Wei & Cheng, Ying & Han, Da & Han, Shumin, 2015. "The hydrogen storage properties of MgH2–Fe3S4 composites," Energy, Elsevier, vol. 93(P1), pages 625-630.
    2. Ismail, M., 2015. "Effect of LaCl3 addition on the hydrogen storage properties of MgH2," Energy, Elsevier, vol. 79(C), pages 177-182.
    3. Kou, Huaqin & Luo, Wenhua & Huang, Zhiyong & Sang, Ge & Meng, Daqiao & Zhang, Guanghui & Chen, Changan & Luo, Deli & Hu, Changwen, 2015. "Fabrication and experimental validation of a full-scale depleted uranium bed with thin double-layered annulus configuration for hydrogen isotopes recovery and delivery," Energy, Elsevier, vol. 90(P1), pages 588-594.
    4. Öz, Çisem & Coşkuner Filiz, Bilge & Kantürk Figen, Aysel, 2017. "The effect of vinegar–acetic acid solution on the hydrogen generation performance of mechanochemically modified Magnesium (Mg) granules," Energy, Elsevier, vol. 127(C), pages 328-334.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Kou, Huaqin & Luo, Wenhua & Huang, Zhiyong & Sang, Ge & Meng, Daqiao & Zhang, Guanghui & Chen, Changan & Luo, Deli & Hu, Changwen, 2015. "Fabrication and experimental validation of a full-scale depleted uranium bed with thin double-layered annulus configuration for hydrogen isotopes recovery and delivery," Energy, Elsevier, vol. 90(P1), pages 588-594.
    2. Gkanas, Evangelos I. & Khzouz, Martin & Panagakos, Grigorios & Statheros, Thomas & Mihalakakou, Giouli & Siasos, Gerasimos I. & Skodras, Georgios & Makridis, Sofoklis S., 2018. "Hydrogenation behavior in rectangular metal hydride tanks under effective heat management processes for green building applications," Energy, Elsevier, vol. 142(C), pages 518-530.
    3. Ma, Li-Juan & Wang, Jianfeng & Han, Min & Jia, Jianfeng & Wu, Hai-Shun & Zhang, Xiang, 2019. "Adsorption of multiple H2 molecules on the complex TiC6H6: An unusual combination of chemisorption and physisorption," Energy, Elsevier, vol. 171(C), pages 315-325.
    4. Kumar, Sandeep & Dhilip Kumar, T.J., 2020. "Hydrogen trapping potential of Ca decorated metal-graphyne framework," Energy, Elsevier, vol. 199(C).
    5. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    6. Chung, Kyong-Hwan, 2010. "High-pressure hydrogen storage on microporous zeolites with varying pore properties," Energy, Elsevier, vol. 35(5), pages 2235-2241.
    7. Okur, Osman & İyigün Karadağ, Çiğdem & Boyacı San, Fatma Gül & Okumuş, Emin & Behmenyar, Gamze, 2013. "Optimization of parameters for hot-pressing manufacture of membrane electrode assembly for PEM (polymer electrolyte membrane fuel cells) fuel cell," Energy, Elsevier, vol. 57(C), pages 574-580.
    8. Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    9. Yuan, Zhenyu & Yang, Jie & Li, Xiaoyang & Wang, Shikai, 2016. "The micro-scale analysis of the micro direct methanol fuel cell," Energy, Elsevier, vol. 100(C), pages 10-17.
    10. Wang, Junye, 2015. "Theory and practice of flow field designs for fuel cell scaling-up: A critical review," Applied Energy, Elsevier, vol. 157(C), pages 640-663.
    11. Perng, Shiang-Wuu & Wu, Horng-Wen & Shih, Gin-Jang, 2015. "Effect of prominent gas diffusion layer (GDL) on non-isothermal transport characteristics and cell performance of a proton exchange membrane fuel cell (PEMFC)," Energy, Elsevier, vol. 88(C), pages 126-138.
    12. Rahnavard, Aylin & Rowshanzamir, Soosan & Parnian, Mohammad Javad & Amirkhanlou, Gholam Reza, 2015. "The effect of sulfonated poly (ether ether ketone) as the electrode ionomer for self-humidifying nanocomposite proton exchange membrane fuel cells," Energy, Elsevier, vol. 82(C), pages 746-757.
    13. Kalamse, Vijayanand & Wadnerkar, Nitin & Chaudhari, Ajay, 2013. "Multi-functionalized naphthalene complexes for hydrogen storage," Energy, Elsevier, vol. 49(C), pages 469-474.
    14. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Investigation of NaOH concentration effect in injected fuel on the performance of passive direct methanol alkaline fuel cell with modified cation exchange membrane," Energy, Elsevier, vol. 94(C), pages 589-599.
    15. Yuan, Zhenyu & Yang, Jie & Zhang, Yufeng & Wang, Shikai & Xu, Tingnian, 2015. "Mass transport optimization in the anode diffusion layer of a micro direct methanol fuel cell," Energy, Elsevier, vol. 93(P1), pages 599-605.
    16. El-Eskandarany, M. Sherif & Al-Matrouk, H. & Shaban, Ehab & Al-Duweesh, Ahmed, 2015. "Superior catalytic effect of nanocrystalline big-cube Zr2Ni metastable phase for improving the hydrogen sorption/desorption kinetics and cyclability of MgH2 powders," Energy, Elsevier, vol. 91(C), pages 274-282.
    17. Díaz, Manuel Antonio & Iranzo, Alfredo & Rosa, Felipe & Isorna, Fernando & López, Eduardo & Bolivar, Juan Pedro, 2015. "Effect of carbon dioxide on the contamination of low temperature and high temperature PEM (polymer electrolyte membrane) fuel cells. Influence of temperature, relative humidity and analysis of regener," Energy, Elsevier, vol. 90(P1), pages 299-309.
    18. An, Myung-Gi & Mehmood, Asad & Hwang, Jinyeon & Ha, Heung Yong, 2016. "A novel method of methanol concentration control through feedback of the amplitudes of output voltage fluctuations for direct methanol fuel cells," Energy, Elsevier, vol. 100(C), pages 217-226.
    19. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Study of physicochemical characterization of potassium-doped Nafion117 membrane and performance evaluation of air-breathing fuel cell in different alkali-methanol solutions," Energy, Elsevier, vol. 113(C), pages 1090-1098.
    20. Wang, Luwen & He, Mingyan & Hu, Yue & Zhang, Yufeng & Liu, Xiaowei & Wang, Gaofeng, 2015. "A “4-cell” modular passive DMFC (direct methanol fuel cell) stack for portable applications," Energy, Elsevier, vol. 82(C), pages 229-235.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:55:y:2013:i:c:p:933-938. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.