IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v90y2015ip1p344-350.html
   My bibliography  Save this article

High-performance solid oxide electrolysis cell based on ScSZ/GDC (scandia-stabilized zirconia/gadolinium-doped ceria) bi-layered electrolyte and LSCF (lanthanum strontium cobalt ferrite) oxygen electrode

Author

Listed:
  • Mahmood, Asif
  • Bano, Saira
  • Yu, Ji Haeng
  • Lee, Kew-Ho

Abstract

The work presented focuses on the development and performance evaluation of Ni-YSZ (nickel-yttria-stabilized zirconia) supported solid oxide cell with bi-layered ScSZ/GDC electrolyte structure and LSCF (lanthanum strontium cobalt ferrite) oxygen electrode in high-temperature steam and carbon dioxide electrolysis. At 800 °C, the cell exhibited a very high electrolysis current density of about −2.2 A/cm2 and −1.9 A/cm2 in steam and CO2 electrolysis, respectively. A slightly lower ASR (area specific resistance) is observed in electrolysis mode when compared to fuel-cell mode. Moreover, the ASR is increased when increasing the CO2 concentration in both modes of operation. The OCV (open circuit voltage) of SOEC with bi-layered electrolyte structure is significantly improved than the cell with single-layered GDC (gadolinium-doped ceria) electrolyte but at the cost of an increase in the ohmic resistance (Rs) of cell. The formation of (Zr, Ce)O2−x solid solution by the mutual diffusion of zirconium and cerium during co-sintering is found to be the origin of the increase in the Rs. Impedance spectra revealed that the high electrolysis performance is caused by the low polarization losses at LSCF oxygen electrode rather than the thin bi-layered ScSZ/GDC electrolyte structure.

Suggested Citation

  • Mahmood, Asif & Bano, Saira & Yu, Ji Haeng & Lee, Kew-Ho, 2015. "High-performance solid oxide electrolysis cell based on ScSZ/GDC (scandia-stabilized zirconia/gadolinium-doped ceria) bi-layered electrolyte and LSCF (lanthanum strontium cobalt ferrite) oxygen electr," Energy, Elsevier, vol. 90(P1), pages 344-350.
    • Handle: RePEc:eee:energy:v:90:y:2015:i:p1:p:344-350
    DOI: 10.1016/j.energy.2015.06.109
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544215008658
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2015.06.109?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Becker, W.L. & Braun, R.J. & Penev, M. & Melaina, M., 2012. "Production of Fischer–Tropsch liquid fuels from high temperature solid oxide co-electrolysis units," Energy, Elsevier, vol. 47(1), pages 99-115.
    2. Luo, Yu & Shi, Yixiang & Li, Wenying & Cai, Ningsheng, 2014. "Comprehensive modeling of tubular solid oxide electrolysis cell for co-electrolysis of steam and carbon dioxide," Energy, Elsevier, vol. 70(C), pages 420-434.
    3. Ridjan, Iva & Mathiesen, Brian Vad & Connolly, David, 2014. "Synthetic fuel production costs by means of solid oxide electrolysis cells," Energy, Elsevier, vol. 76(C), pages 104-113.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gómez, Sergio Yesid & Hotza, Dachamir, 2016. "Current developments in reversible solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 155-174.
    2. AlZahrani, Abdullah A. & Dincer, Ibrahim, 2022. "Assessment of a thin-electrolyte solid oxide cell for hydrogen production," Energy, Elsevier, vol. 243(C).
    3. Lee, Dong-Young & Mehran, Muhammad Taqi & Kim, Jonghwan & Kim, Sangcho & Lee, Seung-Bok & Song, Rak-Hyun & Ko, Eun-Yong & Hong, Jong-Eun & Huh, Joo-Youl & Lim, Tak-Hyoung, 2020. "Scaling up syngas production with controllable H2/CO ratio in a highly efficient, compact, and durable solid oxide coelectrolysis cell unit-bundle," Applied Energy, Elsevier, vol. 257(C).
    4. Asensio, Antonio Maria & Clematis, Davide & Viviani, Massimo & Carpanese, M. Paola & Presto, Sabrina & Cademartori, Davide & Cabot, Pere L. & Barbucci, Antonio, 2021. "Impregnation of microporous SDC scaffold as stable solid oxide cell BSCF-based air electrode," Energy, Elsevier, vol. 237(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Brynolf, Selma & Taljegard, Maria & Grahn, Maria & Hansson, Julia, 2018. "Electrofuels for the transport sector: A review of production costs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1887-1905.
    2. Freire Ordóñez, Diego & Shah, Nilay & Guillén-Gosálbez, Gonzalo, 2021. "Economic and full environmental assessment of electrofuels via electrolysis and co-electrolysis considering externalities," Applied Energy, Elsevier, vol. 286(C).
    3. Xu, Haoran & Maroto-Valer, M. Mercedes & Ni, Meng & Cao, Jun & Xuan, Jin, 2019. "Low carbon fuel production from combined solid oxide CO2 co-electrolysis and Fischer-Tropsch synthesis system: A modelling study," Applied Energy, Elsevier, vol. 242(C), pages 911-918.
    4. Morgenthaler, Simon & Kuckshinrichs, Wilhelm & Witthaut, Dirk, 2020. "Optimal system layout and locations for fully renewable high temperature co-electrolysis," Applied Energy, Elsevier, vol. 260(C).
    5. Samavati, Mahrokh & Santarelli, Massimo & Martin, Andrew & Nemanova, Vera, 2017. "Thermodynamic and economy analysis of solid oxide electrolyser system for syngas production," Energy, Elsevier, vol. 122(C), pages 37-49.
    6. Luo, Yu & Shi, Yixiang & Li, Wenying & Cai, Ningsheng, 2015. "Dynamic electro-thermal modeling of co-electrolysis of steam and carbon dioxide in a tubular solid oxide electrolysis cell," Energy, Elsevier, vol. 89(C), pages 637-647.
    7. Stempien, Jan Pawel & Ni, Meng & Sun, Qiang & Chan, Siew Hwa, 2015. "Production of sustainable methane from renewable energy and captured carbon dioxide with the use of Solid Oxide Electrolyzer: A thermodynamic assessment," Energy, Elsevier, vol. 82(C), pages 714-721.
    8. Yang, Chao & Jing, Xiuhui & Miao, He & Wu, Yu & Shu, Chen & Wang, Jiatang & Zhang, Houcheng & Yu, Guojun & Yuan, Jinliang, 2020. "Analysis of effects of meso-scale reactions on multiphysics transport processes in rSOFC fueled with syngas," Energy, Elsevier, vol. 190(C).
    9. Lechtenböhmer, Stefan & Nilsson, Lars J. & Åhman, Max & Schneider, Clemens, 2016. "Decarbonising the energy intensive basic materials industry through electrification – Implications for future EU electricity demand," Energy, Elsevier, vol. 115(P3), pages 1623-1631.
    10. König, Daniel H. & Baucks, Nadine & Dietrich, Ralph-Uwe & Wörner, Antje, 2015. "Simulation and evaluation of a process concept for the generation of synthetic fuel from CO2 and H2," Energy, Elsevier, vol. 91(C), pages 833-841.
    11. Luo, Yu & Shi, Yixiang & Li, Wenying & Cai, Ningsheng, 2014. "Comprehensive modeling of tubular solid oxide electrolysis cell for co-electrolysis of steam and carbon dioxide," Energy, Elsevier, vol. 70(C), pages 420-434.
    12. Bedoić, Robert & Dorotić, Hrvoje & Schneider, Daniel Rolph & Čuček, Lidija & Ćosić, Boris & Pukšec, Tomislav & Duić, Neven, 2021. "Synergy between feedstock gate fee and power-to-gas: An energy and economic analysis of renewable methane production in a biogas plant," Renewable Energy, Elsevier, vol. 173(C), pages 12-23.
    13. Mathiesen, B.V. & Lund, H. & Connolly, D. & Wenzel, H. & Østergaard, P.A. & Möller, B. & Nielsen, S. & Ridjan, I. & Karnøe, P. & Sperling, K. & Hvelplund, F.K., 2015. "Smart Energy Systems for coherent 100% renewable energy and transport solutions," Applied Energy, Elsevier, vol. 145(C), pages 139-154.
    14. Xiao, Gang & Sun, Anwei & Liu, Hongwei & Ni, Meng & Xu, Haoran, 2023. "Thermal management of reversible solid oxide cells in the dynamic mode switching," Applied Energy, Elsevier, vol. 331(C).
    15. Qin, Shiyue & Chang, Shiyan & Yao, Qiang, 2018. "Modeling, thermodynamic and techno-economic analysis of coal-to-liquids process with different entrained flow coal gasifiers," Applied Energy, Elsevier, vol. 229(C), pages 413-432.
    16. Chen, Bin & Xu, Haoran & Ni, Meng, 2017. "Modelling of SOEC-FT reactor: Pressure effects on methanation process," Applied Energy, Elsevier, vol. 185(P1), pages 814-824.
    17. Mahbub, Md Shahriar & Cozzini, Marco & Østergaard, Poul Alberg & Alberti, Fabrizio, 2016. "Combining multi-objective evolutionary algorithms and descriptive analytical modelling in energy scenario design," Applied Energy, Elsevier, vol. 164(C), pages 140-151.
    18. Shafiei, Ehsan & Davidsdottir, Brynhildur & Leaver, Jonathan & Stefansson, Hlynur & Asgeirsson, Eyjolfur Ingi, 2015. "Comparative analysis of hydrogen, biofuels and electricity transitional pathways to sustainable transport in a renewable-based energy system," Energy, Elsevier, vol. 83(C), pages 614-627.
    19. Cinti, Giovanni & Baldinelli, Arianna & Di Michele, Alessandro & Desideri, Umberto, 2016. "Integration of Solid Oxide Electrolyzer and Fischer-Tropsch: A sustainable pathway for synthetic fuel," Applied Energy, Elsevier, vol. 162(C), pages 308-320.
    20. Quarton, Christopher J. & Samsatli, Sheila, 2020. "The value of hydrogen and carbon capture, storage and utilisation in decarbonising energy: Insights from integrated value chain optimisation," Applied Energy, Elsevier, vol. 257(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:90:y:2015:i:p1:p:344-350. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.