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Thermodynamic analysis of combined Solid Oxide Electrolyzer and Fischer–Tropsch processes

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  • Stempien, Jan Pawel
  • Ni, Meng
  • Sun, Qiang
  • Chan, Siew Hwa

Abstract

In this paper a thermodynamic analysis and simple optimization of a combined Solid Oxide Electrolyzer Cell and Fisher–Tropsch Synthesis processes for sustainable hydrocarbons fuel production is reported. Comprehensive models are employed to describe effects of temperature, pressure, reactant composition and molar flux and flow on the system efficiency and final production distribution. The electrolyzer model was developed in-house and validated with experimental data of a typical Solid Oxide Electrolyzer. The Fischer–Tropsch Synthesis model employed lumped kinetics of syngas utilization, which includes inhibiting effect of water content and kinetics of Water–Gas Shift reaction. Product distribution model incorporated olefin re-adsorption and varying physisorption and solubility of hydrocarbons with their carbon number. The results were compared with those reported by Becker et al. with simplified analysis of such process. In the present study an opposite effect of operation at elevated pressure was observed. Proposed optimized system achieved overall efficiency of 66.67% and almost equal spread of light- (31%wt), mid-(36%wt) and heavy-hydrocarbons (33%wt). Paraffins contributed the majority of the yield.

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  • Stempien, Jan Pawel & Ni, Meng & Sun, Qiang & Chan, Siew Hwa, 2015. "Thermodynamic analysis of combined Solid Oxide Electrolyzer and Fischer–Tropsch processes," Energy, Elsevier, vol. 81(C), pages 682-690.
    • Handle: RePEc:eee:energy:v:81:y:2015:i:c:p:682-690
    DOI: 10.1016/j.energy.2015.01.013
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    1. Connolly, D. & Mathiesen, B.V. & Ridjan, I., 2014. "A comparison between renewable transport fuels that can supplement or replace biofuels in a 100% renewable energy system," Energy, Elsevier, vol. 73(C), pages 110-125.
    2. Graves, Christopher & Ebbesen, Sune D. & Mogensen, Mogens & Lackner, Klaus S., 2011. "Sustainable hydrocarbon fuels by recycling CO2 and H2O with renewable or nuclear energy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 1-23, January.
    3. Becker, W.L. & Braun, R.J. & Penev, M. & Melaina, M., 2012. "Production of Fischer–Tropsch liquid fuels from high temperature solid oxide co-electrolysis units," Energy, Elsevier, vol. 47(1), pages 99-115.
    4. Stempien, Jan Pawel & Sun, Qiang & Chan, Siew Hwa, 2013. "Performance of power generation extension system based on solid-oxide electrolyzer cells under various design conditions," Energy, Elsevier, vol. 55(C), pages 647-657.
    5. Haarlemmer, Geert & Boissonnet, Guillaume & Peduzzi, Emanuela & Setier, Pierre-Alexandre, 2014. "Investment and production costs of synthetic fuels – A literature survey," Energy, Elsevier, vol. 66(C), pages 667-676.
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    Cited by:

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    14. Mahrokh Samavati & Andrew Martin & Massimo Santarelli & Vera Nemanova, 2018. "Synthetic Diesel Production as a Form of Renewable Energy Storage," Energies, MDPI, vol. 11(5), pages 1-21, May.
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