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Highly reversible lithium storage in uniform Li4Ti5O12/carbon hybrid nanowebs as anode material for lithium-ion batteries

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  • Yang, Zunxian
  • Meng, Qing
  • Guo, Zaiping
  • Yu, Xuebin
  • Guo, Tailiang
  • Zeng, Rong

Abstract

Very large area, uniform Li4Ti5O12/carbon composite nanowebs consisting of interconnected nanofibers were synthesized by a simple method based on thermal pyrolysis and oxidation of a composite of electrospun lithium–titanium/polyacrylonitrile nanowebs in argon atmosphere. This novel composite is characterized by the encapsulation of highly uniform nanoscale Li4Ti5O12 crystals in the porous cotton-like carbon matrix. This unique structure, consisting of ultra-small crystals in carbon core/shell architecture, is also characterized by high porosity, with many nanopores and mesopores in the composite, and this, together with the high conductive carbon matrix, would facilitate the excellent electrochemical performance of Li4Ti5O12/carbon composite nanoweb electrode. The Li4Ti5O12/carbon hybrid nanoweb electrodes display a reversible capacity of approximately 160.8 mAhg−1 at a current density of 30 mAg−1 and excellent cycling stability. The Li4Ti5O12/carbon hybrid nanoweb electrodes also exhibit excellent rate performance, delivering a discharge capacity of over 87 mAhg−1 at a current density of 3000 mAg−1. These results indicate that the composite is a promising anode candidate for lithium ion batteries.

Suggested Citation

  • Yang, Zunxian & Meng, Qing & Guo, Zaiping & Yu, Xuebin & Guo, Tailiang & Zeng, Rong, 2013. "Highly reversible lithium storage in uniform Li4Ti5O12/carbon hybrid nanowebs as anode material for lithium-ion batteries," Energy, Elsevier, vol. 55(C), pages 925-932.
    • Handle: RePEc:eee:energy:v:55:y:2013:i:c:p:925-932
    DOI: 10.1016/j.energy.2013.01.055
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    5. Eddahech, Akram & Briat, Olivier & Vinassa, Jean-Michel, 2015. "Performance comparison of four lithium–ion battery technologies under calendar aging," Energy, Elsevier, vol. 84(C), pages 542-550.
    6. Wang, Mingyue & Huang, Ying & Wang, Ke & Zhu, Yade & Zhang, Na & Zhang, Hongming & Li, Suping & Feng, Zhenhe, 2018. "PVD synthesis of binder-free silicon and carbon coated 3D α-Fe2O3 nanorods hybrid films as high-capacity and long-life anode for flexible lithium-ion batteries," Energy, Elsevier, vol. 164(C), pages 1021-1029.
    7. Cauda, Valentina & Pugliese, Diego & Garino, Nadia & Sacco, Adriano & Bianco, Stefano & Bella, Federico & Lamberti, Andrea & Gerbaldi, Claudio, 2014. "Multi-functional energy conversion and storage electrodes using flower-like Zinc oxide nanostructures," Energy, Elsevier, vol. 65(C), pages 639-646.
    8. Kim, Hong-Ki & Lee, Seung-Hwan, 2016. "Enhanced electrochemical performances of cylindrical hybrid supercapacitors using activated carbon/ Li4-xMxTi5-yNyO12 (M=Na, N=V, Mn) electrodes," Energy, Elsevier, vol. 109(C), pages 506-511.
    9. Jiang, Zhibin & Chen, Ling & Zhang, Wenguang & Chen, Shiyu & Jian, Xiying & Liu, Xiang & Chen, Hongyu & Guo, Chunlei & Li, Weishan, 2021. "Sandwich-like NOCC@S8/rGO composite as cathode for high energy lithium-sulfur batteries," Energy, Elsevier, vol. 220(C).
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    11. Jagadale, Ajay D. & Kumbhar, Vijay S. & Bulakhe, Ravindra N. & Lokhande, Chandrakant D., 2014. "Influence of electrodeposition modes on the supercapacitive performance of Co3O4 electrodes," Energy, Elsevier, vol. 64(C), pages 234-241.
    12. Bai, Hongwei & Liu, Zhaoyang & Sun, Darren Delai & Chan, Siew Hwa, 2014. "Hierarchical 3D micro-/nano-V2O5 (vanadium pentoxide) spheres as cathode materials for high-energy and high-power lithium ion-batteries," Energy, Elsevier, vol. 76(C), pages 607-613.
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