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Novel three-dimensional tin/carbon hybrid core/shell architecture with large amount of solid cross-linked micro/nanochannels for lithium ion battery application

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  • Yang, Zunxian
  • Meng, Qing
  • Yan, Wenhuan
  • Lv, Jun
  • Guo, Zaiping
  • Yu, Xuebin
  • Chen, Zhixin
  • Guo, Tailiang
  • Zeng, Rong

Abstract

Uniform Sn/C hybrid core/shell nanocomposites were synthesized by a combination of electrospinning and subsequent thermal treatment in a reducing atmosphere. The particular three-dimensional architecture, consisting of a Sn@C nanoparticle core and porous hollow carbon nanofiber shell, is characterized by many micro/nanochannels, enhanced mechanical support from the three-dimensional hollow carbon shell, and the abundant porous carbon matrix. The as-prepared Sn/C core/shell nanomaterials exhibit excellent electrochemical performance. They display a reversible capacity of 546.7 mAhg−1 up to 100 cycles at the current density of 40 mAg−1 and good rate capability of 181.8 mAhg−1 at 4000 mAg−1. These results indicate that the composite could be a promising anode candidate for lithium ion batteries.

Suggested Citation

  • Yang, Zunxian & Meng, Qing & Yan, Wenhuan & Lv, Jun & Guo, Zaiping & Yu, Xuebin & Chen, Zhixin & Guo, Tailiang & Zeng, Rong, 2015. "Novel three-dimensional tin/carbon hybrid core/shell architecture with large amount of solid cross-linked micro/nanochannels for lithium ion battery application," Energy, Elsevier, vol. 82(C), pages 960-967.
    • Handle: RePEc:eee:energy:v:82:y:2015:i:c:p:960-967
    DOI: 10.1016/j.energy.2015.01.105
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    References listed on IDEAS

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