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Porous Mn3O4 nanorod/reduced graphene oxide hybrid paper as a flexible and binder-free anode material for lithium ion battery

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  • Park, Seung-Keun
  • Seong, Chae-Yong
  • Yoo, Suyeon
  • Piao, Yuanzhe

Abstract

A highly flexible and free-standing, porous Mn3O4 nanorod/reduced graphene oxide (pMn3O4 NR/rGO) paper was prepared by a two-step process: vacuum filtration and thermal treatment. The MnOOH nanorod/graphene oxide (MnOOH NR/GO) paper obtained by a simple filtration method is transformed into pMn3O4 NR/rGO paper after a thermal reduction process. A unique lamellar structure was achieved with pMn3O4 NR homogeneously intercalated within the GO layers. In the hybrid structure, graphene nanosheets provide a conductive pathway and act as the buffer layers to prevent the pulverization of pMn3O4 NRs during reaction. Therefore, when used as the anode in lithium ion batteries, this pMn3O4 NR/rGO paper exhibits a first high discharge capacity of 943 mA h g−1, which quickly stabilizes and remains at 573 mA h g−1 even after 100 cycles at 100 mA h g−1, which is much higher than the discharge capacity of the corresponding pristine graphene paper (183 mA h g−1).

Suggested Citation

  • Park, Seung-Keun & Seong, Chae-Yong & Yoo, Suyeon & Piao, Yuanzhe, 2016. "Porous Mn3O4 nanorod/reduced graphene oxide hybrid paper as a flexible and binder-free anode material for lithium ion battery," Energy, Elsevier, vol. 99(C), pages 266-273.
    • Handle: RePEc:eee:energy:v:99:y:2016:i:c:p:266-273
    DOI: 10.1016/j.energy.2016.01.061
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    2. Wang, Mingyue & Huang, Ying & Wang, Ke & Zhu, Yade & Zhang, Na & Zhang, Hongming & Li, Suping & Feng, Zhenhe, 2018. "PVD synthesis of binder-free silicon and carbon coated 3D α-Fe2O3 nanorods hybrid films as high-capacity and long-life anode for flexible lithium-ion batteries," Energy, Elsevier, vol. 164(C), pages 1021-1029.
    3. Thauer, Elisa & Shi, Xiaoze & Zhang, Shuai & Chen, Xuecheng & Deeg, Lukas & Klingeler, Rüdiger & Wenelska, Karolina & Mijowska, Ewa, 2021. "Mn3O4 encapsulated in hollow carbon spheres coated by graphene layer for enhanced magnetization and lithium-ion batteries performance," Energy, Elsevier, vol. 217(C).
    4. Dohyeong Seok & Yohan Jeong & Kyoungho Han & Do Young Yoon & Hiesang Sohn, 2019. "Recent Progress of Electrochemical Energy Devices: Metal Oxide–Carbon Nanocomposites as Materials for Next-Generation Chemical Storage for Renewable Energy," Sustainability, MDPI, vol. 11(13), pages 1-34, July.

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