IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v44y2012i1p616-622.html
   My bibliography  Save this article

An experimental investigation into biodiesel stability by means of oxidation and property determination

Author

Listed:
  • Shahabuddin, M.
  • Kalam, M.A.
  • Masjuki, H.H.
  • Bhuiya, M.M.K.
  • Mofijur, M.

Abstract

This paper presents the experimental results carried out to evaluate the oxidation and storage stabilities of various biodiesel fuels. The biodiesel fuels are palm methyl ester (PME), jatropha methyl ester (JME), coconut oil methyl ester (COME), 20% blends of PME with diesel fuel and 20% blends of JME with diesel fuel. The ordinary diesel fuel was used for comparison purposes. Various ASTM standard methods were used to evaluate all the samples at the interval of 180 h over a 2160 h (three months) duration. Oxidation stability of the samples was measured by induction period (IP) using a Rancimat instrument. Other properties such as density, viscosity, flash point, total acid number (TAN), and total base number (TBN) were measured. The results show that almost all fuel samples met the standard specifications regarding IP. The trends for density, viscosity and TAN increased, while the TBN decreased due to oxidation. For the flash point, the trend also decreased, but the rate was very low. In overall consideration, among the biodiesels, COME was found to be better in respect to oxidation and storage stabilities. The results of this investigation will be used to sustainable development of biodiesel fuel from various stock resources.

Suggested Citation

  • Shahabuddin, M. & Kalam, M.A. & Masjuki, H.H. & Bhuiya, M.M.K. & Mofijur, M., 2012. "An experimental investigation into biodiesel stability by means of oxidation and property determination," Energy, Elsevier, vol. 44(1), pages 616-622.
    • Handle: RePEc:eee:energy:v:44:y:2012:i:1:p:616-622
    DOI: 10.1016/j.energy.2012.05.032
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544212004124
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2012.05.032?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Haseeb, A.S.M.A. & Sia, S.Y. & Fazal, M.A. & Masjuki, H.H., 2010. "Effect of temperature on tribological properties of palm biodiesel," Energy, Elsevier, vol. 35(3), pages 1460-1464.
    2. Chauhan, Bhupendra Singh & Kumar, Naveen & Cho, Haeng Muk, 2012. "A study on the performance and emission of a diesel engine fueled with Jatropha biodiesel oil and its blends," Energy, Elsevier, vol. 37(1), pages 616-622.
    3. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K., 2010. "Blends of biodiesels synthesized from non-edible and edible oils: Influence on the OS (oxidation stability)," Energy, Elsevier, vol. 35(8), pages 3449-3453.
    4. Jain, Siddharth & Sharma, M.P., 2010. "Review of different test methods for the evaluation of stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(7), pages 1937-1947, September.
    5. Karavalakis, Georgios & Hilari, Despina & Givalou, Lida & Karonis, Dimitrios & Stournas, Stamos, 2011. "Storage stability and ageing effect of biodiesel blends treated with different antioxidants," Energy, Elsevier, vol. 36(1), pages 369-374.
    6. Hu, Zhiyuan & Tan, Piqiang & Yan, Xiaoyu & Lou, Diming, 2008. "Life cycle energy, environment and economic assessment of soybean-based biodiesel as an alternative automotive fuel in China," Energy, Elsevier, vol. 33(11), pages 1654-1658.
    7. Jain, Siddharth & Sharma, M.P., 2011. "Long term storage stability of Jatropha curcas biodiesel," Energy, Elsevier, vol. 36(8), pages 5409-5415.
    8. Mani, M. & Nagarajan, G., 2009. "Influence of injection timing on performance, emission and combustion characteristics of a DI diesel engine running on waste plastic oil," Energy, Elsevier, vol. 34(10), pages 1617-1623.
    9. Chen, Kang-Shin & Lin, Yuan-Chung & Hsieh, Lien-Te & Lin, Long-Full & Wu, Chia-Chieh, 2010. "Saving energy and reducing pollution by use of emulsified palm-biodiesel blends with bio-solution additive," Energy, Elsevier, vol. 35(5), pages 2043-2048.
    10. Jain, Siddharth & Sharma, M.P., 2010. "Stability of biodiesel and its blends: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 667-678, February.
    11. Chen, Yi-Hung & Chen, Jhih-Hong & Luo, Yu-Min & Shang, Neng-Chou & Chang, Cheng-Hsin & Chang, Ching-Yuan & Chiang, Pen-Chi & Shie, Je-Lueng, 2011. "Property modification of jatropha oil biodiesel by blending with other biodiesels or adding antioxidants," Energy, Elsevier, vol. 36(7), pages 4415-4421.
    12. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sharma, Meeta & Malhotra, R.K., 2009. "Influence of metal contaminants on oxidation stability of Jatropha biodiesel," Energy, Elsevier, vol. 34(9), pages 1271-1275.
    13. Deng, Xin & Fang, Zhen & Liu, Yun-hu & Yu, Chang-Liu, 2011. "Production of biodiesel from Jatropha oil catalyzed by nanosized solid basic catalyst," Energy, Elsevier, vol. 36(2), pages 777-784.
    14. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K. & Sharma, Meeta & Khan, Arif Ali, 2010. "Synergistic effect of metal deactivator and antioxidant on oxidation stability of metal contaminated Jatropha biodiesel," Energy, Elsevier, vol. 35(5), pages 2333-2337.
    15. Sarin, Amit & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K., 2010. "Natural and synthetic antioxidants: Influence on the oxidative stability of biodiesel synthesized from non-edible oil," Energy, Elsevier, vol. 35(12), pages 4645-4648.
    16. Kumaran, P. & Mazlini, Nur & Hussein, Ibrahim & Nazrain, M. & Khairul, M., 2011. "Technical feasibility studies for Langkawi WCO (waste cooking oil) derived-biodiesel," Energy, Elsevier, vol. 36(3), pages 1386-1393.
    17. Jain, Siddharth & Sharma, M.P., 2010. "Prospects of biodiesel from Jatropha in India: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 763-771, February.
    18. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K. & Kundu, K., 2009. "Effect of blends of Palm-Jatropha-Pongamia biodiesels on cloud point and pour point," Energy, Elsevier, vol. 34(11), pages 2016-2021.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yaakob, Zahira & Narayanan, Binitha N. & Padikkaparambil, Silija & Unni K., Surya & Akbar P., Mohammed, 2014. "A review on the oxidation stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 136-153.
    2. Sorate, Kamalesh A. & Bhale, Purnanand V., 2015. "Biodiesel properties and automotive system compatibility issues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 777-798.
    3. E, Jiaqiang & Pham, Minhhieu & Zhao, D. & Deng, Yuanwang & Le, DucHieu & Zuo, Wei & Zhu, Hao & Liu, Teng & Peng, Qingguo & Zhang, Zhiqing, 2017. "Effect of different technologies on combustion and emissions of the diesel engine fueled with biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 620-647.
    4. Kalam, M.A. & Ahamed, J.U. & Masjuki, H.H., 2012. "Land availability of Jatropha production in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3999-4007.
    5. Sundus, F. & Fazal, M.A. & Masjuki, H.H., 2017. "Tribology with biodiesel: A study on enhancing biodiesel stability and its fuel properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 399-412.
    6. Sarin, Amit & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K., 2010. "Natural and synthetic antioxidants: Influence on the oxidative stability of biodiesel synthesized from non-edible oil," Energy, Elsevier, vol. 35(12), pages 4645-4648.
    7. Lamba, Bhawna Yadav & Joshi, Girdhar & Tiwari, Avanish K. & Rawat, Devendra Singh & Mallick, Sudesh, 2013. "Effect of antioxidants on physico-chemical properties of EURO-III HSD (high speed diesel) and Jatropha biodiesel blends," Energy, Elsevier, vol. 60(C), pages 222-229.
    8. Fazal, M.A. & Haseeb, A.S.M.A. & Masjuki, H.H., 2011. "Effect of temperature on the corrosion behavior of mild steel upon exposure to palm biodiesel," Energy, Elsevier, vol. 36(5), pages 3328-3334.
    9. Rizwanul Fattah, I.M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Masum, B.M. & Imtenan, S. & Ashraful, A.M., 2014. "Effect of antioxidants on oxidation stability of biodiesel derived from vegetable and animal based feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 356-370.
    10. Fazal, M.A. & Haseeb, A.S.M.A. & Masjuki, H.H., 2011. "Biodiesel feasibility study: An evaluation of material compatibility; performance; emission and engine durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(2), pages 1314-1324, February.
    11. Mahmudul, H.M. & Hagos, F.Y. & Mamat, R. & Adam, A. Abdul & Ishak, W.F.W. & Alenezi, R., 2017. "Production, characterization and performance of biodiesel as an alternative fuel in diesel engines – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 497-509.
    12. Jakeria, M.R. & Fazal, M.A. & Haseeb, A.S.M.A., 2014. "Influence of different factors on the stability of biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 154-163.
    13. Mofijur, M. & Masjuki, H.H. & Kalam, M.A. & Atabani, A.E. & Shahabuddin, M. & Palash, S.M. & Hazrat, M.A., 2013. "Effect of biodiesel from various feedstocks on combustion characteristics, engine durability and materials compatibility: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 441-455.
    14. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    15. Roveda, Ana Carolina & Comin, Marina & Caires, Anderson Rodrigues Lima & Ferreira, Valdir Souza & Trindade, Magno Aparecido Gonçalves, 2016. "Thermal stability enhancement of biodiesel induced by a synergistic effect between conventional antioxidants and an alternative additive," Energy, Elsevier, vol. 109(C), pages 260-265.
    16. Grana, Roberto & Frassoldati, Alessio & Cuoci, Alberto & Faravelli, Tiziano & Ranzi, Eliseo, 2012. "A wide range kinetic modeling study of pyrolysis and oxidation of methyl butanoate and methyl decanoate. Note I: Lumped kinetic model of methyl butanoate and small methyl esters," Energy, Elsevier, vol. 43(1), pages 124-139.
    17. Fazal, M.A. & Haseeb, A.S.M.A. & Masjuki, H.H., 2012. "Degradation of automotive materials in palm biodiesel," Energy, Elsevier, vol. 40(1), pages 76-83.
    18. Karavalakis, Georgios & Hilari, Despina & Givalou, Lida & Karonis, Dimitrios & Stournas, Stamos, 2011. "Storage stability and ageing effect of biodiesel blends treated with different antioxidants," Energy, Elsevier, vol. 36(1), pages 369-374.
    19. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K., 2010. "Blends of biodiesels synthesized from non-edible and edible oils: Influence on the OS (oxidation stability)," Energy, Elsevier, vol. 35(8), pages 3449-3453.
    20. Mofijur, M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Liaquat, A.M. & Shahabuddin, M. & Varman, M., 2012. "Prospects of biodiesel from Jatropha in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5007-5020.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:44:y:2012:i:1:p:616-622. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.