IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v89y2015icp924-931.html
   My bibliography  Save this article

Investigation of long term reactive stability of ceria for use in solar thermochemical cycles

Author

Listed:
  • Rhodes, Nathan R.
  • Bobek, Michael M.
  • Allen, Kyle M.
  • Hahn, David W.

Abstract

The use of an intermediate reactive material composed of cerium (IV) oxide (ceria) is explored for solar fuel production through a CO2-splitting thermochemical redox cycle. To this end, powder and porous ceria samples are tested with TGA (thermogravimetric analysis) to ascertain their maximum fuel production potential from the CeO2 → CeO2−δ cycle. A maximum value of the non-stoichiometric reduction factor δ of ceria powder was 0.0383 at 1450 °C. The reactive stability of a synthesized porous ceria sample is then observed with carbon dioxide splitting at 1100 °C and thermal reduction at 1450 °C. Approximately 86.4% of initial fuel production is retained after 2000 cycles, and the mean value of δ is found to be 0.0197. SEM (scanning electron microscopy) imaging suggests that the porous ceria structure is retained over 2000 cycles despite apparent loss of some surface area. EDS (energy dispersive x-ray spectroscopy) line scans show that oxidation of porous ceria becomes increasingly homogenous throughout the bulk material over an increasing number of cycles. Significant retention of reactivity and porous structure demonstrates the potential of porous ceria for use in a commercial thermochemical reactor.

Suggested Citation

  • Rhodes, Nathan R. & Bobek, Michael M. & Allen, Kyle M. & Hahn, David W., 2015. "Investigation of long term reactive stability of ceria for use in solar thermochemical cycles," Energy, Elsevier, vol. 89(C), pages 924-931.
    • Handle: RePEc:eee:energy:v:89:y:2015:i:c:p:924-931
    DOI: 10.1016/j.energy.2015.06.041
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544215007975
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2015.06.041?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Charvin, Patrice & Abanades, Stéphane & Flamant, Gilles & Lemort, Florent, 2007. "Two-step water splitting thermochemical cycle based on iron oxide redox pair for solar hydrogen production," Energy, Elsevier, vol. 32(7), pages 1124-1133.
    2. Xiao, Lan & Wu, Shuang-Ying & Li, You-Rong, 2012. "Advances in solar hydrogen production via two-step water-splitting thermochemical cycles based on metal redox reactions," Renewable Energy, Elsevier, vol. 41(C), pages 1-12.
    3. Lapp, J. & Davidson, J.H. & Lipiński, W., 2012. "Efficiency of two-step solar thermochemical non-stoichiometric redox cycles with heat recovery," Energy, Elsevier, vol. 37(1), pages 591-600.
    4. Tamaura, Y. & Steinfeld, A. & Kuhn, P. & Ehrensberger, K., 1995. "Production of solar hydrogen by a novel, 2-step, water-splitting thermochemical cycle," Energy, Elsevier, vol. 20(4), pages 325-330.
    5. Song, Lee-hwa & Kang, Hyun Woo & Park, Seung Bin, 2012. "Thermally stable iron based redox catalysts for the thermo-chemical hydrogen generation from water," Energy, Elsevier, vol. 42(1), pages 313-320.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kong, Hui & Hao, Yong & Jin, Hongguang, 2018. "Isothermal versus two-temperature solar thermochemical fuel synthesis: A comparative study," Applied Energy, Elsevier, vol. 228(C), pages 301-308.
    2. Kong, Hui & Kong, Xianghui & Wang, Jian & Zhang, Jun, 2019. "Thermodynamic analysis of a solar thermochemical cycle-based direct coal liquefaction system for oil production," Energy, Elsevier, vol. 179(C), pages 1279-1287.
    3. Stéphane Abanades, 2022. "Redox Cycles, Active Materials, and Reactors Applied to Water and Carbon Dioxide Splitting for Solar Thermochemical Fuel Production: A Review," Energies, MDPI, vol. 15(19), pages 1-28, September.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Agrafiotis, Christos & Roeb, Martin & Sattler, Christian, 2015. "A review on solar thermal syngas production via redox pair-based water/carbon dioxide splitting thermochemical cycles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 254-285.
    2. Daphne Oudejans & Michele Offidani & Achilleas Constantinou & Stefania Albonetti & Nikolaos Dimitratos & Atul Bansode, 2022. "A Comprehensive Review on Two-Step Thermochemical Water Splitting for Hydrogen Production in a Redox Cycle," Energies, MDPI, vol. 15(9), pages 1-24, April.
    3. Christopher L. Muhich & Brian D. Ehrhart & Ibraheam Al-Shankiti & Barbara J. Ward & Charles B. Musgrave & Alan W. Weimer, 2016. "A review and perspective of efficient hydrogen generation via solar thermal water splitting," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 5(3), pages 261-287, May.
    4. Mohsen Fallah Vostakola & Babak Salamatinia & Bahman Amini Horri, 2022. "A Review on Recent Progress in the Integrated Green Hydrogen Production Processes," Energies, MDPI, vol. 15(3), pages 1-41, February.
    5. Stéphane Abanades, 2022. "Redox Cycles, Active Materials, and Reactors Applied to Water and Carbon Dioxide Splitting for Solar Thermochemical Fuel Production: A Review," Energies, MDPI, vol. 15(19), pages 1-28, September.
    6. Song, Lee-hwa & Kang, Hyun Woo & Park, Seung Bin, 2012. "Thermally stable iron based redox catalysts for the thermo-chemical hydrogen generation from water," Energy, Elsevier, vol. 42(1), pages 313-320.
    7. Mao, Yanpeng & Gao, Yibo & Dong, Wei & Wu, Han & Song, Zhanlong & Zhao, Xiqiang & Sun, Jing & Wang, Wenlong, 2020. "Hydrogen production via a two-step water splitting thermochemical cycle based on metal oxide – A review," Applied Energy, Elsevier, vol. 267(C).
    8. Hua, Xiuning & Fan, Yiran & Wang, Yidi & Fu, Tiantian & Fowler, G.D. & Zhao, Dongmei & Wang, Wei, 2017. "The behaviour of multiple reaction fronts during iron (III) oxide reduction in a non-steady state packed bed for chemical looping water splitting," Applied Energy, Elsevier, vol. 193(C), pages 96-111.
    9. Imponenti, Luca & Albrecht, Kevin J. & Kharait, Rounak & Sanders, Michael D. & Jackson, Gregory S., 2018. "Redox cycles with doped calcium manganites for thermochemical energy storage to 1000 °C," Applied Energy, Elsevier, vol. 230(C), pages 1-18.
    10. Yadav, Deepak & Banerjee, Rangan, 2016. "A review of solar thermochemical processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 497-532.
    11. Koepf, E. & Alxneit, I. & Wieckert, C. & Meier, A., 2017. "A review of high temperature solar driven reactor technology: 25years of experience in research and development at the Paul Scherrer Institute," Applied Energy, Elsevier, vol. 188(C), pages 620-651.
    12. Lange, M. & Roeb, M. & Sattler, C. & Pitz-Paal, R., 2014. "T–S diagram efficiency analysis of two-step thermochemical cycles for solar water splitting under various process conditions," Energy, Elsevier, vol. 67(C), pages 298-308.
    13. Sadeghi, Shayan & Ghandehariun, Samane, 2022. "A standalone solar thermochemical water splitting hydrogen plant with high-temperature molten salt: Thermodynamic and economic analyses and multi-objective optimization," Energy, Elsevier, vol. 240(C).
    14. Michalsky, Ronald & Parman, Bryon J. & Amanor-Boadu, Vincent & Pfromm, Peter H., 2012. "Solar thermochemical production of ammonia from water, air and sunlight: Thermodynamic and economic analyses," Energy, Elsevier, vol. 42(1), pages 251-260.
    15. Carlos E. Arreola-Ramos & Omar Álvarez-Brito & Juan Daniel Macías & Aldo Javier Guadarrama-Mendoza & Manuel A. Ramírez-Cabrera & Armando Rojas-Morin & Patricio J. Valadés-Pelayo & Heidi Isabel Villafá, 2021. "Experimental Evaluation and Modeling of Air Heating in a Ceramic Foam Volumetric Absorber by Effective Parameters," Energies, MDPI, vol. 14(9), pages 1-15, April.
    16. Sheline, W. & Matthews, L. & Lindeke, N. & Duncan, S. & Palumbo, R., 2013. "An exploratory study of the solar thermal electrolytic production of Mg from MgO," Energy, Elsevier, vol. 51(C), pages 163-170.
    17. Vidal, Alfonso & Gonzalez, Aurelio & Denk, Thorsten, 2020. "A 100 kW cavity-receiver reactor with an integrated two-step thermochemical cycle: Thermal performance under solar transients," Renewable Energy, Elsevier, vol. 153(C), pages 270-279.
    18. Yilmaz, Fatih & Balta, M. Tolga & Selbaş, Reşat, 2016. "A review of solar based hydrogen production methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 171-178.
    19. Alonso, Elisa & Pérez-Rábago, Carlos & Licurgo, Javier & Gallo, Alessandro & Fuentealba, Edward & Estrada, Claudio A., 2017. "Experimental aspects of CuO reduction in solar-driven reactors: Comparative performance of a rotary kiln and a packed-bed," Renewable Energy, Elsevier, vol. 105(C), pages 665-673.
    20. Hoskins, Amanda L. & Millican, Samantha L. & Czernik, Caitlin E. & Alshankiti, Ibraheam & Netter, Judy C. & Wendelin, Timothy J. & Musgrave, Charles B. & Weimer, Alan W., 2019. "Continuous on-sun solar thermochemical hydrogen production via an isothermal redox cycle," Applied Energy, Elsevier, vol. 249(C), pages 368-376.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:89:y:2015:i:c:p:924-931. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.