IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v81y2015icp489-500.html
   My bibliography  Save this article

Modeling study of a Li–O2 battery with an active cathode

Author

Listed:
  • Li, Xianglin
  • Huang, Jing
  • Faghri, Amir

Abstract

In this study, a new organic lithium oxygen (Li–O2) battery structure is proposed to enhance battery capacity. The electrolyte is forced to recirculate through the cathode and then saturated with oxygen in a tank external to the battery. The forced convection enhances oxygen transport and alleviates the problem of electrode blockage during discharge. A two dimensional, transient, non-isothermal simulation model is developed to study the heat and mass transfer within the battery and validate the proposed design. Results show that this novel active cathode design improves the battery capacity at all discharge current densities. The capacity of the Li–O2 battery is increased by 15.5 times (from 12.2 mAh g−1 to 201 mAh g−1) at the discharge current of 2.0 mA cm−2 when a conventional passive electrode is replaced by the newly designed active electrode. Furthermore, a cathode with non-uniform porosity is suggested and simulation results show that it can reach a higher discharge capacity without decreasing its power density. Detailed mass transport processes in the battery are also studied.

Suggested Citation

  • Li, Xianglin & Huang, Jing & Faghri, Amir, 2015. "Modeling study of a Li–O2 battery with an active cathode," Energy, Elsevier, vol. 81(C), pages 489-500.
    • Handle: RePEc:eee:energy:v:81:y:2015:i:c:p:489-500
    DOI: 10.1016/j.energy.2014.12.062
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214014406
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2014.12.062?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Colmenar-Santos, Antonio & Alberdi-Jiménez, Lucía & Nasarre-Cortés, Lorenzo & Mora-Larramona, Joaquín, 2014. "Residual heat use generated by a 12 kW fuel cell in an electric vehicle heating system," Energy, Elsevier, vol. 68(C), pages 182-190.
    2. Richard Van Noorden, 2014. "The rechargeable revolution: A better battery," Nature, Nature, vol. 507(7490), pages 26-28, March.
    3. Li, Xianglin & Faghri, Amir, 2011. "Local entropy generation analysis on passive high-concentration DMFCs (direct methanol fuel cell) with different cell structures," Energy, Elsevier, vol. 36(1), pages 403-414.
    4. Vynnycky, M., 2011. "Analysis of a model for the operation of a vanadium redox battery," Energy, Elsevier, vol. 36(4), pages 2242-2256.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ye, Luhan & Wang, Xiaoning & Lv, Weiqiang & Fei, Jipeng & Zhu, Gaolong & Liang, Yachun & Song, Yuanqiang & Zhai, Junyi & He, Weidong, 2015. "Analytical insight into the oxygen diffusion in wetted porous cathodes of Li-air batteries," Energy, Elsevier, vol. 93(P1), pages 416-420.
    2. Ren, Y.X. & Zhao, T.S. & Tan, P. & Wei, Z.H. & Zhou, X.L., 2017. "Modeling of an aprotic Li-O2 battery incorporating multiple-step reactions," Applied Energy, Elsevier, vol. 187(C), pages 706-716.
    3. Kisoo Yoo & Soumik Banerjee & Jonghoon Kim & Prashanta Dutta, 2017. "A Review of Lithium-Air Battery Modeling Studies," Energies, MDPI, vol. 10(11), pages 1-42, November.
    4. Yuan, Jiashu & Zhu, Yongming & Gao, Jian & Li, Wantang, 2015. "Electrochemical performance of mixed carbon material with waterproof membrane for lithium air battery in the ambient atmosphere," Energy, Elsevier, vol. 89(C), pages 84-91.
    5. Tang, Michael & Chang, Jia-Cheng & Kumar, S. Rajesh & Lue, Shingjiang Jessie, 2019. "Glyme-based electrolyte formulation analysis in aprotic lithium-oxygen battery and its cyclic stability," Energy, Elsevier, vol. 187(C).
    6. Berrueta, Alberto & Urtasun, Andoni & Ursúa, Alfredo & Sanchis, Pablo, 2018. "A comprehensive model for lithium-ion batteries: From the physical principles to an electrical model," Energy, Elsevier, vol. 144(C), pages 286-300.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sebastian Puls & Elina Nazmutdinova & Fariza Kalyk & Henry M. Woolley & Jesper Frost Thomsen & Zhu Cheng & Adrien Fauchier-Magnan & Ajay Gautam & Michael Gockeln & So-Yeon Ham & Md Toukir Hasan & Min-, 2024. "Benchmarking the reproducibility of all-solid-state battery cell performance," Nature Energy, Nature, vol. 9(10), pages 1310-1320, October.
    2. Yuan, Zhenyu & Yang, Jie & Li, Xiaoyang & Wang, Shikai, 2016. "The micro-scale analysis of the micro direct methanol fuel cell," Energy, Elsevier, vol. 100(C), pages 10-17.
    3. Sciacovelli, A. & Verda, V. & Sciubba, E., 2015. "Entropy generation analysis as a design tool—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1167-1181.
    4. Zhang, Zhenying & Wang, Jiayu & Feng, Xu & Chang, Li & Chen, Yanhua & Wang, Xingguo, 2018. "The solutions to electric vehicle air conditioning systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 443-463.
    5. Fang, Shuo & Zhang, Yufeng & Zou, Yuezhang & Sang, Shengtian & Liu, Xiaowei, 2017. "Structural design and analysis of a passive DMFC supplied with concentrated methanol solution," Energy, Elsevier, vol. 128(C), pages 50-61.
    6. Yuan, Zhenyu & Zhang, Yufeng & Fu, Wenting & Li, Zipeng & Liu, Xiaowei, 2013. "Investigation of a small-volume direct methanol fuel cell stack for portable applications," Energy, Elsevier, vol. 51(C), pages 462-467.
    7. Sun, Zhe & Wang, Ning & Bi, Yunrui & Srinivasan, Dipti, 2015. "Parameter identification of PEMFC model based on hybrid adaptive differential evolution algorithm," Energy, Elsevier, vol. 90(P2), pages 1334-1341.
    8. Gert Berckmans & Maarten Messagie & Jelle Smekens & Noshin Omar & Lieselot Vanhaverbeke & Joeri Van Mierlo, 2017. "Cost Projection of State of the Art Lithium-Ion Batteries for Electric Vehicles Up to 2030," Energies, MDPI, vol. 10(9), pages 1-20, September.
    9. Nguyen-Tien, Viet & Dai, Qiang & Harper, Gavin D.J. & Anderson, Paul A. & Elliott, Robert J.R., 2022. "Optimising the geospatial configuration of a future lithium ion battery recycling industry in the transition to electric vehicles and a circular economy," Applied Energy, Elsevier, vol. 321(C).
    10. Mahian, Omid & Mahmud, Shohel & Heris, Saeed Zeinali, 2012. "Analysis of entropy generation between co-rotating cylinders using nanofluids," Energy, Elsevier, vol. 44(1), pages 438-446.
    11. Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Yan, X.H., 2015. "A vanadium redox flow battery model incorporating the effect of ion concentrations on ion mobility," Applied Energy, Elsevier, vol. 158(C), pages 157-166.
    12. Alijanpour sheshpoli, Mohamad & Mousavi Ajarostaghi, Seyed Soheil & Delavar, Mojtaba Aghajani, 2018. "Waste heat recovery from a 1180 kW proton exchange membrane fuel cell (PEMFC) system by Recuperative organic Rankine cycle (RORC)," Energy, Elsevier, vol. 157(C), pages 353-366.
    13. Ren, Y.X. & Zhao, T.S. & Tan, P. & Wei, Z.H. & Zhou, X.L., 2017. "Modeling of an aprotic Li-O2 battery incorporating multiple-step reactions," Applied Energy, Elsevier, vol. 187(C), pages 706-716.
    14. Tianqi He & Rongqi Shi & Jie Peng & Weilin Zhuge & Yangjun Zhang, 2016. "Waste Heat Recovery of a PEMFC System by Using Organic Rankine Cycle," Energies, MDPI, vol. 9(4), pages 1-15, April.
    15. Zheng, Qiong & Li, Xianfeng & Cheng, Yuanhui & Ning, Guiling & Xing, Feng & Zhang, Huamin, 2014. "Development and perspective in vanadium flow battery modeling," Applied Energy, Elsevier, vol. 132(C), pages 254-266.
    16. Wang, Q. & Qu, Z.G. & Jiang, Z.Y. & Yang, W.W., 2018. "Numerical study on vanadium redox flow battery performance with non-uniformly compressed electrode and serpentine flow field," Applied Energy, Elsevier, vol. 220(C), pages 106-116.
    17. Arjmandi, H.R. & Amani, E., 2015. "A numerical investigation of the entropy generation in and thermodynamic optimization of a combustion chamber," Energy, Elsevier, vol. 81(C), pages 706-718.
    18. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Investigation of NaOH concentration effect in injected fuel on the performance of passive direct methanol alkaline fuel cell with modified cation exchange membrane," Energy, Elsevier, vol. 94(C), pages 589-599.
    19. Qunhong Shen & Kaidong Feng & Xiaobin Zhang, 2016. "Divergent technological strategies among leading electric vehicle firms in China: Multiplicity of institutional logics and responses of firms," Science and Public Policy, Oxford University Press, vol. 43(4), pages 492-504.
    20. Yuan, Zhenyu & Yang, Jie & Zhang, Yufeng, 2015. "A self-adaptive supply method of micro direct methanol fuel cell," Energy, Elsevier, vol. 91(C), pages 1064-1069.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:81:y:2015:i:c:p:489-500. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.