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Dissolution of steelmaking slags in acetic acid for precipitated calcium carbonate production

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  • Teir, Sebastian
  • Eloneva, Sanni
  • Fogelholm, Carl-Johan
  • Zevenhoven, Ron

Abstract

A promising option for long-term storage of CO2 is to fixate carbon dioxide as magnesium- and calcium carbonates. Slags from iron and steel works are potential raw materials for carbonation due to their high contents of calcium silicates. Precipitated calcium carbonate (PCC) is used as filler and coating materials in paper. If slag could be used instead of limestone for producing PCC, considerable energy savings and carbon dioxide emissions reductions could be achieved. In this paper, the leaching of calcium from iron and steel slags using acetic acid was investigated. Thermodynamic equilibrium calculations at atmospheric gas pressures showed that extraction of calcium is exothermic and feasible at temperatures lower than 156°C, while the precipitation of calcium carbonate is endothermic and feasible at temperatures above 45°C. The formation of calcium- and magnesium acetate in the solution was found to be thermodynamically possible. Laboratory-scale batch experiments showed that iron and steel slags rapidly dissolve in acetic acid in a few minutes and the exothermic nature of the reaction was verified. While silicon was successfully removed by filtration using solution temperatures of 70–80°C, further separation methods are required for removing iron, aluminum and magnesium from the solution.

Suggested Citation

  • Teir, Sebastian & Eloneva, Sanni & Fogelholm, Carl-Johan & Zevenhoven, Ron, 2007. "Dissolution of steelmaking slags in acetic acid for precipitated calcium carbonate production," Energy, Elsevier, vol. 32(4), pages 528-539.
    • Handle: RePEc:eee:energy:v:32:y:2007:i:4:p:528-539
    DOI: 10.1016/j.energy.2006.06.023
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    References listed on IDEAS

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    1. Kakizawa, M. & Yamasaki, A. & Yanagisawa, Y., 2001. "A new CO2 disposal process via artificial weathering of calcium silicate accelerated by acetic acid," Energy, Elsevier, vol. 26(4), pages 341-354.
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    2. Xiaolong Wang & Aimaro Sanna & M. Mercedes Maroto‐Valer & Tom Paulson, 2015. "Carbon dioxide capture and storage by pH swing mineralization using recyclable ammonium salts and flue gas mixtures," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 5(4), pages 389-402, August.
    3. Jun-Hwan Bang & Seung-Woo Lee & Chiwan Jeon & Sangwon Park & Kyungsun Song & Whan Joo Jo & Soochun Chae, 2016. "Leaching of Metal Ions from Blast Furnace Slag by Using Aqua Regia for CO 2 Mineralization," Energies, MDPI, vol. 9(12), pages 1-13, November.
    4. Natalia Czaplicka & Donata Konopacka-Łyskawa, 2020. "Utilization of Gaseous Carbon Dioxide and Industrial Ca-Rich Waste for Calcium Carbonate Precipitation: A Review," Energies, MDPI, vol. 13(23), pages 1-25, November.
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    11. Enze Ren & Siyang Tang & Changjun Liu & Hairong Yue & Chun Li & Bin Liang, 2020. "Carbon dioxide mineralization for the disposition of blast‐furnace slag: reaction intensification using NaCl solutions," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(2), pages 436-448, April.
    12. Park, Sangwon, 2018. "CO2 reduction-conversion to precipitates and morphological control through the application of the mineral carbonation mechanism," Energy, Elsevier, vol. 153(C), pages 413-421.
    13. Said, Arshe & Mattila, Hannu-Petteri & Järvinen, Mika & Zevenhoven, Ron, 2013. "Production of precipitated calcium carbonate (PCC) from steelmaking slag for fixation of CO2," Applied Energy, Elsevier, vol. 112(C), pages 765-771.
    14. Quader, M. Abdul & Ahmed, Shamsuddin & Ghazilla, Raja Ariffin Raja & Ahmed, Shameem & Dahari, Mahidzal, 2015. "A comprehensive review on energy efficient CO2 breakthrough technologies for sustainable green iron and steel manufacturing," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 594-614.
    15. Jo, Hoyong & Lee, Min-Gu & Park, Jinwon & Jung, Kwang-Deog, 2017. "Preparation of high-purity nano-CaCO3 from steel slag," Energy, Elsevier, vol. 120(C), pages 884-894.
    16. Ukwattage, N.L. & Ranjith, P.G. & Wang, S.H., 2013. "Investigation of the potential of coal combustion fly ash for mineral sequestration of CO2 by accelerated carbonation," Energy, Elsevier, vol. 52(C), pages 230-236.
    17. Hosseini, Tahereh & Haque, Nawshad & Selomulya, Cordelia & Zhang, Lian, 2016. "Mineral carbonation of Victorian brown coal fly ash using regenerative ammonium chloride – Process simulation and techno-economic analysis," Applied Energy, Elsevier, vol. 175(C), pages 54-68.
    18. Zhang, Huining & Gao, Chong & Chen, Ben & Tang, Jiang & He, Dongfeng & Xu, Anjun, 2018. "Stainless steel tailings accelerated direct carbonation process at low pressure: Carbonation efficiency evaluation and chromium leaching inhibition correlation analysis," Energy, Elsevier, vol. 155(C), pages 772-781.
    19. Eloneva, Sanni & Said, Arshe & Fogelholm, Carl-Johan & Zevenhoven, Ron, 2012. "Preliminary assessment of a method utilizing carbon dioxide and steelmaking slags to produce precipitated calcium carbonate," Applied Energy, Elsevier, vol. 90(1), pages 329-334.
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