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A new CO2 disposal process via artificial weathering of calcium silicate accelerated by acetic acid

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  • Kakizawa, M.
  • Yamasaki, A.
  • Yanagisawa, Y.

Abstract

A new disposal process for anthropogenic CO2 via an artificially accelerated weathering reaction is proposed to counteract global warming. The process is essentially composed of the following two steps:(1)CaSiO3+2CH3COOH→Ca2++2CH3COO−+H2O+SiO2(2)Ca2++2CH3COO−+CO2+H2O→CaCO3↓+2CH3COOHStep (1) is the extraction of calcium ions by acetic acid from calcium silicate, for example, wollastonite rocks. Step (2) is the deposition of calcium carbonate from the solution of calcium ions by CO2 injection. The Gibbs free energy change of each step is negative; the reactions would proceed spontaneously without consuming large amounts of energy. The CO2 would be captured from the concentrated emission sources such as thermal power plant, and be disposed of and sequestrated in the form of calcium carbonate. The feasibility of the proposed process was evaluated through a process design based on the experimental results of the reaction kinetics. The operational energy consumption was 20.4 MW for the disposal of CO2 produced by a 100-MW thermal power plant.

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  • Kakizawa, M. & Yamasaki, A. & Yanagisawa, Y., 2001. "A new CO2 disposal process via artificial weathering of calcium silicate accelerated by acetic acid," Energy, Elsevier, vol. 26(4), pages 341-354.
    • Handle: RePEc:eee:energy:v:26:y:2001:i:4:p:341-354
    DOI: 10.1016/S0360-5442(01)00005-6
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    References listed on IDEAS

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    1. Lackner, Klaus S. & Wendt, Christopher H. & Butt, Darryl P. & Joyce, Edward L. & Sharp, David H., 1995. "Carbon dioxide disposal in carbonate minerals," Energy, Elsevier, vol. 20(11), pages 1153-1170.
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    2. Kodama, Satoshi & Nishimoto, Taiki & Yamamoto, Naoki & Yogo, Katsunori & Yamada, Koichi, 2008. "Development of a new pH-swing CO2 mineralization process with a recyclable reaction solution," Energy, Elsevier, vol. 33(5), pages 776-784.
    3. Natalia Czaplicka & Donata Konopacka-Łyskawa, 2020. "Utilization of Gaseous Carbon Dioxide and Industrial Ca-Rich Waste for Calcium Carbonate Precipitation: A Review," Energies, MDPI, vol. 13(23), pages 1-25, November.
    4. Teir, Sebastian & Eloneva, Sanni & Fogelholm, Carl-Johan & Zevenhoven, Ron, 2007. "Dissolution of steelmaking slags in acetic acid for precipitated calcium carbonate production," Energy, Elsevier, vol. 32(4), pages 528-539.
    5. Mihee Lim & Gi-Chun Han & Ji-Whan Ahn & Kwang-Suk You, 2010. "Environmental Remediation and Conversion of Carbon Dioxide (CO 2 ) into Useful Green Products by Accelerated Carbonation Technology," IJERPH, MDPI, vol. 7(1), pages 1-26, January.
    6. Alicja Uliasz-Bocheńczyk, 2024. "A Comprehensive Review of CO 2 Mineral Sequestration Methods Using Coal Fly Ash for Carbon Capture, Utilisation, and Storage (CCUS) Technology," Energies, MDPI, vol. 17(22), pages 1-19, November.
    7. Sanna, Aimaro & Dri, Marco & Hall, Matthew R. & Maroto-Valer, Mercedes, 2012. "Waste materials for carbon capture and storage by mineralisation (CCSM) – A UK perspective," Applied Energy, Elsevier, vol. 99(C), pages 545-554.
    8. Lombardi, L. & Carnevale, E.A., 2016. "Analysis of an innovative process for landfill gas quality improvement," Energy, Elsevier, vol. 109(C), pages 1107-1117.
    9. Naraharisetti, Pavan Kumar & Yeo, Tze Yuen & Bu, Jie, 2019. "New classification of CO2 mineralization processes and economic evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 99(C), pages 220-233.
    10. Noor Allesya Alis Ramli & Faradiella Mohd Kusin & Verma Loretta M. Molahid, 2021. "Influencing Factors of the Mineral Carbonation Process of Iron Ore Mining Waste in Sequestering Atmospheric Carbon Dioxide," Sustainability, MDPI, vol. 13(4), pages 1-17, February.
    11. Hyun Sic Park & JunYoung Han & Ju Sung Lee & Kwang-Mo Kim & Hyung Jun Jo & Byoung Ryul Min, 2016. "Comparison of Two Processes Forming CaCO 3 Precipitates by Electrolysis," Energies, MDPI, vol. 9(12), pages 1-8, December.
    12. Enze Ren & Siyang Tang & Changjun Liu & Hairong Yue & Chun Li & Bin Liang, 2020. "Carbon dioxide mineralization for the disposition of blast‐furnace slag: reaction intensification using NaCl solutions," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(2), pages 436-448, April.
    13. Eloneva, Sanni & Teir, Sebastian & Salminen, Justin & Fogelholm, Carl-Johan & Zevenhoven, Ron, 2008. "Fixation of CO2 by carbonating calcium derived from blast furnace slag," Energy, Elsevier, vol. 33(9), pages 1461-1467.

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