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Effective strategy for enhancing the activity and durability of gas diffusion electrode in high-temperature polymer electrolyte membrane fuel cells: In-situ growth of Pt nanowires on dual microporous layers

Author

Listed:
  • Zhang, Weiqi
  • Chen, Yuan
  • Jin, Yuan
  • Liu, Huiyuan
  • Ma, Qiang
  • Xu, Qian
  • Su, Huaneng

Abstract

High-temperature polymer electrolyte membrane fuel cells (HT-PEMFCs) suffer from high platinum (Pt) loading and limited lifetime issues due to the low Pt efficiency of the conventional electrode and poor durability of Pt/C catalyst under harsh operating conditions. Thus, dual microporous layer (MPL) structured gas diffusion layers were developed, utilizing formic acid reduction for the in-situ growth of Pt nanowires (NWs). The optimal ratio of the hydrophilic and hydrophobic MPLs was determined to be 1:1. The resulting Pt NWs gas diffusion electrode (GDE) achieved a significantly high Pt mass-specific peak power density, which was 2.48 times higher than the conventional Pt/C GDE. After accelerated degradation tests, the peak power density and the electrochemically active surface area of Pt NWs GDE decreased by 10.84 % and 4.47 %, respectively, significantly lower than those of the conventional Pt/C GDE. The superior activity and durability of Pt NWs GDE are attributed to its binder-free characteristic, the outstanding activity and stability of one-dimensional Pt NWs, and the strong adherent force between the in-situ grown Pt and the carbon substrate. This study provides a straightforward and effective strategy to reduce the Pt loading and enhance electrode durability, thereby facilitating the large-scale application of HT-PEMFCs.

Suggested Citation

  • Zhang, Weiqi & Chen, Yuan & Jin, Yuan & Liu, Huiyuan & Ma, Qiang & Xu, Qian & Su, Huaneng, 2024. "Effective strategy for enhancing the activity and durability of gas diffusion electrode in high-temperature polymer electrolyte membrane fuel cells: In-situ growth of Pt nanowires on dual microporous ," Energy, Elsevier, vol. 308(C).
    • Handle: RePEc:eee:energy:v:308:y:2024:i:c:s0360544224026689
    DOI: 10.1016/j.energy.2024.132894
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    References listed on IDEAS

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