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Hydrogen-rich syngas production via sorption-enhanced steam gasification of biomass using FexNiyCaO bi-functional materials

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  • Liu, Rui
  • Li, Chongcong
  • Zheng, Jinhao
  • Xue, Feilong
  • Yang, Mingjun
  • Zhang, Yan

Abstract

Sorption-enhanced steam gasification (SESG) of biomass using Ca-based materials is a promising technology for H2 production and in-situ CO2 capture. Herein, FexNiyCaO bi-functional materials were prepared from carbide slag and used for hydrogen-rich syngas production in a two-stage fixed-bed system with continuous biomass feeding. The results showed that the Fe-doped CaO exhibited better catalytic activity on the water gas shift reaction than Ni-doped CaO, while the Ni-doped CaO was more favorable to steam reforming of tar than Fe-doped CaO. Besides, bimetallic Fe7Ni3CaO possessed the best performance in cyclic CO2 capture capacity, H2 production and catalytic stability among all monometallic and other bimetallic Fe/Ni-doped CaO bi-functional materials. The positive interaction between Fe and Ni alleviated the sintering of Ca2Fe2O5 and improved the resistance of NiO to carbon deposition, thereby improving the catalytic activity and stability of Fe7Ni3CaO. When the catalyst/biomass mass ratio was 3.33, the H2 concentration and H2 yield for Fe7Ni3CaO were 69.2 vol% and 660 mL/g, respectively. Finally, Fe7Ni3CaO exhibited good cyclic stability in H2 production, and the H2 yield of Fe7Ni3CaO was still more than twice that of pure CaO after 5 SESG cycles.

Suggested Citation

  • Liu, Rui & Li, Chongcong & Zheng, Jinhao & Xue, Feilong & Yang, Mingjun & Zhang, Yan, 2023. "Hydrogen-rich syngas production via sorption-enhanced steam gasification of biomass using FexNiyCaO bi-functional materials," Energy, Elsevier, vol. 281(C).
    • Handle: RePEc:eee:energy:v:281:y:2023:i:c:s0360544223016638
    DOI: 10.1016/j.energy.2023.128269
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    1. Sun, Zhao & Chen, Shiyi & Hu, Jun & Chen, Aimin & Rony, Asif Hasan & Russell, Christopher K. & Xiang, Wenguo & Fan, Maohong & Darby Dyar, M. & Dklute, Elizabeth C., 2018. "Ca2Fe2O5: A promising oxygen carrier for CO/CH4 conversion and almost-pure H2 production with inherent CO2 capture over a two-step chemical looping hydrogen generation process," Applied Energy, Elsevier, vol. 211(C), pages 431-442.
    2. Li, Lin & Tang, Dawei & Song, Yongchen & Jiang, Bo & Zhang, Qian, 2018. "Hydrogen production from ethanol steam reforming on Ni-Ce/MMT catalysts," Energy, Elsevier, vol. 149(C), pages 937-943.
    3. Yan, Xianyao & Li, Yingjie & Sun, Chaoying & Zhang, Chunxiao & Yang, Liguo & Fan, Xiaoxu & Chu, Leizhe, 2022. "Enhanced H2 production from steam gasification of biomass by red mud-doped Ca-Al-Ce bi-functional material," Applied Energy, Elsevier, vol. 312(C).
    4. Yan, Xianyao & Li, Yingjie & Ma, Xiaotong & Bian, Zhiguo & Zhao, Jianli & Wang, Zeyan, 2020. "CeO2-modified CaO/Ca12Al14O33 bi-functional material for CO2 capture and H2 production in sorption-enhanced steam gasification of biomass," Energy, Elsevier, vol. 192(C).
    5. Hu, Mian & Guo, Dabin & Ma, Caifeng & Hu, Zhiquan & Zhang, Beiping & Xiao, Bo & Luo, Siyi & Wang, Jingbo, 2015. "Hydrogen-rich gas production by the gasification of wet MSW (municipal solid waste) coupled with carbon dioxide capture," Energy, Elsevier, vol. 90(P1), pages 857-863.
    6. Parvez, Ashak Mahmud & Hafner, Selina & Hornberger, Matthias & Schmid, Max & Scheffknecht, Günter, 2021. "Sorption enhanced gasification (SEG) of biomass for tailored syngas production with in-situ CO2 capture: Current status, process scale-up experiences and outlook," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    7. Gong, Xuzhong & Zhang, Tong & Zhang, Junqiang & Wang, Zhi & Liu, Junhao & Cao, Jianwei & Wang, Chuan, 2022. "Recycling and utilization of calcium carbide slag - current status and new opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    8. Su, Chenglin & Duan, Lunbo & Donat, Felix & Anthony, Edward John, 2018. "From waste to high value utilization of spent bleaching clay in synthesizing high-performance calcium-based sorbent for CO2 capture," Applied Energy, Elsevier, vol. 210(C), pages 117-126.
    9. Siddiqi, Hammad & Bal, Manisha & Kumari, Usha & Meikap, B.C., 2020. "In-depth physiochemical characterization and detailed thermo-kinetic study of biomass wastes to analyze its energy potential," Renewable Energy, Elsevier, vol. 148(C), pages 756-771.
    10. Magoua Mbeugang, Christian Fabrice & Li, Bin & Lin, Dan & Xie, Xing & Wang, Shuaijun & Wang, Shuang & Zhang, Shu & Huang, Yong & Liu, Dongjing & Wang, Qian, 2021. "Hydrogen rich syngas production from sorption enhanced gasification of cellulose in the presence of calcium oxide," Energy, Elsevier, vol. 228(C).
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    1. Wang, Yuzhuo & Wu, Jun Jie, 2023. "Thermochemical conversion of biomass: Potential future prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 187(C).

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