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Thermochemical equilibrium modeling of biomass downdraft gasifier: Stoichiometric models

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  • Mendiburu, Andrés Z.
  • Carvalho, João A.
  • Coronado, Christian J.R.

Abstract

The aim of this work is to develop stoichiometric equilibrium models that permit the study of parameters effect in the gasification process of a particular feedstock. In total four models were tested in order to determine the syngas composition. One of these four models, called M2, was based on the theoretical equilibrium constants modified by two correction factors determined using published experimental data. The other two models, M3 and M4 were based in correlations, while model M4 was based in correlations to determine the equilibrium constants, model M3 was based in correlations that relate the H2, CO and CO2 content on the synthesis gas. Model M2 proved to be the more accurate and versatile among these four models, and also showed better results than some previously published models. Also a case study for the gasification of a blend of hardwood chips and glycerol at 80% and 20% respectively, was performed considering equivalence ratios form 0.3 to 0.5, moisture contents from 0%–20% and oxygen percentages in the gasification agent of 100%, 60% and 21%.

Suggested Citation

  • Mendiburu, Andrés Z. & Carvalho, João A. & Coronado, Christian J.R., 2014. "Thermochemical equilibrium modeling of biomass downdraft gasifier: Stoichiometric models," Energy, Elsevier, vol. 66(C), pages 189-201.
    • Handle: RePEc:eee:energy:v:66:y:2014:i:c:p:189-201
    DOI: 10.1016/j.energy.2013.11.022
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    1. Luo, Siyi & Zhou, Yangmin & Yi, Chuijie, 2012. "Syngas production by catalytic steam gasification of municipal solid waste in fixed-bed reactor," Energy, Elsevier, vol. 44(1), pages 391-395.
    2. Pellegrini, Luiz Felipe & de Oliveira, Silvio, 2007. "Exergy analysis of sugarcane bagasse gasification," Energy, Elsevier, vol. 32(4), pages 314-327.
    3. van der Heijden, Harro & Ptasinski, Krzysztof J., 2012. "Exergy analysis of thermochemical ethanol production via biomass gasification and catalytic synthesis," Energy, Elsevier, vol. 46(1), pages 200-210.
    4. Fischer, Barry & Pigneri, Attilio, 2011. "Potential for electrification from biomass gasification in Vanuatu," Energy, Elsevier, vol. 36(3), pages 1640-1651.
    5. Ptasinski, Krzysztof J. & Prins, Mark J. & Pierik, Anke, 2007. "Exergetic evaluation of biomass gasification," Energy, Elsevier, vol. 32(4), pages 568-574.
    6. Erlich, Catharina & Fransson, Torsten H., 2011. "Downdraft gasification of pellets made of wood, palm-oil residues respective bagasse: Experimental study," Applied Energy, Elsevier, vol. 88(3), pages 899-908, March.
    7. Bui, T. & Loof, R. & Bhattacharya, S.C., 1994. "Multi-stage reactor for thermal gasification of wood," Energy, Elsevier, vol. 19(4), pages 397-404.
    8. Karamarkovic, Rade & Karamarkovic, Vladan, 2010. "Energy and exergy analysis of biomass gasification at different temperatures," Energy, Elsevier, vol. 35(2), pages 537-549.
    9. Raman, P. & Ram, N.K. & Gupta, Ruchi, 2013. "A dual fired downdraft gasifier system to produce cleaner gas for power generation: Design, development and performance analysis," Energy, Elsevier, vol. 54(C), pages 302-314.
    10. Azzone, Emanuele & Morini, Mirko & Pinelli, Michele, 2012. "Development of an equilibrium model for the simulation of thermochemical gasification and application to agricultural residues," Renewable Energy, Elsevier, vol. 46(C), pages 248-254.
    11. Chiang, Kung-Yuh & Lu, Cheng-Han & Lin, Ming-Hui & Chien, Kuang-Li, 2013. "Reducing tar yield in gasification of paper-reject sludge by using a hot-gas cleaning system," Energy, Elsevier, vol. 50(C), pages 47-53.
    12. Ashizawa, Masami & Hara, Saburo & Kidoguchi, Kazuhiro & Inumaru, Jun, 2005. "Gasification characteristics of extra-heavy oil in a research-scale gasifier," Energy, Elsevier, vol. 30(11), pages 2194-2205.
    13. Prins, Mark J. & Ptasinski, Krzysztof J. & Janssen, Frans J.J.G., 2007. "From coal to biomass gasification: Comparison of thermodynamic efficiency," Energy, Elsevier, vol. 32(7), pages 1248-1259.
    14. Ma, Zhongqing & Zhang, Yimeng & Zhang, Qisheng & Qu, Yongbiao & Zhou, Jianbin & Qin, Hengfei, 2012. "Design and experimental investigation of a 190 kWe biomass fixed bed gasification and polygeneration pilot plant using a double air stage downdraft approach," Energy, Elsevier, vol. 46(1), pages 140-147.
    15. Jarungthammachote, S. & Dutta, A., 2007. "Thermodynamic equilibrium model and second law analysis of a downdraft waste gasifier," Energy, Elsevier, vol. 32(9), pages 1660-1669.
    16. Sues, Anna & Juraščík, Martin & Ptasinski, Krzysztof, 2010. "Exergetic evaluation of 5 biowastes-to-biofuels routes via gasification," Energy, Elsevier, vol. 35(2), pages 996-1007.
    17. Leoneti, Alexandre Bevilacqua & Aragão-Leoneti, Valquiria & de Oliveira, Sonia Valle Walter Borges, 2012. "Glycerol as a by-product of biodiesel production in Brazil: Alternatives for the use of unrefined glycerol," Renewable Energy, Elsevier, vol. 45(C), pages 138-145.
    18. Dogru, M. & Howarth, C.R. & Akay, G. & Keskinler, B. & Malik, A.A., 2002. "Gasification of hazelnut shells in a downdraft gasifier," Energy, Elsevier, vol. 27(5), pages 415-427.
    19. Hernández, J.J. & Ballesteros, R. & Aranda, G., 2013. "Characterisation of tars from biomass gasification: Effect of the operating conditions," Energy, Elsevier, vol. 50(C), pages 333-342.
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