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Conversion of poly-isoprene based rubber to value-added chemicals and liquid fuel via ethanolysis: Effect of operating parameters on product quality and quantity

Author

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  • Ahmad, Nabeel
  • Ahmad, Nauman
  • Maafa, Ibrahim M.
  • Ahmed, Usama
  • Akhter, Parveen
  • Shehzad, Nasir
  • Amjad, Um-e-salma
  • Hussain, Murid
  • Javaid, Momina

Abstract

Liquefaction of poly-isoprene based rubber (PIR) was performed using ethanol as a solvent for the production of liquid fuel and chemicals. An autoclave batch reactor was used to perform the ethanolysis of PIR at different temperature ranges (250–375 °C), with different ethanol to PIR ratio (0.5:1 to 4:1), and at different reaction times (15–75mins). The experimental results showed that a maximum yield of 86 wt % was achieved at temperature of 325 °C, ethanol to PIR ratio 1/1, and reaction time of 30 min. This liquid oil yield is about 14% higher than the yield obtained from the pyrolysis of PIR at 500 °C and about 10% higher than the yield obtained from hydrothermal liquefaction of PIR at 375 °C. Moreover, the utilization of ethanol in the process was also incorporated and product yields were redefined. Furthermore, ethanol contributed to enhance the quality of liquid-oil, particularly in term of viscosity, acidity, and energy density. Furthermore, the FTIR analysis showed methyl and methylene were most dominating functional groups found in the liquid product and GCMS analysis identified that they were presented by alkenes, aromatics, and alkyls.

Suggested Citation

  • Ahmad, Nabeel & Ahmad, Nauman & Maafa, Ibrahim M. & Ahmed, Usama & Akhter, Parveen & Shehzad, Nasir & Amjad, Um-e-salma & Hussain, Murid & Javaid, Momina, 2020. "Conversion of poly-isoprene based rubber to value-added chemicals and liquid fuel via ethanolysis: Effect of operating parameters on product quality and quantity," Energy, Elsevier, vol. 191(C).
    • Handle: RePEc:eee:energy:v:191:y:2020:i:c:s0360544219322388
    DOI: 10.1016/j.energy.2019.116543
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    1. Toor, Saqib Sohail & Rosendahl, Lasse & Rudolf, Andreas, 2011. "Hydrothermal liquefaction of biomass: A review of subcritical water technologies," Energy, Elsevier, vol. 36(5), pages 2328-2342.
    2. Brand, Steffen & Hardi, Flabianus & Kim, Jaehoon & Suh, Dong Jin, 2014. "Effect of heating rate on biomass liquefaction: Differences between subcritical water and supercritical ethanol," Energy, Elsevier, vol. 68(C), pages 420-427.
    3. Mekhilef, S. & Siga, S. & Saidur, R., 2011. "A review on palm oil biodiesel as a source of renewable fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(4), pages 1937-1949, May.
    4. Prajitno, Hermawan & Park, Jongkeun & Ryu, Changkook & Park, Ho Young & Lim, Hyun Soo & Kim, Jaehoon, 2018. "Effects of solvent participation and controlled product separation on biomass liquefaction: A case study of sewage sludge," Applied Energy, Elsevier, vol. 218(C), pages 402-416.
    5. Dimitriadis, Athanasios & Bezergianni, Stella, 2017. "Hydrothermal liquefaction of various biomass and waste feedstocks for biocrude production: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 113-125.
    6. Song, Zhanlong & Liu, Li & Yang, Yaqing & Sun, Jing & Zhao, Xiqiang & Wang, Wenlong & Mao, Yanpeng & Yuan, Xueliang & Wang, Qingsong, 2018. "Characteristics of limonene formation during microwave pyrolysis of scrap tires and quantitative analysis," Energy, Elsevier, vol. 142(C), pages 953-961.
    7. Zeb, Hassan & Choi, Jaeyeon & Kim, Yunje & Kim, Jaehoon, 2017. "A new role of supercritical ethanol in macroalgae liquefaction (Saccharina japonica): Understanding ethanol participation, yield, and energy efficiency," Energy, Elsevier, vol. 118(C), pages 116-126.
    8. Tian, Chunyan & Li, Baoming & Liu, Zhidan & Zhang, Yuanhui & Lu, Haifeng, 2014. "Hydrothermal liquefaction for algal biorefinery: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 933-950.
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