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Co-Hydrothermal Liquefaction of Lignocellulosic Biomass in Supercritical Water

Author

Listed:
  • Kamaldeep Sharma

    (Department of Energy Technology, Aalborg University, Pontoppidanstræde 111, 9220 Aalborg, Denmark)

  • Ayaz A. Shah

    (Department of Energy Technology, Aalborg University, Pontoppidanstræde 111, 9220 Aalborg, Denmark
    Department of Energy & Environment Engineering, Dawood University of Engineering & Technology, New M. A. Jinnah Road, Jamshed Quarters Muslimabad, Karachi 74800, Sindh, Pakistan)

  • Saqib S. Toor

    (Department of Energy Technology, Aalborg University, Pontoppidanstræde 111, 9220 Aalborg, Denmark)

  • Tahir H. Seehar

    (Department of Energy Technology, Aalborg University, Pontoppidanstræde 111, 9220 Aalborg, Denmark
    Department of Energy & Environment Engineering, Dawood University of Engineering & Technology, New M. A. Jinnah Road, Jamshed Quarters Muslimabad, Karachi 74800, Sindh, Pakistan)

  • Thomas H. Pedersen

    (Department of Energy Technology, Aalborg University, Pontoppidanstræde 111, 9220 Aalborg, Denmark)

  • Lasse A. Rosendahl

    (Department of Energy Technology, Aalborg University, Pontoppidanstræde 111, 9220 Aalborg, Denmark)

Abstract

Hydrothermal liquefaction (HTL) is an effective technology for bio-crude production. To date, various co-liquefaction studies were performed with contrasted (different composition) biomasses in subcritical water. Therefore, the present study investigated co-hydrothermal liquefaction of similar kinds of lignocellulosic biomasses (wheat straw, eucalyptus, and pinewood) in supercritical water under equal ratios at 400 °C with catalytic medium (K 2 CO 3 ). The lower bio-crude and higher solid yields were obtained in co-liquefaction experiments, as compared to liquefaction of individual feedstocks. On the other hand, higher carbon recovery and higher HHVs were noticed in co-liquefaction-derived bio-crudes. Gas chromatography with mass spectrometry (GC-MS) results showed that organic compounds were detected in all bio-crudes in the order of phenol derivatives > ketones/aldehydes > aromatics > carboxylic acids/esters. The aqueous phase from all samples contained higher TOC in the range of 19 to 33 g/L, with alkaline pH. In short, the co-liquefaction slightly improved the bio-crude quality with a significant reduction in bio-crude energy recovery. This reflects that co-liquefaction of lignocellulosic feedstock is not favorable for enhancing bio-crude yield and improving the overall process economics of HTL.

Suggested Citation

  • Kamaldeep Sharma & Ayaz A. Shah & Saqib S. Toor & Tahir H. Seehar & Thomas H. Pedersen & Lasse A. Rosendahl, 2021. "Co-Hydrothermal Liquefaction of Lignocellulosic Biomass in Supercritical Water," Energies, MDPI, vol. 14(6), pages 1-13, March.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:6:p:1708-:d:520198
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    References listed on IDEAS

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