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Hydrogen donor solvents in liquefaction of biomass: A review

Author

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  • Isa, Khairuddin Md
  • Abdullah, Tuan Amran Tuan
  • Ali, Umi Fazara Md

Abstract

The environmental impact of global warming, caused by greenhouse gases has also fuelled the needs to utilise biomass, as its energy utilisation creates less environmental pollution and fewer health risks than fossil fuel combustion. Liquefaction of biomass using hydrogen donor solvents is a promising route to obtain clean biofuel using various solvents at moderate to high temperature (250–460°C) and pressure (150–320bar). Solvents such as sub-and supercritical water, alcohol, decalin, glycerol and tetralin can be used as potential hydrogen donor to enhance liquid oil yield with a reduced of oxygen content. Supercritical water with its excellent transport properties as well as hydrogen donor capability leads to hydrothermal decomposition of biomass and enhancing various compounds depending upon operating parameters. The selection of alcohol as a solvent related to the action of hydrogen donor and to its alkylating ability. The hydrogen donor solvents provide an alternative to hydrogen gas as a reducing gas. The advantage of using hydrogen donor solvent is to stabilise the free radical in the biomass liquefaction and yielding a higher product conversion. Compared with non-hydrogen donor solvents, hydrogen donor solvents such as tetralin and decalin show significant improvement not only in conversion and product distribution to liquid but also on the quality of bio-oil (oxygen content) due to the improvement of hydrogenation and hydrocracking reactions with inhibition of polycondensation. The advantage of hydrogen donor solvents over the molecular hydrogen due to a lower strength bonding of C-H as compared to H-H bond. A review on performances of water, alcohols and other hydrogen donor solvents in liquefaction of biomass has been made. The yield of hydrogen donated in the reaction has also been reported.

Suggested Citation

  • Isa, Khairuddin Md & Abdullah, Tuan Amran Tuan & Ali, Umi Fazara Md, 2018. "Hydrogen donor solvents in liquefaction of biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1259-1268.
    • Handle: RePEc:eee:rensus:v:81:y:2018:i:p1:p:1259-1268
    DOI: 10.1016/j.rser.2017.04.006
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    as
    1. Huang, Hua-jun & Yuan, Xing-zhong & Zhu, Hui-na & Li, Hui & Liu, Yan & Wang, Xue-li & Zeng, Guang-ming, 2013. "Comparative studies of thermochemical liquefaction characteristics of microalgae, lignocellulosic biomass and sewage sludge," Energy, Elsevier, vol. 56(C), pages 52-60.
    2. Toor, Saqib Sohail & Rosendahl, Lasse & Rudolf, Andreas, 2011. "Hydrothermal liquefaction of biomass: A review of subcritical water technologies," Energy, Elsevier, vol. 36(5), pages 2328-2342.
    3. Brand, Steffen & Hardi, Flabianus & Kim, Jaehoon & Suh, Dong Jin, 2014. "Effect of heating rate on biomass liquefaction: Differences between subcritical water and supercritical ethanol," Energy, Elsevier, vol. 68(C), pages 420-427.
    4. Sun, Peiqin & Heng, Mingxing & Sun, Shaohui & Chen, Junwu, 2010. "Direct liquefaction of paulownia in hot compressed water: Influence of catalysts," Energy, Elsevier, vol. 35(12), pages 5421-5429.
    5. Luo, Siyi & Feng, Yu, 2016. "The production of hydrogen-rich gas by wet sludge pyrolysis using waste heat from blast-furnace slag," Energy, Elsevier, vol. 113(C), pages 845-851.
    6. Xiu, Shuangning & Shahbazi, Abolghasem, 2012. "Bio-oil production and upgrading research: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4406-4414.
    7. Bridgwater, A. V. & Peacocke, G. V. C., 2000. "Fast pyrolysis processes for biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 4(1), pages 1-73, March.
    8. Brand, Steffen & Kim, Jaehoon, 2015. "Liquefaction of major lignocellulosic biomass constituents in supercritical ethanol," Energy, Elsevier, vol. 80(C), pages 64-74.
    9. Akhtar, Javaid & Amin, Nor Aishah Saidina, 2011. "A review on process conditions for optimum bio-oil yield in hydrothermal liquefaction of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1615-1624, April.
    10. Dimitriadis, Athanasios & Bezergianni, Stella, 2017. "Hydrothermal liquefaction of various biomass and waste feedstocks for biocrude production: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 113-125.
    11. Abbasi, Tasneem & Abbasi, S.A., 2010. "Biomass energy and the environmental impacts associated with its production and utilization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(3), pages 919-937, April.
    12. Luo, Siyi & Fu, Jie & Zhou, Yangmin & Yi, Chuijie, 2017. "The production of hydrogen-rich gas by catalytic pyrolysis of biomass using waste heat from blast-furnace slag," Renewable Energy, Elsevier, vol. 101(C), pages 1030-1036.
    13. Beis, S.H. & Onay, Ö. & Koçkar, Ö.M., 2002. "Fixed-bed pyrolysis of safflower seed: influence of pyrolysis parameters on product yields and compositions," Renewable Energy, Elsevier, vol. 26(1), pages 21-32.
    14. Shuping, Zou & Yulong, Wu & Mingde, Yang & Kaleem, Imdad & Chun, Li & Tong, Junmao, 2010. "Production and characterization of bio-oil from hydrothermal liquefaction of microalgae Dunaliella tertiolecta cake," Energy, Elsevier, vol. 35(12), pages 5406-5411.
    15. Qian, Yejian & Zuo, Chengji & Tan, Jian & He, Jianhui, 2007. "Structural analysis of bio-oils from sub-and supercritical water liquefaction of woody biomass," Energy, Elsevier, vol. 32(3), pages 196-202.
    16. Yuan, Xingzhong & Wang, Jingyu & Zeng, Guangming & Huang, Huajun & Pei, Xiaokai & Li, Hui & Liu, Zhifeng & Cong, Minghui, 2011. "Comparative studies of thermochemical liquefaction characteristics of microalgae using different organic solvents," Energy, Elsevier, vol. 36(11), pages 6406-6412.
    17. Brand, Steffen & Susanti, Ratna Frida & Kim, Seok Ki & Lee, Hong-shik & Kim, Jaehoon & Sang, Byung-In, 2013. "Supercritical ethanol as an enhanced medium for lignocellulosic biomass liquefaction: Influence of physical process parameters," Energy, Elsevier, vol. 59(C), pages 173-182.
    18. Williams, Paul T. & Besler, Serpil, 1996. "The influence of temperature and heating rate on the slow pyrolysis of biomass," Renewable Energy, Elsevier, vol. 7(3), pages 233-250.
    Full references (including those not matched with items on IDEAS)

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